Trinitro

N,2,4,5-Tetranitro-N-methylaniline (2,4,5-trinitrophenyl-N-m ethylnitramine), needles from nitric acid mp 143.5° prepd by nitration of 2,4,5-trimtro-N-methylaniline, or by the action of 90% nitric acid on 2,4,5-trinitro-N.N-dimethylaniline (Refs 1 3) 2,3,4,6-Tetranitro-N-methylaniline, mp 127° prepd by the action of sulfuric acid on N,2,4,5-tetranitro-N-methylaniline (Refs 2 3)... [Pg.119]

Trinitro-1-Methylnaphthalene, mp 170°, gold cryst from benz or ale. Prepn from 4,5-dinitro-l-methylnaphthalene by heating with nitric acid (d 1.5g/cc)... [Pg.127]

Trinitro-1-Naphthol (2,4,5-Trinitro-1-hydroxy naphthalene). Yellow leaflets or prisms mp 189—90° bp, explds. Sol in hot AcOH, si sol in hot w, ale, benz, eth acetate, xylene cold AcOH. Prepn from 2,4-dinitro-naphthol by nitration, or from 4-chlor-1,3,8-trinitronaphthalene by heating with 0.1 N NaOH in w or ale... [Pg.202]

Trinitro-N,N-dimethylaniline, om-red crysts (from acet or benz), mp 198°, sp gr 1.585 at 17° Can he prepd by heating N,N-di-methyl-N -phenyl-4,6-dinitro-l, 3-phenylene-diamine with aniline ale in a tube at 110—20°, or by other methods (Ref 10)... [Pg.209]

Trinitro-l-acetamidonaphthalene, cryst, dec ca 275°. Was prepd by treating 2,4,5-trinitro-l-aminonaphthalene with acetic anhydride coned sulfuric acid... [Pg.20]

Trinitro-l-aminonaphthalene or 2,4,5-TrinHfo-a-naphthylomine, yel ndls or microscopic prisms mp ca 264° with darkening and defgr at higher temp(Ref 2) melts with decompn at 305° (Ref 3) decomp at 310°... [Pg.237]

Ref 4). Was first prepd by Staedel(Ref 2) by heating the ethyl ether of 2,4,5 trinitro-o-naphthylamine with ale NHS in a sealed cube at 50° for 2 hours. A simpler method is to pass NHS gas through an amyl alcohol soln of 4 chloro-l,3,8 trinitro-naphthalene (Ref 3). Other methods are described in Ref 4... [Pg.237]

Imidazole, l,2,5-trimethyl-4-nitro-mass spectra, 5, 359 Imidazole, 1-trimethylsilyl-reactions, 5, 454 with acid chlorides, 5, 391 Imidazole, 1-trimethylstannyl-reactions, 5, 454 Imidazole, 2,4,5-trinitro-reactions, 5, 98 synthesis, 5, 395 Imidazole, 1,2,4-triphenyl-UV spectra, 5, 356 Imidazole, 1,2,5-triphenyl-UV spectra, 5, 356 Imidazole, 2,4,5-triphenyl-chemiluminescence, 5, 381, 406 irradiation, 5, 433 oxidation, 5, 376, 406 photochemical addition reactions, 5, 421 synthesis, 5, 467, 483 UV spectra, 5, 356, 357 Imidazole, 1-trityl-rearrangement, 5, 377 Imidazole, vinyl-Michael addition, 5, 437 polymers, 1, 281 Imidazole, 1-vinyl-reactions, 5, 450 thermal rearrangement, 5, 450 Imidazole, 2-vinyl-oxidation, 5, 437 Imidazole, l-(D-xylofuranosyl)-synthesis, 5, 491 277-Imidazole, 2,2-dialkyl-rearrangement, 5, 422 277-Imidazole, 4,5-dicyano-2,2-dimethyl-synthesis, 5, 472... [Pg.654]

Ref 4). Was first prepd by Staedel(Ref 2) by heating the ethyl ether of 2,4,5 trinitro-... [Pg.237]

Several more or less expl halogen compds of Trinitrophenols are listed in Beilstein, ie 3-Chloro-2,4,5-Trinitro phenol. (02N)3CfiH(OHX i, crysts, mp 112.5-113.5° (Beil 6, [283])... [Pg.711]

Trinitro-M,N-dimethylaniline, brownish crysts, sp gr 1.552 at 17° mp 154°. Can be prepd along with the 2,4,5"trinitro deriv by warming of 3 ni trodimethy Ian iline with 70% nitric acid at 40° or by nitrating 3,4-dinitto deriv with nitric acid (d 1.37 to I,40)(Ref 9)... [Pg.209]

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