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Thionyl chloride batteries

Table 9. Specifications of cylindrical lithium—thionyl chloride batteries... Table 9. Specifications of cylindrical lithium—thionyl chloride batteries...
An experimental investigation of explosion hazards in lithium-sulfinyl chloride cells on forced discharge showed cathode limited cells are safe, but anode limited cells may explode without warning signs [1]. Extended reversal at -40°C caused explosion on warming to ambient temperature, owing to thermal runaway caused by accelerated corrosion of lithium [2], The violent explosion of a large prismatic cell of a battery is described [3], Another study of explosion mechanisms in lithium/thionyl chloride batteries is reported [4]... [Pg.1754]

Carbon and graphite are often used as supports for electrocatalysts, but they also have an electrocatalytic function in electrode reactions such as oxygen reduction in alkaline electrolytes, chlorine alkali industry, and SOCI2 reduction in lithium-thionyl chloride batteries. [Pg.485]

G. H. Boyle, F. Goebel, Development and Characterization of a High-Capacity Lithium Thionyl Chloride Battery, J. Power Sources 1995, 54, 186-191. [Pg.316]

Catalogue of lithium-thionyl chloride batteries, Toshiba Battery Co., Ltd., 1996. [Pg.60]

Lithium thionyl chloride batteries are not as numerous in production, but the applications are very widespread. This is mainly because of the very high specific energy and energy density of this battery type. Many different designs and form factors are used in the cells. The most... [Pg.1721]

Ca/SOCl2/Ca(AlCl4)2/C batteries that operate in a manner similar to that of lithium-thionyl chloride batteries/ In contrast, it was impossible to develop Mg-SOCl2 batteries because of the very poor charge transfer kinetics of the Mg anode in SOCI2 solutions (poor ion transport through the MgCl2 surface films)/ ... [Pg.130]

Lithium-thionyl-chloride batteries are most attractive for applications for which design objectives include an ultra-wide operating temperature range (from -55 to +150 C), high volumetric energy density, high pulse-power capability, and long shelf life. These batteries are widely used in commercial and consumer electronics, military communications, transportations, RFID, and memory backup. [Pg.222]

The lithium/sulfuryl chloride (Li/S02Cl2) battery is in addition to the lithium/thionyl chloride battery, the other oxychloride that has been used for primary lithium batteries. The Li/S02Cl2 battery has two potential advantages over the Li/SOCl2 battery ... [Pg.375]

A higher rate capability than the thionyl chloride battery as, during the discharge, more SO2 is formed per mole of lithium, leading to a higher conductivity. [Pg.375]

The Li/S02Cl2 battery is similar to the thionyl chloride battery using a lithium anode, a carbon cathode and the electrolyte/depolarizer of LiAlCl4 in SO2CI2. The discharge mech-... [Pg.375]

R. C. McDonald et al., Investigation of Lithium Thionyl Chloride Battery Srifety Hazard, Tech. Rep. N60921-81-C0229, Naval Surface Weapons Center, Silver Spring, Md., Jan. 1983. [Pg.431]

Lithium/Thionyl Chloride Battery. Until recently, spin-dependent batteries were expected to function for short periods of time and only under sustained spin (necessary to keep the electrolyte within the cells). New applications have arisen that require a battery capable of withstanding artUlery fire and spinning for a short time followed by some substantial operating time in a nonspin mode. Such applications include artillery delivery of mines or communication jammers intended to function after impact with the ground, or projectiles and submunitions that are operative while being slowed down by parachute. [Pg.517]

Figure 20.11 is an illustration of a reserve Uthium/thionyl chloride battery using a bipolar plate construction. This battery weighs approximately 5.4 kg and has a volume of 2000 cm. Activation of the reserve battery is accomplished by supplying an electric pulse to the battery by firing an electric squib or actuator or by some mechanical means. This type of reserve battery has been used chiefly in artillery shells for electronic fuze power supplies and in missiles for the electronic power supply. Therefore the electric pulse can be supplied prior to firing or at the time of launch. However, for artillery fiize power supplies, the battery is usually activated by the launch acceleration (set back) and/or the spin forces. The accel-... [Pg.532]

B. Ravid, A Reserve-Type Lithium-Thionyl Chloride Battery, Tadiran Israel Electronics Industries, 1979. [Pg.539]

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See also in sourсe #XX -- [ Pg.135 ]



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