Trinitro phenetole

Tire present paper describes a simple and convenient procedure for the identification of explosives viz Picramide Hexyl 2,4-Dinitrophenetole (DNP) Tetryl s-TNT s-TNB 2,4,6-Trinitroanisole (TNA) 2,4-Dinitroanisole (DNA) 2,4,6-Trinitro-phenetole (TNP) DNCB m-DNB and Picryl Chloride (PC) in ordnance stores as charge-transfer complexes with amines utilizing TLC... 

RDX and Tetryl), every other available expl substance was also used as an ingredient of expl compns. Among these substances may be mentioned the following TNAns (Trinitroanisole), TNPht (Trinitro-phenetole), HNDPhA (Hexanitrodiphenylamine),... 

N, N -Dimethyl-Nl,4,6-trinitro-m-pbenylene-diamine, H3C.NH.C6H2(N02)2.N(N02)-CM3 crysts, mp 181.5° was prepd by treating 4,6-dinitro-3 methylnitramino-phenetole with an alcoholic methylamine soln can be nitrated to form an expl pentanitro deriv (Refs... 

Trinitro-4-acetaminophenolethylether (called by Lorang 4-Ethoxy-2,3,6-trinitroacetanilide), crysts (from ale), mp ca 260° (dec) sol in acet AcOH, diff sol in hot ale or benz. Can be prepd by nitrating 2,3-dinitro-4-acetamino-phenetole with mixed nitric-sulfuric acid at RT. Its expl props were not examined... 

Tetranitroaniline is a rather unstable compound. Thus, when boiled with water its meta- nitro group undergoes hydrolysis to a phenolic group (II), while on boiling with methyl- or ethyl alcohol it yields an anisole- (III) or phenetole derivative (IV), which with ammonia may form trinitro-m-phenylenediamine (V) ... 

Alkyl derivatives other than halides have been used to form pyridinium salts. Potassium ethyl sulphate gives the ethyl-pyridinium salt i and dimethyl sulphate is nd alkyl toluenesulphonates i quaternize pyridine. Primary and secondary alkyl nitrates and polymethylene dinitrates have also been used, but with t-butyl and cyclohexyl nitrate only elimination occurs320. 2,4,6-Trinitro-anisole and -phenetole convert pyridine into the alkylpyridinium picrates32i. 

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