Toluol

Trinitrotoluene (TNT) was one of the primary World War I explosives used by the United States. During the war, the United States bought all the Chilean sodium nitrate and still needed more nitrate. The United States turned to toluol as the main raw material for producing the quantity of TNT needed, as it was cheaper and more readily available. Some toluol was produced in by-product ovens by the distillation of coal by the companies listed in Table 3.3. [Pg.27]

In addition to these companies, toluol was also extracted from gas, which only marginally reduced the efficiency of gas for home use. The following city gas companies extracted toluol [Pg.27]

New York, NY Brooklyn, NY Boston, MA New Haven, CT Albany, NY Utica, NY Elizabeth, NJ Washington, DC Detroit, MI St. Louis, MO [Pg.27]

Coal Distillation Company Toluol Production GbsAr) [Pg.27]

Extensive contamination has been found at the toluol extraction gas site in Washington, DC, including dinitrotoluene. Some of the groundwater samples vary extensively, indicating that containerized explosives, precursors, or munitions may have been buried on the gas light site. Ironically, this site is next to the Washington Navy Yard, and dinitrotoluene is a component of bag powder. Was the toluol being converted to bag powder [Pg.28]

Extrainer benzene Motor benzole Toluol Xylol... [Pg.290]

Chemical Designations - Synonyms Methylbenzen, Methylbenzol, Toluol Chemical Formula QH,CH3. [Pg.367]

Azo-toluol, m. azotoluene, -verbindung, /. azo compound, -walkrot, n. fulling azo red. Azozy-benzol, n. azoxybenzene. -verbindtin L, /. azoxy compound. [Pg.54]

Brom-s ure, /. bromic acid, -schwefel, tn. sulfur bromide, -silber, n. silver bromide, -silizium, n. silicon bromide. -spat, n. bromyrite (AgBr). -stickstoff, tn. nitrogen bromide, -toluol, n. bromotoluene. -uber-trager, tn. bromine carrier. [Pg.83]

Chlor-siure, /. chloric acid. -sMureanhydrid, n. chloric anhydride, chlorine(V) oxide, -schwefel, n. sulfur chloride (esp. the monochloride). -silber, n. silver chloride, -sili-cium, n. silicon tetrachloride, -soda, /. = Chlornatron. -stickstoff, m. nitrogen chloride. -Strom, m. stream of chlorine, -strontium, n. strontium chloride, -suifonsaure, /. chlorosulfonic acid, chlorosulfuric acid, -toluol, n. chlorotoluene. -fibertrager, m. chlorine carrier. [Pg.91]

Cyan-saure, /. cyanic acid cyano acid, -schlamm, m. cyanide sludge, -senf l, n. cyanomustard oil. -silber, n. silver cyanide. -stickstoS, m. cyanonitride. -toluol, n. cyanotoluene. [Pg.95]

Diamant-glanz, m. adamantine luster, -kitt, m. diamond cement. -mOrser, m, diamond mortar (small steel mortar), -pulver, n. diamond dust, -schwarz, n. diamond black, -spat, m. adamantine spar (corundum). -Stahl, m, very hard steel, tool steel, Diamido-. diamino-, diamido- (see Amido-), -benzol, n. diaminobenzene, -toluol, n. diaminotoluene. [Pg.102]

Fluor-jod, n. iodine fluoride, -kalium, n. potassium fluoride, -kalzium, n. calcium fluoride, -kiesel, m. silicon fluoride, -kie-selsaure,/. fluosilicic acid, -kohlenstoff, m. carbon fluoride, -lithium, n. lithium fluoride. -metall, n. metallic fluoride, -natrium, n. sodium fluoride, -phosphat, n. fluophosphate. -phosphor, m. phosphorus fluoride, -salz, n. fluoride, -schwefel, m. sulfur fluoride, -selen, n. selenium fluoride, -silber, n. silver fluoride, -silikat, n. fluo-silicate. -silizium, n. silicon fluoride, -sili-ziumverbindung, /. fluosilicate. -tantal-sMure, /. fluotantalic acid, -tellur, n. tellurium fluoride, -titan, n. titanium fluoride, -toluol, n. fluorotoluene, fluotoluene. [Pg.160]

Nitro-toluol, n. nitrotoluene. -verbindung, /. nitro compound, -weinsaure, /. nitrotar-taric acid (tartaric acid dinitrate, also the mononitrate), -zelluloselack, m. nitrocellulose lacquer or dope. [Pg.320]

Rein>toluol, n. pure toluene, -wasser, n. pure water, -weiss, n. pure white, clear white. [Pg.363]

When the German ending -ol does not indicate hydroxyl it should be translated -ole (as, anisole, indole), or in the case of a few hydrocarbons -ene (as. Benzol, benzene Toluol, toluene Styrol, styrene). [Pg.552]

By oxidation in 100 cc of absolute toluol with 425 cc of cyclohexanone and 155 cc of a 20% aluminum isopropylate solution in absolute toluol and after repeated crystallizations from isopropyl ether or methanol, 24 grams of pure 17o-oxyprogesterone-17-caproate is obtained, MP 119° to 121°C (dense needles). [Pg.788]

Dinitro Methyl Anisole (4-Nitro-2-nitromethyl anisole, 3-Nitro-6-methoxynitromethyI toluol. or Methyl-[5-nitro-2-nitromethylphenyl] -ether). CH3.0.(N02)C6H3.CH2N02, mw 212.18, N 13.21%, OB to C02 —113.11%, cryst, mp 93—94°. Prepd from 4-nitro-2(lodomethyl) anisole in ether-ben2ene soln by treatment for 3 days at RT with Ag nitrate. The sodium salt explodes violently on heating Refs 1) Beil, not found 2) G. Bendy,... [Pg.122]

Trinitro Methyl Anisole (4,6-Dinitro-2-nitro-methyl-anisole, 3,5-Dinitro-6-methoxy-nitro-methyl toluol or Methyl-[4,6-dinitro-2-nitro-methyl phenyl]-ether). CH3.0.(N02)2C H2.— CH2N02, mw 257.18, N 16.34%, OB to C02 —77.77%, cryst, mp 65—66°. Prepd from 4-nitro 2-(mtromethyl)anisole by slow addition to a mixt of coned sulfuric-nitric acids (2 1) at 0° (Ref 2). Explodes violently when heated quickly (Ref 2)... [Pg.122]

Isopropyl alcohol (IPA) or benzyl alcohol (toluol) often are used in the formulation (as early components in the order of addition) to dissolve the surfactant-detergent base [e.g., Duomeen OL (Akzo Nobel Chemicals, Inc.) or Triton N101 (Union Carbide Corp.)]. [Pg.686]

Mankann auch in Kohlenwasserstoff-Suspensionarbeiten (s. z. B. S. 207). DasmitzweiMolTHF gebildete Solvat ist in Toluol gut loslich, so dafi 3,5 molare Losungen herstellbar sind. [Pg.26]

Selektive Protonolyse der Dialkyl-[alken-(l)-yl]-aluminium-Verbindungen wird durch Zugabe einer Kohlenwasscrstoff-Losung (z.B. Toluol) von Pentandion-(2,4) bei —30° bis 0° erreicht3 ... [Pg.64]

Methode (4 ) EineLosimg von 0,05 Mol Harnstoff in 100ml abs. Toluol wird unter Riihren zu einer Auf-schlammung von 0,05 Mol Lithiumaianat in 100 ml Dibutylather gegeben. Man kocht 5 Stdn. unter RiickfluB. Die Aufarbeitung geschieht nach Methode (Till, a. werden auf diese Weise erhaiten ... [Pg.136]

Auch mit Natrium-bis-[2-methoxy-athoxy]-dihydrido-aluminat in Benzol oder Toluol bei 80° mit 100%igem Hydrid-UberschuB werden Alkohole erhalten z. B. aus Nonansaure NonanoP (30 Min. 92% d.Th.)3. [Pg.149]

Wahrend iiberschiissiges Natrium-bis-[2-methoxy-athoxy]-dihydrido-aluminat 4-Oxo-pentansaure zu Pentandiol-( 1,4) (67% d.Th. 80°, Toluol) reduziert, erhalt man mit 1,1-Molaquivalenten Reduktionsmittel 4-Pentanolid (57% d.Th. bei —20°, inverse Zu-gabe)1. [Pg.160]

Bei Hydroxy-benzoesauren wird durch trockene Destination des mit Lithiumalanat hcrgestellten Komplexes auch die Hydroxy-Gruppe hydrogenolysiert z. B. (s.a. S. 408f.)1 Salicylsaure zu Toluol ... [Pg.171]

Toluole allgemeine Herstellungsvorschrift Zu 0,2 g ( 1,5 mMol) Benzoesaure werden 1 ml Trifluoressig-saure und 0,5 ml Trifluoressigsaureanhydrid gegeben. Man erwarmt 5-30 Min. bis zur Losung, versetzt mit 1 ml (0,74 g, 6,4 mMol) Triathyl-silan, riihrt 5 Stdn. bei 50-60° und arbeitet wie oben beschrieben auf. [Pg.172]

See also in sourсe #XX -- [ Pg.367 ]

See also in sourсe #XX -- [ Pg.43 ]

See also in sourсe #XX -- [ Pg.96 , Pg.681 ]

See also in sourсe #XX -- [ Pg.223 ]

See also in sourсe #XX -- [ Pg.18 , Pg.50 , Pg.69 ]

See also in sourсe #XX -- [ Pg.367 ]

See also in sourсe #XX -- [ Pg.400 ]

See also in sourсe #XX -- [ Pg.398 ]

See also in sourсe #XX -- [ Pg.311 ]

See also in sourсe #XX -- [ Pg.357 , Pg.358 ]

See also in sourсe #XX -- [ Pg.272 ]

See also in sourсe #XX -- [ Pg.22 ]

Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...