Tret’yakov

N.N. Oleinikov, Tu.D. Tret yakov and A.V. Shumyantsev, J. Solid State Chem.,... 

G.M.Tret yakov, "Artillery Ammunition, Voyennizdat,Moscow(1946) Transactions of the Faraday Society(London)... 

Tret yakov Yu.D., Vestnik Akadem. Nauk SSSR, (2), 98 (1987). 

Yu.D. Tret yakov. Tverdofazniye reaktsii - Moskwa Khimiya, 1978. 

Tret yakov [111] did not find half-order kinetics for the atomisation of hydrogen by gold under these conditions. On the contrary, they reported first-order kinetics. They attributed the observation of half-order kinetics by Brennan and Fletcher for this system to the presence of surface impurities capable of rapidly dissociating molecular hydrogen, whereas molecular adsorption on the clean surface, being activated, was considered by them to be rate-determining. We will return to the H2—Au system in Sect. 3.2.1(d). Nomes and Donaldson [8] have demonstrated half-order behaviour for the N2—W system, but over a narrower pressure range. 

Kislyuk and Tret yakov [111] have reported that the atomisation of hydrogen (and deuterium) over gold is first-order in the temperature range 950—1250 K at pressures in the range 10 3 to 10 5 torr. Their result for... 

However, the really important point of Fig. 12 is to demonstrate that an activation energy of only 75 kJ mole-1 is not sufficient to make the supply of molecules to the surface rate determining under the conditions used by Kislyuk and Tret yakov. At their highest pressures for 1200 K, the kinetics have almost completed the transition to half-order. Clearly, more work is required to resolve these inconsistencies. 

M.U. Kislyuk and I.I. Tret yakov, Kinet. Ratal., 17 (1976) 1515 Engl. Transl., Plenum Publications Corp., p. 1302. 

A. V. Sklyarov, I. I. Tret yakov, R. R. Shub, and S. Z. Roginskii, Doklady Akad. Nauk... 

Volkova LK, Tret yakov VP (1995) Theoretical Experimental Chem 31 27... 

A previous study (]J has also shown that CO2 can be converted into methane. Infrared studies have shown that CO2 forms a bicarbonate in accordance with the adsorption studies of Tret yakov et al. ( ). Heating the bicarbonate-containing zirconia in hydrogen led to a surface methoxide species ( ). It has been suggested that CO2 interacts with terminal hydroxyl groups to form the bicarbonate ( ). The route from CO2 to methoxide (the methane precursor) has not been reported over zirconia. 

Tret yakov, V. P. React. Kinet. Catal. Lett. 1982, 21, 49. 

Romanenko GV, Fokin SV, Vasilevskii SF, Tret yakov EV, Shvedenkov YG, Ovcharenko VI (2001) Russ J Coord Chem 27 360... 

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