Stick-slip

It is evident that boundary lubrication is considerably dependent on the state of the monolayer. Frewing [48] found that, on heating, the value of fi rose sharply near the melting point sometimes accompanied by a change from smooth to stick-slip sliding. Very likely these points of change correspond to the transition between an expanded film and a condensed film in analogy with... 

Klein and co-workers have documented the remarkable lubricating attributes of polymer brushes tethered to surfaces by one end only [56], Studying zwitterionic polystyrene-X attached to mica by the zwitterion end group in a surface forces apparatus, they found /i < 0.001 for loads of 100 and speeds of 15-450 nm/sec. They attributed the low friction to strong repulsions existing between such polymer layers. At higher compression, stick-slip motion was observed. In a related study, they compared the friction between polymer brushes in toluene (ji < 0.005) to that of mica in pure toluene /t = 0.7 [57]. 

Discuss why stick-slip friction is favored if fi decreases with sliding speed. 

Foam rheology has been a challenging area of research of interest for the yield behavior and stick-slip flow behavior (see the review by Kraynik [229]). Recent studies by Durian and co-workers combine simulations [230] and a dynamic light scattering technique suited to turbid systems [231], diffusing wave spectroscopy (DWS), to characterize coarsening and shear-induced rearrangements in foams. The dynamics follow stick-slip behavior similar to that found in earthquake faults and friction (see Section XU-2D). 

Yoshizawa FI and Israelaohvili J N 1993 Fundamental mechanisms of interfacial friction. 2. Stick-slip friction of spherical and chain molecules J. Phys. Chem. 97 11 300-13... 

Yoshizawa FI, McGuiggan P and Israelaohvili J N 1993 Identification of a second dynamic state during stick-slip motion Science 259 1305-8... 

Figure C2.9.2 Shear force versus time during (a) sliding and (b) stick-slip motion. The motion of the surface beneath the sliding block of figure C2.9.1 is at constant velocity.

This stick-slip cycle, observed for all types of film compounds ranging from long-chain (e.g., hexadecane) to spheroidal [e.g., octamethylcyclotetra-siloxane (OMCTS)] hydrocarbons [21], has been attributed by Gee et al. [30] to the formation of solid-like films that pin the walls together (region of sticking) and must be made to flow plastically in order for the walls to slip. This suggests that the structure of the walls induces the formation of a solid film when the walls are properly registered and that this film melts when... 

Stick-Slip Transitions from an Equilibrium Perspective... 

M. G. Rozman, M. Urbakh, J. Klafter. Stick-slip motion and force fluctuations in a driven two-wave potential. Phys Rev Lett 77 683-686, 1996. 

Torsional vibrations are due to the stick-slip effect of the stabilizers in deviated boreholes. They can be seen at surface as large torque oscillations with a period of 3 to 10 s. Figure 4-308 shows a near-bit stabilizer in a deviated borehole. The stick-slip effect increases with WOB and RPM. 

A torque feedback system has been developed to dampen the surface torque oscillations and consequently the stick-slip motion at the bit. The system consists of (see Figure 4-309)... 

Figure 4-308. Stick-slip effect due to near-bit fraction in a deviated borehole. (Courtesy Anadrill [113].,)...

Probably stabilizer digging in a stick-slip fashion. 

Plain slideways are preferred in the majority of applications. Only a thin film of lubricant is present, so its properties - especially its viscosity, adhesion and extreme-pressure characteristics - are of vital importance. If lubrication breaks down intermittently, a condition is created known as stick-slip , which affects surface finish, causes vibration and chatter and makes close limits difficult to hold. Special adhesive additives are incorporated into the lubricant to provide good bonding of the oil film to the sliding surfaces, which helps to overcome the problems of table and slideway lubrication. On long traverses, oil may be fed through grooves in the underside of the slideway. 

The use of hydrostatic slideways - in which pressurized oil or air is employed - completely eliminates stick-slip and reduces friction to very low values but there are disadvantages in the form of higher costs and greater complication. 

This type was developed to avoid stick-slip in heavily loaded leadscrews. It employs a screw and nut of special form, with bearing balls running between them. When the balls run off one end of the nut they return through an external channel to the other end. Such bearings are usually grease-packed for life. 

Specific application for machines with combined hydraulic and plain bearings, and lubrication systems where discontinuous or intermittent sliding (stick-slip) at low speed is to be prevented... 

Stick Slip Flow. The continuous sudden stoppage and resumption of catalyst flow in a standpipe. This is usually caused by underaeration. 

Stick-Slip Flow is erratic circulation caused when the catalyst packs and bridges across the standpipe. 

Stick-slip motion is another issue that has been explored using SFA. It is found that the occurrence of stick-slip depends on the sliding velocity and the stiffness of the system, and the mechanism of the phenomenon can be interpreted in terms of periodic transition between liquid and solid states of the conhned lubricant [40],... 

The solidihed layer yields and returns to the liquid phase if the shear stress excesses the critical value, which initiates the sliding. When the stress is relaxed as a result of slip, the solid phase resumes again. The periodic transition between the solid and liquid states has been interpreted in the literature as a major cause of the stick-slip motion in lubricated sliding. Understanding the stick-slip and static friction in terms of solid-liquid transitions in thin films makes a re-... 

The dependence of friction on sliding velocity is more complicated. Apparent stick-slip motions between SAM covered mica surfaces were observed at the low velocity region, which would disappear when the sliding velocity excesses a certain threshold [35]. In AFM experiments when the tip scanned over the monolayers at low speeds, friction force was reported to increase with the logarithm of the velocity, which is similar to that observed when the tip scans on smooth substrates. This is interpreted in terms of thermal activation that results in depinning of interfacial atoms in case that the potential barrier becomes small [36]. 

Fig. 19—Shear stress and chain angle as a function of sliding distance, from simulations of alkanethiolates on Au(111) at temperature 1 K (a) results from commensurate sliding show a stick-slip motion with a period of 2.5 A, (b) in incommensurate case both shear stress and chain angle exhibit random fluctuations with a much smaller average friction [45],...

In the studies that attribute the boundary friction to confined liquid, on the other hand, the interests are mostly in understanding the role of the spatial arrangement of lubricant molecules, e.g., the molecular ordering and transitions among solid, liquid, and amorphous states. It has been proposed in the models of confined liquid, for example, that a periodic phase transition of lubricant between frozen and melting states, which can be detected in the process of sliding, is responsible for the occurrence of the stick-slip motions, but this model is unable to explain how the chemical natures of lubricant molecules would change the performance of boundary lubrication. 

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