Tungsten -oxide

Sellaite, see Magnesium fluoride Senarmontite, see Antimony(III) oxide Siderite, see Iron(II) carbonate Siderotil, see Iron(II) sulfate 5-water Silica, see Silicon dioxide Silicotungstic acid, see Silicon oxide—tungsten oxide—water (1/12/26)... 

Traditionally, tungsten ore is chemically processed to ammonium paratungstate [1311-93-9] 5H20, and tungsten oxides, W O. These... 

T. WHken, C. Wert,J. Woodhouse, and W. Morcom, "Reduction of Blue Tungsten Oxide," in H. H. Hausner and P. V. Taubenblat, eds.. Modem Developments in Powder Metallurgy, Vol. 9, Plenum Press, New York, 1977, pp. 161—169. 

Blue tungsten oxide and combiaations thereof (106—113) have been the subject of a number of patents, as have copper(II) fluoborate (114) and alkaH metal or ammonium sulfate-hydrogen sulfate catalysts (115,116). 

Wolframit, n. (Min.) wolframite. Wolfram-lampe, /. tungsten lamp, metall, n. metallic tungsten, -ocker, m. tungstic ocher, tungstite. -oxyd, n. tungsten oxide, -salz, n. tungsten salt. 

Tungsten halides, 3, 974, 984, 988 synthesis, 3,974 Tungsten hexaalkoxides physical properties, 2,347 Tungsten oxide ruthenium oxide support... 

D.G. Barton, M. Shtein, R.D. Wilson, S.L. Soled, and E. Iglesia, Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostmctures, J. Phys. Chem. 103(4), 630-640 (1999). 

New inorganic electrode films based on molybdenum and tungsten oxides have been introduced for aqueous solutions heteropolyanion electrodes... 

Fig. 6.1b) in which twelve inner ligands bridge the edges of the Me octahedron, and six outer ligands occupy apical positions, predominate. These units are found in reduced zirconium, niobium, tantalum, and rare-earth halides, and niobium, tantalum, molybdenum and tungsten oxides [la, 6, 10]. 

Fig. 4. Cyclic voltammograms of various tungsten oxides (a) WOyxHjO, (b) WOj-xHjO, and (c) Nao. WOyxHjO.

Investigation of direct conversion of methane to transportation fiiels has been an ongoing effort at PETC for over 10 years. One of our current areas of research is the conversion of methane to methanol, under mild conditions, using li t, water, and a semiconductor photocatalyst. Research in our laboratory is directed toward ad ting the chemistry developed for photolysis of water to that of methane conversion. The reaction sequence of interest uses visible light, a doped tungsten oxide photocatalyst and an electron transfer molecule to produce a hydroxyl i cal. Hydroxyl t cal can then react with a methane molecule to produce a methyl radical. In the preferred reaction pathway, the methyl radical then reacts with an additional wata- molecule to produce methanol and hydrogen. 

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