Two-phase correlations

In this correlation the effect of channel entrance loss, wdiich is a stabilizing factor for the system, is not included. The amount of the heat transfer at OFI depends on pressure through saturation temperature, Tg t Since pressure drop characteristics are not required, the accuracy of the prediction does not depend on two phase correlations (subcooled void fi action, pressure drop, and heat transfer coefficient). All two phase effects are included in parameter, 4i , and flow instability is intimately related to pressure drop. The pressure drop depends on the local water quality, which follows firom the axial heat distribution. 

It should be noted that this two-phase correlation has not been developed for cross-country pipelines. This program is to be used to design plant battery limit piping. This calculation does not attempt to establish the impact of temperature (heat loss/gain) simply because the impact can only be established once the full fluid dynamics are available. For example, if there is heat loss, some liquid will condense, and vapor and liquid physical properties will change. It is not possible to calculate these without full fluid properties. 

The above approximation, however, is valid only for dilute solutions and with assemblies of molecules of similar structure. In the event that concentration is high where intemiolecular interactions are very strong, or the system contains a less defined morphology, a different data analysis approach must be taken. One such approach was derived by Debye et al [21]. They have shown tliat for a random two-phase system with sharp boundaries, the correlation fiinction may carry an exponential fomi. 

Lamellar morphology variables in semicrystalline polymers can be estimated from the correlation and interface distribution fiinctions using a two-phase model. The analysis of a correlation function by the two-phase model has been demonstrated in detail before [30,11] The thicknesses of the two constituent phases (crystal and amorphous) can be extracted by several approaches described by Strobl and Schneider [32]. For example, one approach is based on the following relationship ... 

When two phases are present the situation is quite complex, especially in beds of fine soHds where interfacial forces can be significant. In coarse beds, eg, packed towers, the effects are often correlated empirically in terms of pressure drops for the single phases taken individually. 

Outlined below are the steps required for of a X T.E calciilation of vapor-phase composition and pressure, given the liquid-phase composition and temperature. A choice must be made of an equation of state. Only the Soave/Redlich/Kwong and Peng/Robinson equations, as represented by Eqs. (4-230) and (4-231), are considered here. These two equations usually give comparable results. A choice must also be made of a two-parameter correlating expression to represent the liquid-phase composition dependence of for each pq binaiy. The Wilson, NRTL (with a fixed), and UNIQUAC equations are of general applicabihty for binary systems, the Margules and van Laar equations may also be used. The equation selected depends on evidence of its suitability to the particular system treated. Reasonable estimates of the parameters in the equation must also be known at the temperature of interest. These parameters are directly related to infinite-dilution values of the activity coefficients for each pq binaiy. 

TABLE 5-28 Mass Transfer Correlations for Packed Two-Phase Contactors—Absorption, Distillation, Cooling Towers, and Extractors (Packing Is Inert)... 

Rhodes, and Scott Can. j. Chem. Eng., 47,445 53 [1969]) and Aka-gawa, Sakaguchi, and Ueda Bull JSME, 14, 564-571 [1971]). Correlations for flow patterns in downflow in vertical pipe are given by Oshinowo and Charles Can. ]. Chem. Eng., 52, 25-35 [1974]) and Barnea, Shoham, and Taitel Chem. Eng. Sci, 37, 741-744 [1982]). Use of drift flux theoiy for void fraction modeling in downflow is presented by Clark anci Flemmer Chem. Eng. Set., 39, 170-173 [1984]). Downward inclined two-phase flow data and modeling are given by Barnea, Shoham, and Taitel Chem. Eng. Set., 37, 735-740 [1982]). Data for downflow in helically coiled tubes are presented by Casper Chem. Ins. Tech., 42, 349-354 [1970]). 

Pressure drop during condensation inside horizontal tubes can be computed by using the correlations for two-phase flow given in Sec. 6 and neglec ting the pressure recoveiy due to deceleration of the flow. 

The power for agitation of two-phase mixtures in vessels such as these is given by the cuiwes in Fig. 15-23. At low levels of power input, the dispersed phase holdup in the vessel ((j)/ ) can be less than the value in the feed (( )df) it will approach the value in the feed as the agitation is increased. Treybal Mass Transfer Operations, 3d ed., McGraw-HiU, New York, 1980) gives the following correlations for estimation of the dispersed phase holdup based on power and physical properties for disc flat-blade turbines ... 

For our purposes, a rough estimate for general two-phase situations can be achieved with the Lockhart and Martinelli correlation. Perry s has a writeup on this correlation. To apply the method, each phase s pressure drop is calculated as though it alone was in the line. Then the following parameter is calculated ... 

Lockhart, R. W., and Martinelli, R. C., Proposed Correlation of Data for Isothermal Two-Phase, Two-Component Plow in Pipes, Chemical Engineering Progress, 45 39 8, 1949. 

Lockhart and Martinelli used pipes of one inch or less in diameter in their test work, achieving an accuracy of about -l-/-50%. Predictions are on the high side for certain two-phase flow regimes and low for others. The same -l-/-50% accuracy will hold up to about four inches in diameter. Other investigators have studied pipes to ten inches in diameter and specific systems however, no better, generalized correlation has been found.The way... 

The standard free energy can be divided up in two ways to explain the mechanism of retention. First, the portions of free energy can be allotted to specific types of molecular interaction that can occur between the solute molecules and the two phases. This approach will be considered later after the subject of molecular interactions has been discussed. The second requires that the molecule is divided into different parts and each part allotted a portion of the standard free energy. With this approach, the contributions made by different parts of the solvent molecule to retention can often be explained. This concept was suggested by Martin [4] many years ago, and can be used to relate molecular structure to solute retention. Initially, it is necessary to choose a molecular group that would be fairly ubiquitous and that could be used as the first building block to develop the correlation. The methylene group (CH2) is the... 

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