Surface treating

Hebard A F, Zhou O, Zhong Q, Fleming R M and Fladdon R C 1995 Cgq films on surface-treated silicon recipes for amorphous and crystalline growth Thin Soiid Fiims 257 147-53... 

An important newer use of fluorine is in the preparation of a polymer surface for adhesives (qv) or coatings (qv). In this apphcation the surfaces of a variety of polymers, eg, EPDM mbber, polyethylene—vinyl acetate foams, and mbber tine scrap, that are difficult or impossible to prepare by other methods are easily and quickly treated. Fluorine surface preparation, unlike wet-chemical surface treatment, does not generate large amounts of hazardous wastes and has been demonstrated to be much more effective than plasma or corona surface treatments. Figure 5 details the commercially available equipment for surface treating plastic components. Equipment to continuously treat fabrics, films, sheet foams, and other web materials is also available. 

Fig. 5. Equipment foi surface treating plastic components. Parts ate loaded into one of the two lower chambers which is then evacuated to remove most of the air. This chamber is then flooded with a dilute mixture of fluorine and nitrogen which is made and stored in the upper chamber. After the treatment is completed, the fluorine mixture is pumped back up to the upper chamber for storage and the lower chamber repeatedly flooded with air and evacuated to remove any traces of fluorine gas. Two treatment chambers are cycled between the loading/unloading operation and the treatment step to increase equipment output. The fluorine—nitrogen blend may be used several times before by-products from the treatment process begin to interfere. AH waste...

Pigments are available ia a number of commercial forms including dry powders (either surface treated or untreated), presscakes, flushed colors (thick pastes), fluidi2ed dispersions (pourable pastes), resia predispersed pigments (powders), and plastic color concentrates or master batches (granules) (see PiGLffiNTDISPERSIONS). 

The next advance in total hip arthroplasty came with the development of various porous surface treatments which allow bone tissue to grow into the metal porous coating on the femoral stem of the hip implant and on the acetabular component of the total joint replacement. These developments arose because of patients who were not able to tolerate cemented implants because of allergies to the cement, methylmethacrylate. More youthflil patients are better served by a press-fit implant as well. Figure 12 shows the difference between textured and beaded surface-treated orthopedic prostheses. 

Liquid Crystals. In liquid crystal displays, clarity and permanence of image is enhanced if the display can be oriented parallel or perpendicular to the substrate. Oxide surfaces treated with dimethyloctadecy1-3-trimethoxysi1y1propy1 ammonium chloride [27668-52-6] ... 

Cjg H37 (CH3 )2CH2CH2CH2Si(OCH3 )3C1 , tend to orient Hquid crystals perpendicular to the surface (see Liquid crystalline materials) parallel orientation is obtained on surfaces treated with /V-methy1aminopropy1trimethoxysi1ane [3069-25-8] CH2NHCH2CH2CH2Si(OCH2)3 (25). 

Substitution of some of the alkoxy groups on the polytitanoxanes with glycols, P-diketones or P-ketoesters, fatty acids, diester phosphates or pyrophosphates, and sulfonic acids gives a group of products that are very effective surface-treating agents for carbon black, graphite, or fibers (32). 

Reaction of TYZOR TPT with polyperfluoroalkylene ethers containing a carbonyl group produces a complex that is an excellent surface-treating agent, imparting improved surface wettabiUty and anticorrosion properties to metal surfaces (144). These complexes can be used by themselves, or as additives to perfluoropolyethers as vacuum pump oils, lubricant oils, or mold release agents. 

Inks. Refined kaolin is a common ingredient in a large variety of printing inks (qv). In addition to extending the more expensive polymers present, ka olin also contributes to improved color strength, limits the penetration of the ink into the paper, controls rheology, and improves adhesion. Kaolin for this appHcation must usually be as white as possible and free from oversize particles. Surface treated clays are used to improve compatibiHty with oil-based ink. Clays can also be an ingredient in the newer water-based or uv-cured inks. 

Clays vary in price from only a few doUars per ton for common clay to > 0.25/kg for some of the specialty surface treated clays. For clays that are used in large quantities such as kaolins for paper coatings, transportation to the point of use may be the primary cost component. 

Microstructural examinations revealed branched, transgranular cracks originating on the external surface (treated cooling water). Analysis of material covering the crack surfaces revealed the presence of chlorine. 

If corona, plasma, or flame treatment is chosen as the surface treatment, it is important to bond quickly after the treatment. Waiting several hours will reduce the effectiveness of the treatment. In some cases, attempts to bond 24 h after the treatment can give the same poor bonding results as if the plastic had never been surface treated. If surface oxidation is not possible, priming the surface with a chlorinated polyethylene primer is a second choice [95]. 

Figure 14 shows the ATR spectrum of the etched polyethylene surface treated with a chronic acid group [76]. Absorption bands due to surface treatment appear at 3300, 1700, 1260, 1215, and 1050 cm". The band at 3300 cm represents the absorption due to the hydroxyl group and that at 1700 cm " is due to the carbonyl group. The bands at 1260, 1215, and 1050 cm are all due to the alkyl sulfonate group. 

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