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Subject rock salt

The 3(f ions Cr2+ and Mn3+ and the 3d9 ion Cu2+ are subject to Jahn-Teller distortions. For example, CuO does not have the rock salt structure, but one with four close Cu 0 neighbours and two at longer distance similar tetragonally distorted coordination is found in most other simple compounds of Cr2+ and Cu2+. (Note that CrO is unknown). [Pg.91]

The interaction of metal atoms, clusters and layers with the MgO surface has been the subject of a large number of experimental and theoretical studies. In particular, the training playground for theoretical studies has often been the interaction of isolated metal atoms with regular simple surfaces, amongst which, the simplest is MgO(OOl). MgO has a rock-salt structure and the (001) face shows a motive of square structures where the ions are only at the corners and Mg and O atoms are alternated. The same structure is alternated and repeated in the perpendicular direction (Fig. 2.1). Due to... [Pg.48]

The (100) face of MgO crystals has been the subject of many studies and is energetically the most stable face in rock salt crystals (Coluccia et al., 1979 Colburn and Mackrodt, 1983 Moodie and Warble, 1971). The reason for its stability is that it is electroneutral (nonpolar), containing equal numbers of cations and anions. MgO cleaves extremely well along the (100) plane, yielding a relatively flat and defect-free surface. The anions and cations on the (100) surface are pentacoordinated, four in the surface plane and one directly below in the second atomic plane. The missing bond lies directly above the surface ion. [Pg.129]

Sodium chloride occurs naturally as the mineral halite, commonly called rock salt, in large underground deposits on every continent. Seawater contains about 3.5 percent dissolved minerals, of which 2.8 percent is sodium chloride and the other 0.7 percent is primarily calcium, magnesium, and sulfate ions. Natural brines, or salty waters other than seawater, are foxmd in wells and lakes, such as the Great Salt Lake of Utah and the Dead Sea. Salt is also found in surface deposits in regions subject to arid climates. [Pg.1128]

If the rock-salt crystal is being subjected to a hydrostatic stress, i.e., directions, the force / acting on a single bond is given by f=cral. If... [Pg.72]

Salt mining is a large-scale specialized activity. Few chlorine producers mine salt or have much control over the process. Section 7.1.2 therefore gives only a brief review of the subject of mechanical mining of rock salt. Solar salt production, on the other hand, is closely tied to chlorine plants in some parts of the world. A fuller description of its production seems appropriate and appears in Section 7.1.3. [Pg.466]

Over the next one hundred years the essential nature of IR radiation was slowly established, electrical methods of measurement were developed and a number of materials such as rock salt were found to be largely transparent to it and thus useful as refracting elements. Interest was mainly directed to the physics of the subject, with little attention given to any possibilities for application to chemistry. [Pg.1252]

Bodies of Water and the Chemical Sediments ,— The chemistry of the deposition of salts from sea-water has already been made the subject of special research, and van t Hoff s results in this field are already familiar. The deposition of calcium carbonate awaits a similar thorough study. Allied questions are the formation of dolomite, the deposition of various salts from inclosed bodies of water, the deposition of phosphate rocks, the precipitation of colloidal suspensions of clay and other substances, and the origin of the great deposits of sedimentary iron ore. [Pg.6]

Before leaving the subject of alkali we must note that electrolytic methods of manufacture form an increasingly important branch of the industry. Solutions of common salt are electrolysed in a. special vessel, of which the Castner rocking cell is a type,... [Pg.32]

Typical soils exhibiting distinctive layers with increasing depth are called horizons (Fig. 9.7). The top layer, normally several centimetres in thickness, is known as the A horizon, or topsoil. This is the layer of maximum biological activity in the soil and it contains most of the soil organic matter. Metal ions and clay particles in the A horizon are subject to considerable leaching. The next layer is the B horizon, or subsoil. It receives material such as organic matter, salts, and clay particles leached from the topsoil. The C horizon is composed of weathered parent rocks from which the soil originated [1]. [Pg.810]


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