Stripped organic phase

Stage is included to control the level of iron build-up on the organic phase. Amine circuits also often require a regeneration circuit to protonate the extractant ahead of the extraction process. Other amine circuits may use a strong caustic wash to remove very strongly bound impurity species from the stripped organic phase to avoid loss of capacity on recycle of the organic to the extraction circuit. 

Another solvent extraction scheme uses the mixed anhydrous chlorides from a chlorination process as the feed (28). The chlorides, which are mostly of niobium, tantalum, and iron, are dissolved in an organic phase and are extracted with 12 Ai hydrochloric acid. The best separation occurs from a mixture of MIBK and diisobutyl ketone (DIBK). The tantalum transfers to the hydrochloric acid leaving the niobium and iron, the DIBK enhancing the separation factor in the organic phase. Niobium and iron are stripped with hot 14—20 wt % H2SO4 which is boiled to precipitate niobic acid, leaving the iron in solution. 

The distribution of highly extractable solutes such as and Pu between the aqueous and organic phases is strongly dependent upon the nitrate anion concentration in the aqueous phase. This salting effect permits extraction or reextraction (stripping) of the solute by controlling the nitric acid concentration in the aqueous phase. The distribution coefficient, D, of the solute is expressed as... 

In the uranium-stripping step, a dilute HNO solution is used to remove uranium from the organic phase. The aqueous effluent containing the... 

The purified acid is recovered from the loaded organic stream by contacting with water in another countercurrent extraction step. In place of water, an aqueous alkafl can be used to recover a purified phosphate salt solution. A small portion of the purified acid is typically used in a backwashing operation to contact the loaded organic phase and to improve the purity of the extract phase prior to recovery of the purified acid. Depending on the miscibility of the solvent with the acid, the purified acid and the raffinate may be stripped of residual solvent which is recycled to the extraction loop. The purified acid can be treated for removal of residual organic impurities, stripped of fluoride to low (10 ppm) levels, and concentrated to the desired P2 s Many variations of this basic scheme have been developed to improve the extraction of phosphate and rejection of impurities to the raffinate stream, and numerous patents have been granted on solvent extraction processes. 

The principle of solvent extraction in refining is as follows when a dilute aqueous metal solution is contacted with a suitable extractant, often an amine or oxime, dissolved in a water-immiscible organic solvent, the metal ion is complexed by the extractant and becomes preferentially soluble in the organic phase. The organic and aqueous phases are then separated. By adding another aqueous component, the metal ions can be stripped back into the aqueous phase and hence recovered. Upon the identification of suitable extractants, and using a multistage process, solvent extraction can be used to extract individual metals from a mixture. 

The loaded organic phase is stripped of beryUium using an aqueous ammonium carbonate [506-87-6] solution, apparently as a highly soluble ammonium beryUium carbonate [65997-36-6] complex, (NH 4Be(C02)3. AU of the iron [7439-89-6] contained in the leach solution is coextracted with the beryUium. Heating the strip solution to about 70°C separates the iron and a smaU amount of coextracted aluminum as hydroxide or basic carbonate... 

This particular difference in the Lewis acidity of tantalum and niobium complexes provides the possibility of an effective separation between the elements using liquid-liquid extraction. It is obvious that tantalum will extract into the organic phase at a lower acidity of the aqueous solution, whereas niobium will require a higher level of acidity in order to be extracted. The stripping of the elements from the organic phase into the aqueous phase will take place in reverse order. 

The stripping of tantalum and niobium from the organic phase into aqueous media occurs in solutions with low acidity levels, leading to the formation of TaF 2 and NbOFs2, which have a lower charge and weaker Lewis acidity. 

Two main schemes exist for the separation and purification of tantalum and niobium using liquid-liquid extraction. The first is based on the collective extraction of tantalum and niobium from an initial solution into an organic phase so as to separate them from impurities that remain in the aqueous media, the raffinate. The separation of tantalum and niobium is subsequently performed by fractional stripping into two different aqueous solutions. In this case, stripping of niobium is performed using relatively weak acids prior to the stripping of tantalum. Fig. 125 presents a flow chart of the process. 

In both cases, the extraction process includes washing (scrubbing) of the extract, a stage that is not shown separately. The organic phase that results from the stripping process is returned to the beginning of the extraction process for reuse as an extractant. 

Stripping. Stripping is the removal of the extracted solute from the organic phase for further preparation for the detailed analysis. In many analytical procedures involving an extraction process, however, the concentration of the desired solute is determined directly in the organic phase. 

This latter situation affords a good method for separating uranium from plutonium. Hydroxylammonium formate (HAF) and hydrazium formate (NHF) were added to the formic acid to reduce Pu(IV) to Pu(III) to aid in plutonium recovery, although formic acid alone will strip tetravalent actinides, e.g., Th(IV) from 0D[IB]CMP0, once excess HNO3 present in the organic phase is removed. Thus, formic acid with HAF and NHF affords an excellent method for stripping all the actinides from these very powerful CMP extractants. Under the above conditions Am(III) and Cm(III) present in... 

Conceptual Flowsheet for the Extraction of Actinides from HLLW. Figure 5 shows a conceptual flowsheet for the extraction of all the actinides (U, Np, Pu, Am, and Cm) from HLLW using 0.4 M 0< >D[IB]CMP0 in DEB. The CMPO compound was selected for this process because of the high D m values attainable with a small concentration of extractant and because of the absence of macro-concentrations of uranyl ion. Distribution ratios relevant to the flowsheet are shown in previous tables, IV, V, VI, and VII and figures 1 and 2. One of the key features of the flowsheet is that plutonium is extracted from the feed solution and stripped from the organic phase without the addition of any nitric acid or use of ferrous sulfamate. However, oxalic acid is added to complex Zr and Mo (see Table IV). The presence of oxalic acid reduces any Np(VI) to Np(IV) (15). The presence of ferrous ion, which is... 

Should pure olefin be used for alkylation (Shell process), the organic phase consists of benzene, LAB, and heavy alkylate and is fractionally distilled, after which the remaining HF is usually removed by stripping. When using olefin as a solution in paraffin (Pacol and Hiils process) for alkylation, the organic phase contains additional large quantities of paraffin which have to be separated out by distillation and used again in the production of olefin. 

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