Silicon fluoride SiF

The fibers synthesized suggest that the formation of silicon nitride occur in the gaseous phase. However, SigN is not formed from silicon fluoride (SiF ) as was presumed. It is formed from silicon reduced from (NH4)2SiFg hypothetically as imide Si f(NH)j. or amide Si f(NH2)y. This hypothetical scheme is supported by the fact that the reaction 8.20 gives the fibers, where as the reaction 8.14 does not give ones. If the fibers were formed from SiF, both Equations 8.14 and 8.20 reactions would give the fibers. 

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See also in sourсe #XX -- [ , , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , , ]

See also in sourсe #XX -- [ , , ]

See also in sourсe #XX -- [ , , ]

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