T-Octyl chloride

Figure 11-6. Behavior of octyl chlorides in the four-ball test. 8.52% t-Octyl chloride 2 seconds —A. 10 seconds. 8.48% n-Octyl...

Figure 11-14 shows data obtained by Dorinson [38] in an investigation of the cooperative action of di-t-octyl disulfide and t-octyl chloride, two independently effective lubricant additives. The criteria for evaluation are the initial seizure load in the 10-second ASTM four-ball test and the magnitude and course of the post-seizure wear. With either 2% sulfur or 2% chlorine as the single active additive element in the lubricant, the post-seizure transition occurs in the load interval 80-100 kg, and the degree of seizure, as judged by the extent of wear, is not severe. With a combination of 1% sulfur and 1% chlorine in the... 

Figure 11-14. Cooperative additive action of t-octyl chloride and di-t-octyl disulfide. Four-ball test 10 seconds at 1750 rpm. Additives in white oil and wear/load index A. 9.1% Di-t-octyl disulfide, 2.08% S 48.0 kg. B. 8.52% t-Octyl chloride, 2.05% Cl 51.9 kg. C. 4.55% Di-t-octyl disulfide + 4.53% t-octyl chloride, 1.06% S, 1.00% Cl 81.0 kg. D. 9.1% Di-t-octyl disulfide + 8.52% t-octyl chloride, 2.1% S, 2.0% Cl 112.1 kg. Data by A. Dorinson [38].

Peroxyesters. Peroxyesters, such as -butyl peroxybenzoate and t-octyl peroxyester, are made from the reaction of an alkyl hydroperoxide, such as -butyl hydroperoxide, with an acid chloride. 

The rate constants for the solvolysis of chloromethyl ethyl ether, chloromethyl octyl ether, and chloromethyl methyl sulfide have been determined in several pure and binary solvents. Application of the extended Grunwald-Winstein equation, logffe/fe, ) = /Nj + mY + c, gave appreciable T values (0.55-0.71) for the three substrates indicating that there is significant nucleophilic solvation of the developing carbenium ion in the transition states of these reactions. The kQ lkp = 1.2 x 10 found for the hydrolysis of chloromethyl methyl ether in water is virtually identical to that observed for the uni-molecular solvolyses of t-butyl chloride and trityl halides confirming the unimolecular mechanism for these reactions. 

BRN 1912585, see Hexachlorobenzene BRN 1912384, see 2,4-Dinitrotoluene BRN 1913355, seep,p -DDE BRN 1914064, see Di-fl-butyl phthalate BRN 1914072, see p,p -DDD BRN 1915474, see Chlordane BRN 1915994, see Di-fl-octyl phthalate BRN 2049930, see Naled BRN 2051258, see Pindone BRN 2052046, see 2,6-Dinitrotoluene BRN 2054389, see 4,6-Dinitro-o-cresol BRN 2055620, see 2,4,5-T BRN 2057367, see Methoxychlor BRN 2059093, see Parathion BRN 2062204, see Benzyl butyl phthalate BRN 2215168, see Diuron BRN 2542580, see EPN BRN 2807677, see 2-Acetylaminofluorene BRN 3195880, see a-BHC BRN 3196099, see Camphor BRN 3910347, see cis-Chlordane, frans-Chlordane Brocide, see 1,2-Dichloroethane Brodan, see Chlorpyrifos Bromchlophos, see Naled Bromex, see Naled Bromic ether, see Ethyl bromide Bromobenzol, see bromobenzene 4-Bromobiphenyl ether, see 4-Bromophenyl phenyl ether 4-Bromodiphenyl ether, see 4-Bromophenyl phenyl ether p-Bromodiphenyl ether, see 4-Bromophenyl phenyl ether Bromoethane, see Ethyl bromide Bromofluoroform, see Bromotrifluoromethane Bromofume, see Ethylene dibromide Brom-o-gaz, see Methyl bromide Bromomethane, see Methyl bromide Bromomethyl chloride, see Bromochloromethane... 

The thermodynamic properties at T = 298.15 K shown in Figure 18.11 come from S. Causi, R. De Lisi, and S. Milioto, Thermodynamic properties of N-octyl-, N-decyl- and N-dodecylpyridinium chlorides in water , J. Solution Chem., 20, 1031-1058 (1991). Results at the other two temperatures are courtesy of K. Ballerat-Busserolles, C. Bizzo, L. Pezzimi, K. Sullivan, and E. M. Woolley, Apparent molar volumes and heat capacities at aqueous n-dodecyclpyridium chloride at molalities from 0.003 molkg-1 to 0.15 molkg-1, at temperatures from 283.15 K. to 393.15 K, and at the pressure 0.35 MPa , J. Chem. Thermodyn., 30, 971-983 (1998). 

FIGURE 31.17 Schemes of the highly selective ligand for uranium recovery from seawater, (a) The hexacarboxylate Ugand (b) after reaction with tri-octyl methyl ammonium chloride. (Reproduced from Tabushi, I., Kobuke, Y., Nakayama, N., Aoki, T., and Yashizawa, A., Ind. Eng. Chem. Prod. Res. Dev., 23, 445, 1984. With permission.)... 

Letcher T M, Deenadayalu N. Ternary liquid-liquid equilibria for mixtures of 1-methyl-3-octyl-imidazolium chloride + benzene + an alkane at T = 298.2 K and 1 atm. J. Chem. Thermodynamics. 2003. 35, 67-76. 

Manuf./Distrib. Aristech http //WWW. aristechchem. com, I nolex http //www.inolex. com Trade Name Synonyms Plasthall 8-10 TM-E [C.P. Hall http //www.cphall.com], Staflex NONDTM t[C.P. Hall http //www.cphall.com] Octyidecyl trimonium chloride Synonyms Decanaminium, 2-octyl-N,N,N-trimethyl-, chloride Uses Antistat in cosmetics... 

Pelemol ODSS [Phoenix http //www.phoenix-chem.com], Protachem OSS t[Protameen http //www.protameen.com], Trivent SS-20 [Trivent S. Black http //www.sblack.com] Octyidodecyltrimonium chloride Synonyms 1-Dodecanaminium, 2-octyl-N,N,N-trimethyl-, chloride... 

Naphtha a-Naphthylamine Natural rubber latex Neopentyl glycol dibenzoate Nitric acid Nitrocellulose 2-Nitropropane Nonoxynol-2 Nonoxynol-4 Nonoxynol-5 Nonoxynol-6 Nonoxynol-7 Nonoxynol-8 Nonoxynol-13 Nonoxynol-14 Nonoxynol-15 Nonoxynol-18 Nonoxynol-20 Nonoxynol-23 Nonoxynol-30 Nonoxynol-40 Nonoxynol-6 phosphate Nonoxynol-9 phosphate Octadecyl 3,5-di-t-butyl-4-hydroxyhydrocinnamate Octoxynol Octoxynol-1 Octoxynol-3 Octoxynol-5 Octoxynol-6 Octoxynol-7 Octoxynol-8 Octoxynol-9 Octoxynol-10 Octoxynol-11 Octoxynol-12 Octoxynol-13 Octoxynol-16 Octoxynol-20 Octoxynol-25 Octoxynol-30 Octoxynol-33 Octoxynol-40 n-Octyl n-decyl phthalate Octyl phenol Olealkonium chloride Oieamide Oieamide DEA Oieic acid Oleth-20 Olive (Olea europaea) oii... 

Methyl acrylate Acrylonitrile Methyl methacrylate Vinyl acetate Vinyl stearate Vinyl pelargonate Vinyl acetate Methyl methacrylate n-Butyl methacrylate n-Octyl methacrylate Methyl acrylate n-Butyl acrylate n-Octyl acrylate Vinyl chloride Vinyl bromide Vinyl iodide T etrachloroethy lene Maleic anhydride Maleic anhydride... 

N. Goujon, N. Byrne, T.R. Walsh, M. Forsyth, The influence of water and metal salt on the transport and structural properties of l-octyl-3-methyhmidazolium chloride, Aust. J. Chem. 68 (3) (2015) 420—425. 

Donnan equilibrium of the system allows Pb(II) and Cd(II) chloride complexes to be concentrated in the aqueous receiving phase. To enhance permeation selectivity and efficiency, a novel polymeric plasticizer membrane, which is composed of cellulose triacetate polymer as a membrane support, t>-nitrophenyl octyl ether as a membrane plasticizer and trioctylmethylammonium chloride as an anion-exchange carrier, has been developed. This type of membrane exhibited a superior separation selectivity and efficiency to the conventional anion-exchange membranes. 

Letcher, T. M Deenadayalu, N. (2003). Ternary Liquid-Liquid Equilibria for Mbdures of 1-Methyl-3-Octyl-Imidazolium Chloride Plus Benzene Plus an Alkane at T-298.2 K and 1 Atm. Jourrud of Chemical Thermodynamics, Vol. 35, No. 1, p>p. 67-76, ISSN 0021-%14 Li, C. R, Xin, B. P., Xu, W. G. Zhang, Q. (2007). Study on the Extraction of Dyes into a Room-Temperature Ionic Liquid and their Mechanisms. Jourrud of Chemical Technology and Biotechnology, Vol. 82, No. 2, pp. 196-204, ISSN 0268-2575... 

Chen L, Zhou T, Chen L, et al. Selective oxidation of cyclohexanol to cyclohexanone in the ionic liquid l-octyl-3-methylimidazolium chloride. Chem Commun. 2011 47 9354-9356. 

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