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Surface-enhanced hyper-Raman

Yang W H, Hulteen J 0, Schatz G G and Van Duyne R P 1996 A surface-enhanced hyper-Raman and surface-enhanced Raman scattering study of trans-1,2-bis(4-pyridyl)ethylene adsorbed onto silver film over nanosphere electrodes. Vibrational assignments experiments and theory J. Chem. Phys. 104 4313-26... [Pg.1228]

Kneipp K, Kneipp H and Seifert F 1994 Near-infrared excitation profile study of surface-enhanced hyper-Raman scattering and surface-enhanced Raman scattering by means of tunable mode-locked... [Pg.1231]

Yu N-T, Nie S and Lipscomb L 1990 Surface-enhanced hyper-Raman spectrosocpy with a picosecond laser. New vibrational information for non-centrosymmetric carbocyanine molecules adsorbed on colloidal silver J. Raman Spectrosc. 21 797-802... [Pg.1232]

Kneipp, J., Kneipp, H. and Kneipp, K (2006) Two-photon vibrational spectroscopy for hiosdences based on surface-enhanced hyper-Raman scattering. Proc. Natl. Acad. Sci. U.S.A., 103, 17149-17153. [Pg.98]

Golab J.T., Sprague J.R., Carron K.T., Schatz G.C., Vanduyne R.P., A surface enhanced hyper-Raman scattering study of pyridine adsorbed onto silver - experiment and theory, J. Chem. Phys. 1988 88 7942-7951. [Pg.254]

Ziegler et al. (1989, 1990) have recently reviewed hyper Raman. spectroscopic studies including hyper Raman scattering in liquids and crystals, surface enhanced hyper Raman scattering (Golab et al., 1988) as well as the vibronic and rotational theory for resonance enhanced hyper Raman scattering. [Pg.500]

Since the HRS scattering cross section is so small, enhancement of the signal intensity is indispensable for a practical use of the HRS technique in the field of molecular science. As already mentioned, one of the methods for signal enhancement is to use plasmonic resonances of metal nanostructures [20, 21, 25]. This enhancement technique is called surface-enhanced hyper-Raman scattering (SEHRS) because it is similar to that of surface-enhanced Raman scattering (SERS). In SERS or SEHRS, both excitation absorption and scattered emission benefit from plasmonic field enhancement. Therefore, the plasmonic enhancement factor M is described as... [Pg.105]

Itoh T, Yoshikawa H, Yoshida K, Biju Y, Ishikawa M (2009) Evaluation of electromagnetic enhancement of surface enhanced hyper Raman scattering using plasmonic properties of binary active sites in single Ag nanoaggregates. J Chem Phys 130 214706... [Pg.116]

Hulteen, J.C., Young, M.A., and Van Duyne, R.P. (2006) Surface-enhanced hyper-Raman scattering (SEHRS) on Ag film over nanosphere (EON) electrodes surface symmetry of centrosymmetric adsorbates. Langmuir, 22, 10354-10364. [Pg.325]

Surface Enhanced Hyper-Raman Spectroscopy (SEHRS)... [Pg.123]

Instrumentation. Instmmentation in the reported investigations is similar to that employed in SERS [497]. A powerful laser system is employed. In a study of pyrazine and pyridine adsorbed on a roughened silver electrode, it was observed, that spectra measured with adsorbed centrosymmetric pyrazine showed additional bands that were not observed with SERS [497]. With the non-centrosymmetric pyridine, the SEHR spectra were very similar to the respective SER spectra no new bands were found. Surface enhanced hyper-Raman spectra were found to be more sensitive (than SERS) towards interaction between the adsorbate and the surface. This is illustrated in vibrational spectra of bis(4-pyridine)acetylene (BPA) adsorbed on a silver electrode [497]. [Pg.123]

SEHRS Surface enhanced hyper-Raman spectroscopy scattering... [Pg.318]

Surface Enhanced Hyper-Raman Spectroscopy (SEHRS) Hyper-Raman scattering is a nonlinear three-photon energy conversion process, that offers complementary informahon to Raman spectroscopy and has some advantages... [Pg.655]

S. Nie, L.A. Lipscomb, N.T. Yu, Surface-enhanced hyper-Raman spectroscopy. Appl. Spec-trosc. Rev. 26, 203 (1991)... [Pg.696]

W. H. Li, X. Y. Li and N. T. Yu, Surface-enhanced hyper-Raman scattering and surface-enhanced Raman... [Pg.96]


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