Tungsten oxides, structure

D.G. Barton, M. Shtein, R.D. Wilson, S.L. Soled, and E. Iglesia, Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostmctures, J. Phys. Chem. 103(4), 630-640 (1999). 

Gartner, G., Jamiel, P., and Lydtin, H., Plasma-Activated Metalorganic CVD of Illb Oxides/Tungsten Layer Structures, Proc. of 11th Int. Conf on CVD, (K. Spear and G. Cullen, eds.), pp. 589-595, Electrochem. Soc., Pennington, NJ 08534 (1990)... 

Thomas, R., Moulijn, J.A., Debeer, V.H.J. and Medema, J. (1980) Structure-metathesis-activity relations of silica supported molybdenum and tungsten-oxide. J. Mol. Catal., 8, 161. 

Vapor deposition techniques have been extensively studied for the fabrication of metal and metal oxide structures. Indeed, the first reported tungsten oxide nanorods were essentially grown by this method. This groundbreaking synthesis of W02.72 leaves room for improvement, however, as it requires a reaction temperature of 1600°C in an argon atmosphere. Additionally, the researchers found the reaction product to be commingling WO2.72 nanorods and WO3 platelets rather than pure nanorods. Later,... 

The effect of electron transfer between tungsten oxide and titanium oxide is also important in photochromatic applications. In an excellent study of aqueous sols. He et al. analyze the electronic structure of the tungsten oxide-titanium oxide system, finding that titanium oxide can catalyze the generation of W+. This state is a colored state and can be generated from WO3 WH2O by the following reactions ... 

Section II is about the new structure and understanding of nanocatalysts. Chapters 4 and 5 provide insight for understanding the structure and reactivity of gold catalyst. Chapters 6 and 7 disclose new methods for making nanoparticle catalysts in a control way by using the sol-gel technique and dendrimer template, respectively. Chapter 8 reviews the synthesis, structure, and applications of tungsten oxide nanorods. 

Ti02 nanotubes were used to support M0O3 observing a spontaneous dispersion of molybdenum-oxide on the surface of nanotubes, which was different from that observed on titania particles.Supporting tungsten oxides a preferential orientation of the (002) planes was observed. Vanadium-oxide in the form of nanorods could be prepared using the titania nanotube as structure-directing template under hydrothermal... 

Group 4, surface chemistry on oxides, 12, 515 Group 5, surface chemistry on oxides, 12, 524 molybdenum, surface chemistry on oxides, 12, 529 into nickel complexes, 8, 59-60 with palladium, GO insertion, 8, 200 tungsten, surface chemistry on oxides, 12, 531 on zinc compounds, 2, 366 Alkoxido-imido tungsten complexes structure and properties, 5, 754—755 synthesis, 5, 750/... 

The silicon detectors were made of n-typed single crystal of 1 mm thick. They have a MOS structure of gold, tungsten oxide, n-typed silicon and aluminum back contact. Since these layers can be deposited on the silicon wafer by evaporation techniques, the fabrication process is so simple as to be applicable to fabrication of the detectors for a special use. No surface treatment for passivation is given to them so that their performance is affected by ambient gases. For example, some good detectors show a leakage current of half micro-ampere at room temperature in the atmosphere, but a few micro-ampere in vacuum. So, in order to stabilize their performance, the silicon detectors were operated at the dry ice temterature. 

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