Methane, Trinitro

Beilstein Handbook Reference) BRN 1708361 EINECS 208-236-8 Methane, trinitro- Nitroform Trinitromethane. Used in the manufacture of expisives and propellants. Liquid mp -15" bp explodes d = 1.479 very soluble in EtOH, Me2CO,... [Pg.651]

Silylation of Salts of AN a-Functionalized AN 52a-c (trinitro-methane, dinitroethane, dimethyl nitromalonate, nitroacetates, etc.) can form salts, which are quite stable. It should be noted that stability of silver and mercury salts can be increased by complexation with neutral molecules (e.g., with dioxane). Hence, for these AN it is advantageous to prepare salts A, which react with halosilanes to smoothly form the corresponding SENAs 51a—C (Scheme 3.51) (174-177). [Pg.470]

Die Synthese von 2-Nitromethyl-l,3,5-trinitro-benzol ausgchcnd von 2,4,6-Trinitro-toluol gelingt am besten mit Fluor-trinitro-methan in alkalischer THF/Methanol-Losung. Die sonst gangigen Nitrierungsreagentien Nitro-alkane und Tetranitro-methan eignen sich hier nicht2. [Pg.148]

Trinitro methane Ethylenediamine dinitrate Biguanide diperchlorate 3-Nitroperchlorylbenzene Perchorylbenzene Ammonium perchlorate... [Pg.183]

Erythritol tetranitrate Trinitro methane 1,3,5,7-Tetranitro adamant ane... [Pg.358]

Qcombstn 1645 cal/g Qform 70 kcal/mol (Ref 5) was first reported in the open literature by Schenck 8t Wetterholm (Ref 2) who prepd the cgmpd by stirring 2 mo Is of trinitroethanol with 1 mol of urea in aq soln for 2 hrs at 80°. This compd was also prepd by addg dimethylolurea in water to trinitro-methane in aq soln and stirring the mixt for 5 mins at 40°(Ref 3)... [Pg.149]

N-(2f4,6-TRINITRO-N-NITRANILINO)-TRIMETHYLOLMETHANE TRINITRATE N>(274r6 Trinitrophenyl-N-nitramino)>tri-methy lot methane Trinitrate or N-(2,4,6-T ri ni trop heny l) (tri s-nitroxymethyl-methyl)-nitramine, designated as Heptryl. Called by Kistiakowsky N-Nitro-N-picryl-trimethylol-methylamine Trinitrate. Also called 2-(2 ... [Pg.441]

Anilinotrimethylolmethane and derivs 1 A442 2,4-dinitroanilinotrimethylolmethane 1 A441 N-(2,4,6-trinitro-N-nitranilino)-triinethylol-methane trinitrate (Heptryl) 1 A441—A442... [Pg.469]

Contact of acetylene with the cone, acid in presence of mercury salts forms trinitro-methane, explosive above its m.p., 15°C. Subsequent addition of sulfuric acid produces tetranitromethane, a powerful oxidant of limited stability, in high yield. [Pg.1636]

Methan Nitro-trichlor- V/3, 785 (Chlorierung), 788 (aus 2,4,6-Trinitro-phenol) X/l, 123 (destrukt. Nitrierung)... [Pg.86]

Methan Nitrooxy-[nitro-(2,2,2-trinitro-ethyl)-amino]- E14a/2, 88 (R—Cl/AgN03)... [Pg.116]

Trinitrodipheny/methane, (02N>2CgH3.CH2.C6H4(N02), crysts (from ale), mp 111—13° was obtd when 2,2 -dinitro diphenylm ethane in coned sulfuric acid was nitrated with Na nitrate in coned sulfuric acid at 70° for 1.5 hrs (Ref 3) 2.4A -Trinitrodiphenylmethane, crysts (from ale), mp 107—10° was prepd by nitrating 4,4-dinitfodipbenylmethane in coned sulfuric acid with K nitrate in coned sulfuric at 70° for 1.5 hrs. This synthesis is reported to establish the structure as that of the x,x,x-Trinitro deriv prepd by Staedel (Ref 3)... [Pg.359]

Fur die Herstellung von 2,2-Dinitro-2-fluor-ethanol ist die Reduktion von Fluor-trinitro-methan mit Wasserstoffperoxid in Anwesenheit von Formaldehyd (— 5 bis — 10°/30 Min. 91%) die geeignetere Methode893. [Pg.104]

Fluor-trinitro-methan wird elektrochemisch zu Dinitro-fluor-methan reduziert902. [Pg.104]

Durch anodische Oxidation von Trinitro-methan (1,9-2 V) in Gegenwart von THF oder Toluol erha.lt man (2-Tetrahydrofuryl)-trinitro-methan (40-50%) bzw. 2-Phenyl-l,1,1-trinitro-ethan (30%)561-562. [Pg.187]

Trinitro-ethan kann aus Tetranitro-methan oder Halogen-trinitro-methanen und Me-thyljodid in aprotisch-dipolaren Medien hergestellt werden (38-95%)563-567. Redoxpro-... [Pg.187]

Alkylierung, Hydroxylalkylierung und Michael-Addition an Trinitro-methan und Dinitro-halogen-metha-nen s.S. 103, 187. [Pg.191]

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