Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Surface lattice sites

The formation or dissolution of a new phase during an electrode reaction such as metal deposition, anodic oxide formation, precipitation of an insoluble salt, etc. involves surface processes other than charge transfer. For example, the incorporation of a deposited metal atom (adatom [146]) into a stable surface lattice site introduces extra hindrance to the flow of electric charge at the electrode—solution interface and therefore the kinetics of these electrocrystallization processes are important in the overall electrode kinetics. For a detailed discussion of this subject, refs. 147—150 are recommended. [Pg.73]

The dissociative adsorption of water proceeds on a surface M-O pair with the formation of two neighboring OH groups on the surface. It was assumed that the energy of the reversible dissociative adsorption of water depends on the chemical environment of the corresponding surface lattice sites... [Pg.510]

M" + S -1- ze - S.M (S = surface lattice sites) 6 = 2-dimensional site occupancy fraction... [Pg.490]

A recent alternative approach is the use of diacetylene-containing alkylthiol monomer units that, when attached to metals via the thiolate bond, form planar arrays that are photopolymerized [20-22]. Sueh a strategy, shown in Fig. 1, eombines the advantages of SAM formation with the improvements of a more robust polymer end-product. Previous work with L-B films of diacetylenic amphiphiles has demonstrated in-plane requirements for topo-ehemie-ally controlled polymerization [23]. Templating of the diacetylene topochemistry via the thiol docking to metal surface lattice sites spaced according to the metal... [Pg.250]

Face-centered cubic crystals of rare gases are a useful model system due to the simplicity of their interactions. Lattice sites are occupied by atoms interacting via a simple van der Waals potential with no orientation effects. The principal problem is to calculate the net energy of interaction across a plane, such as the one indicated by the dotted line in Fig. VII-4. In other words, as was the case with diamond, the surface energy at 0 K is essentially the excess potential energy of the molecules near the surface. [Pg.264]

Diffraction is not limited to periodic structures [1]. Non-periodic imperfections such as defects or vibrations, as well as sample-size or domain effects, are inevitable in practice but do not cause much difSculty or can be taken into account when studying the ordered part of a structure. Some other forms of disorder can also be handled quite well in their own right, such as lattice-gas disorder in which a given site in the unit cell is randomly occupied with less than 100% probability. At surfaces, lattice-gas disorder is very connnon when atoms or molecules are adsorbed on a substrate. The local adsorption structure in the given site can be studied in detail. [Pg.1752]

Materials that contain defects and impurities can exhibit some of the most scientifically interesting and economically important phenomena known. The nature of disorder in solids is a vast subject and so our discussion will necessarily be limited. The smallest degree of disorder that can be introduced into a perfect crystal is a point defect. Three common types of point defect are vacancies, interstitials and substitutionals. Vacancies form when an atom is missing from its expected lattice site. A common example is the Schottky defect, which is typically formed when one cation and one anion are removed from fhe bulk and placed on the surface. Schottky defects are common in the alkali halides. Interstitials are due to the presence of an atom in a location that is usually unoccupied. A... [Pg.638]

Examination of these and other results indicates that the value of a for a given adsorptive which needs to be used in order to arrive at a value of specific surface consistent with that from nitrogen adsorption, varies according to the nature of the adsorbent. The existence of these variations shows that the conventional picture, in which the value of a corresponds to a monolayer which is completely filled with adsorbate molecules in a liquidlike packing, is over-simplified. Two factors can upset the simple picture (a) there may be a tendency for adsorbed molecules to become localized on lattice sites, or on more active parts of the solid surface and (b) the process... [Pg.68]

A MC study of adsorption of living polymers [28] at hard walls has been carried out in a grand canonical ensemble for semiflexible o- 0 polymer chains and adsorbing interaction e < 0 at the walls of a box of size C. A number of thermodynamic quantities, such as internal energy (per lattice site) U, bulk density (f), surface coverage (the fraction of the wall that is directly covered with segments) 9, specific heat C = C /[k T ]) U ) — U) ), bulk isothermal compressibility... [Pg.532]

At a given ideal composition, two or more types of defects are always present in every compound. The dominant combinations of defects depend on the type of material. The most prominent examples are named after Frenkel and Schottky. Ions or atoms leave their regular lattice sites and are displaced to an interstitial site or move to the surface simultaneously with other ions or atoms, respectively, in order to balance the charge and local composition. Silver halides show dominant Frenkel disorder, whereas alkali halides show mostly Schottky defects. [Pg.529]

The main idea of a lattice model is to assume that atomic or molecular entities constituting the system occupy well-defined lattice sites in space. This method is sometimes employed in simulations with the grand canonical ensemble for the simulation of surface electrochemical proceses. The Hamiltonians H of the lattice gas for one and two adsorbed species from which the ttansition probabilities 11 can be calculated have been discussed by Brown et al. (1999). We discuss in some detail MC lattice model simulations applied to the electrochemical double layer and electrochemical formation and growth two-dimensional phases not addressed in the latter review. MC lattice models have also been applied recently to the study the electrox-idation of CO on metals and alloys (Koper et al., 1999), but for reasons of space we do not discuss this topic here. [Pg.673]

The most powerful approach, at least in principle, is the measurement of the rate of the desired reaction as a function of potential and reagent concentration. In essence, any reaction can be written as a set of consecutive steps this is true even if the reaction is apparently a simple process such as the electrolyte deposition of a monovalent cation such as Ag +, since loss of water of hydration from the cation and the (possibly assisted) transport of atoms over the surface to appropriate lattice sites are clearly consecutive processes. [Pg.31]

Producing a reasonably good accuracy for analytically defined surfaces, this scheme of calculation is very inaccurate when the field is specified by the discrete set of values (the lattice scalar field). The surface in this case is located between the lattice sites of different signs. The first, second, and mixed derivatives can be evaluated numerically by using some finite difference schemes, which normally results in poor accuracy for discrete lattices. In addition, the triangulation of the surface is necessary in order to compute the integral in Eq. (8) or calculate the total surface area S. That makes this method very inefficient on a lattice in comparison to the other methods. [Pg.221]


See other pages where Surface lattice sites is mentioned: [Pg.74]    [Pg.301]    [Pg.252]    [Pg.17]    [Pg.19]    [Pg.61]    [Pg.133]    [Pg.139]    [Pg.468]    [Pg.74]    [Pg.301]    [Pg.252]    [Pg.17]    [Pg.19]    [Pg.61]    [Pg.133]    [Pg.139]    [Pg.468]    [Pg.269]    [Pg.284]    [Pg.298]    [Pg.309]    [Pg.382]    [Pg.33]    [Pg.511]    [Pg.169]    [Pg.269]    [Pg.697]    [Pg.700]    [Pg.295]    [Pg.71]    [Pg.221]    [Pg.225]    [Pg.226]    [Pg.108]    [Pg.172]    [Pg.42]    [Pg.224]    [Pg.235]    [Pg.81]    [Pg.83]    [Pg.45]    [Pg.33]    [Pg.237]   
See also in sourсe #XX -- [ Pg.17 ]




SEARCH



Lattice sites

Surface lattice

Surface sites

© 2024 chempedia.info