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Surfacing, definition

There are, of course, limits to the studies possible within the framework of surface reactivity. These limits are imposed largely by the sensitivities of the techniques employed, though in some cases the limitations do arise from a lack of surface definition. It is impossible to prepare a surface totally free of contaminants or undesired defects such as step edges or kinks. Therefore, since one of the major objectives of studies with single crystals is to associate reactivity with specific structural and compositional features of the surface, reaction events that occur in numbers close to the limiting defect or impurity concentrations must be viewed with suspicion and very care-... [Pg.2]

Charging Hydroxylated Surfaces Definition of IEP(s). A hydroxyl-ated surface should be expected on all oxidic materials which have had a chance to come to equilibrium with an aqueous environment. Charge can develop on a hydroxylated surface through amphoteric dissociation of the surface hydroxide groups. Dissociation reactions can be written as follows, where underscored symbols refer to species forming part of the surface. Symbols not underscored refer to species assumed aqueous unless otherwise specified. [Pg.131]

A. The Use of HRTEM and Scanning Electron Microscopy to Investigate the Morphology of Oxides and Chlorides Comparison of the Surface Definition of Dispersed Materials, Films, and Single Crystals... [Pg.274]

The last two paragraphs show that, although the thermal agitation of water molecules is so violent that they jump in and out of the surface very rapidly, yet the attractive forces between them are able to maintain the surface definite within one or two molecules thickness. This is a most remarkable result of molecular theory. [Pg.7]

Wettability of a solid surface definition and assessment The concept of wettability of a solid by a liquid is directly related to the wetting processes. This concept is specially useful in the fields of detergency, lubrication or enhanced oil recovery. In the context of the oil industry, proposals were made by Briant and Cuiec (1972) for the experimental assessment of wettability, which was defined in terms of the thermodynamic affinity of a solid surface for a liquid. [Pg.126]

This alternative is quite attractive from another standpoint. If the generation of an active site is the slow step in certain chemisorption processes, what is the nature of this site generation An answer must be found in the chemistry of the solid state so that an inquiry into the detailed kinetics of adsorption rejoins a current active trend in catalytic research. While interesting models involving the electronic behavior of adsorbents and catalysts have been proposed during the last ten years, none can be considered as definitely proved and progress has been slow because of the usual experimental difficulties in surface definition and reproducibility. [Pg.415]

Liimited quality of surface definition and. product must be finished (deburred, etc.) after blowing. [Pg.9]

Equations 12.39, 12.35, and 12.40 form a coupled system of equations describing the surface function S, charge concentrations Pa, and electrostatic potential. This coupled system differs from the original PNP equations through the coupling of the surface definition are to charge concentrations and electrostatics. We call this DG-based system the "Laplace-Beltrami Poisson-Nernst-Planck" (LB-PNP) model. [Pg.440]

During cloudy weather a condition known as white-out may occur when surface definition deteriorates because of the absence of shadows and because the horizon disappears. These conditions are dangerous because they can lead to accidents that result from poor visibility and associated disorientation. Whiteout conditions in Fig. 2.4 can also occur during dense fog and may be caused by ground blizzards when strong katabatic winds inject snow into the air. Travel on the polar platean and in the mountains is not indicated under whiteont conditions. [Pg.45]

Fig. 2.4 During whiteout conditions in the Transantarctic Mountains the horizon becomes invisible and surface definition is lost. In the case shown here, the whiteout conditions resulted from high wind associated with snowfall near the coast of northern Victoria Land. The Scott tent, strU used by geological fieldpar-ties in the Transantarctic Mountains and on the polar plateau, is well suited for use in cold and windy weather, especially when it is set up in well-packed snow or neve. Mills Valley, Pain Mesa, northern Victoria Land, December 1982 (Photo by G. Faure)... Fig. 2.4 During whiteout conditions in the Transantarctic Mountains the horizon becomes invisible and surface definition is lost. In the case shown here, the whiteout conditions resulted from high wind associated with snowfall near the coast of northern Victoria Land. The Scott tent, strU used by geological fieldpar-ties in the Transantarctic Mountains and on the polar plateau, is well suited for use in cold and windy weather, especially when it is set up in well-packed snow or neve. Mills Valley, Pain Mesa, northern Victoria Land, December 1982 (Photo by G. Faure)...
Wire frames with unified topology and geometry use the same entities as solid models but without face and surface definitions. Note that these wire frames are not the same representations as the wire frames in the early era of geometric modeling. When a wireframe model defines a shape unambiguously, a surface or solid model can be replaced by the simple wire frame for economical modeling. If necessary, a verified wire frame can be completed into a surface or solid. [Pg.287]

One may use different types of molecular cavities and surfaces definitions (e.g. equipotential surfaces, equidensity surfaces, van der Waals surfaces). Among them there is a subset that shares a common trait they consider that a molecule may be represented as a set of rigid interlocking spheres. There are three such surfaces a)... [Pg.23]


See other pages where Surfacing, definition is mentioned: [Pg.593]    [Pg.18]    [Pg.219]    [Pg.168]    [Pg.59]    [Pg.427]    [Pg.266]    [Pg.117]    [Pg.473]    [Pg.93]    [Pg.38]    [Pg.8]    [Pg.388]    [Pg.85]    [Pg.368]    [Pg.370]    [Pg.112]    [Pg.177]    [Pg.426]    [Pg.277]   
See also in sourсe #XX -- [ Pg.253 ]




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