Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Transport monotonous

The transport of heavy metals in the atmosphere is described by means of a monotone version of Bott s advection scheme. Pressure-based s-coordinate in the vertical makes possible to take into account an effect of the underlying surface elevation. Vertical eddy... [Pg.364]

The monotonic increase of immobilized material vith the number of deposition cycles in the LbL technique is vhat allo vs control over film thickness on the nanometric scale. Eilm growth in LbL has been very well characterized by several complementary experimental techniques such as UV-visible spectroscopy [66, 67], quartz crystal microbalance (QCM) [68-70], X-ray [63] and neutron reflectometry [3], Fourier transform infrared spectroscopy (ETIR) [71], ellipsometry [68-70], cyclic voltammetry (CV) [67, 72], electrochemical impedance spectroscopy (EIS) [73], -potential [74] and so on. The complement of these techniques can be appreciated, for example, in the integrated charge in cyclic voltammetry experiments or the redox capacitance in EIS for redox PEMs The charge or redox capacitance is not necessarily that expected for the complete oxidation/reduction of all the redox-active groups that can be estimated by other techniques because of the experimental timescale and charge-transport limitations. [Pg.64]

The flow into the central dump combustor is computed by solving the compressible, time-dependent, conservation equations for mass, momentum, and energy using the Flux-Corrected Transport (FCT) algorithm [21], a conservative, monotonic algorithm with fourth-order phase accuracy. No explicit term representing physical viscosity is included in the model. [Pg.113]

It is a self-sustained reaction in which the energy is transmitted from the burning to the unburnt layers of the substance by means of surface transport properties consisting of burning, which is a relatively slow process. The linear deflgrn rate can be considered to be a function of ambient pressure only consequently, steady states are attainable at constant pressures. Specifically, for condensed expls the linear deflgrn rate is a monotone increasing function of pressure, a fact which plays an important role in the self-acceleration of explosive reactions... [Pg.512]

Periodic reactions of this kind have been mentioned before, for example, the Liese-gang type phenomena during internal oxidation. They take place in a solvent crystal by the interplay between transport in combination with supersaturation and nuclea-tion. The transport of two components, A and B, from different surfaces into the crystal eventually leads to the nucleation of a stable compound in the bulk after sufficient supersaturation. The collapse of this supersaturation subsequent to nucleation and the repeated build-up of a new supersaturation at the advancing reaction front is the characteristic feature of the Liesegang phenomenon. Its formal treatment is quite complicated, even under rather simplifying assumptions [C. Wagner (1950)]. Other non-monotonous reactions occur in driven systems, and some were mentioned in Section 10.4.2, where we discussed interface motion during phase transformations. [Pg.289]

The superconducting properties induced in the normal metal manifest themselves in many different ways, including energy-dependent transport properties and a modification of the local density of states. For instance, the conductance of a normal conductor connected to a superconducting electrode shows a striking re-entrant behavior [4]. At non-zero temperature and/or bias, the conductance of the normal metal is enhanced as compared to the normal-state. At zero temperature and zero bias, the expected conductance coincides with the normal-state value. The conductance has therefore a non-monotonous behavior. [Pg.175]

The validity of our description can be checked in Fig. 3 where we compare the actual position of the acquired spectra to the position extracted from the fit, in units of the relevant characteristic length. The data points follow a monotonous behavior, but with a significant scattering. From the slope of the mean line we can draw through the data points on the N side (top part of Fig. 3), we can extract the value = 94 nm. This corresponds exactly to the estimation based on the gap A and the measured mean free path of 16 nm in Au. On the S side (bottom part of Fig. 3), the estimated length is s = 50 nm. Taking into account the reduced gap A, it corresponds to a mean free path of 4.5 nm which is half the value estimated from transport properties of similar samples. In fact, it should be considered more as a property of the Nb-Au layer at its border than a property of the bare Nb film. [Pg.180]

Surprisingly, intuition fails to predict the behavior of the same solute and solvent in a membrane with a uniform pore size larger than both the solvent and solute. The expectation that such a membrane will provide no rejection of the solute has been refuted repeatedly. Indeed, careful experiments indicate that partial rejection of the solute occurs even when the solute is considerably smaller (say 1/1 Oth as large as the pore size) (Miller, 1992 Deen, 1987 Ho and Sirkar, 1992 Happel and Brenner, 1965). The extent of rejection increases monotonically to the total rejection limit as the solute size approaches the pore size. These effects arise both from entropic suppression of partitioning and from augmented hydrodynamic resistance to transport through the fine pores. Thus, in this case, for a porous membrane, thermodynamic partitioning can play a role in the physical chemical processes of transport. [Pg.348]

This equation should be fulfilled at least in one point for x + D > 0. To note y is here the rate of cleavage. Hence, there are no limitations for its value. Eq. (22) shows that the condition for obtaining a maximum when we have a single cleavage center is independent of the actual form of the transport rate function, but is rather dependent on its slope. This would suggest that it is possible to obtain a peak in the length distribution even when the transport rate function is monotonically decreasing, and indeed that is what we find from our numerical simulations. [Pg.384]

Fig. 14.6 (a) Monotonously decreasing transport rate function v(x) = v (x). The vertical lines show the location of the point where the condition for the maximum in the length distribution (Eq. 22) holds and the location of the cleavage centre. The parameters are D = 15 and y = 0.001. [Pg.386]

Figure 15 shows the calculated DOS for electrons in a 40-nm bismuth nanowire compared to that of bulk bismuth. The DOS in nanowires is a superposition of one-dimensional transport channels, each located at a quantized subband energy snm. We note that the DOS in nanowires has sharp peaks at the subband edges, whereas that in a bulk material is a smooth monotonic function of energy. The enhanced DOS at the subband edges of nanowires has important implications for many applications, such as in optics (Black et al, 2000) and thermoelectrics (Hicks and Dresselhaus, 1993). [Pg.188]

If the unsaturated zone is composed of relatively fine sediment (silt and fine sands) a quasi-uniform seepage flow can be assumed for the unsaturated zone in humid climate zones over long time spans. Therefore, the transport of infiltration water can be simulated in PHREEQC as a monotonous movement in accordance with the "piston flow model. A constant flow of infiltration water of 0.5 m per year is assumed for the following simulation. Furthermore, it is considered simplistically that the infiltrating precipitation has a tritium activity of 2000 TU (tritium units) over a period of 10 years. Then, it is assumed that the tritium activity decreases to zero again. [Pg.133]


See other pages where Transport monotonous is mentioned: [Pg.389]    [Pg.2914]    [Pg.213]    [Pg.176]    [Pg.144]    [Pg.541]    [Pg.158]    [Pg.34]    [Pg.334]    [Pg.506]    [Pg.147]    [Pg.211]    [Pg.216]    [Pg.25]    [Pg.82]    [Pg.92]    [Pg.47]    [Pg.290]    [Pg.15]    [Pg.310]    [Pg.346]    [Pg.243]    [Pg.97]    [Pg.99]    [Pg.139]    [Pg.167]    [Pg.380]    [Pg.382]    [Pg.385]    [Pg.385]    [Pg.386]    [Pg.386]    [Pg.387]    [Pg.525]    [Pg.791]    [Pg.469]    [Pg.314]    [Pg.288]    [Pg.78]   
See also in sourсe #XX -- [ Pg.385 ]




SEARCH



Monotonic

Transport monotonously decreasing

© 2024 chempedia.info