Solids concentration fast fluidization

One of the advanced concepts for capturing CO2 is an absorption process that utilizes dry regenerable sorbents. Pure sodium bicarbonate from Dongyang Chemical Company and spray-dried sorbents were used to examine the characteristics of CO2 reaction in a flue gas environment. The chemical characteristics were investigated in a fast fluidized reactor of 0.025 m i.d., and the effects of several variables on sorbent activity, including gas velocity (1.5 to 3.5 m/s), temperature (40 to 70 °C), and solid concentration (15 to 25 kg/m /s)], were examined in a fast fluidized-bed. Spray-dried Sorb NX30 showed fast kinetics in the fluidized reactor. 

As noted earlier, increasing gas velocity for any given fluidized bed beyond the terminal velocity of bed particles leads to upward entrainment of particles out of the bed. To maintain solid concentration in the fluidized bed, an equal flux of solid particles must be injected at the bottom of the bed as makeup. Operation in this regime, with balanced injection of particles into the bed and entrainment of particles out of the bed, may be termed fast fluidization, FFB. Figure 10 presents an approximate map of this fast fluidization regime, in terms of a dimensionless gas velocity and dimensionless particle diameter. 

Figure 11. Axial variation of solid concentration for fast fluidized bed of sand particles, at U— 5 m/s and Gs = 30 kg/m2 s. (From Herb, Dou, Tuzla and Chen,...

Figure 15. Concentration of solid in clusters in fast fluidized bed. (From Soong, Tuzla and Chen, 1993.)...

The data of Fig. 20 also point out an interesting phenomenon—while the heat transfer coefficients at bed wall and bed centerline both correlate with suspension density, their correlations are quantitatively different. This strongly suggests that the cross-sectional solid concentration is an important, but not primary parameter. Dou et al. speculated that the difference may be attributed to variations in the local solid concentration across the diameter of the fast fluidized bed. They show that when the cross-sectional averaged density is modified by an empirical radial distribution to obtain local suspension densities, the heat transfer coefficient indeed than correlates as a single function with local suspension density. This is shown in Fig. 21 where the two sets of data for different radial positions now correlate as a single function with local mixture density. The conclusion is That the convective heat transfer coefficient for surfaces in a fast fluidized bed is determined primarily by the local two-phase mixture density (solid concentration) at the location of that surface, for any given type of particle. The early observed parametric effects of elevation, gas velocity, solid mass flux, and radial position are all secondary to this primary functional dependence. 

The simplest correlations are of the form shown by Eq. (15), in attempts to recognize the strong influence of solid concentration (i.e., suspension density) on the convective heat transfer coefficient. Some examples of this type of correlation, for heat transfer at vertical wall of fast fluidized beds are ... 

The lean/gas phase convection contribution has received the least attention in the literature. Many models in fact assume it to be negligible in comparison to dense phase convection and set hl to be zero. Compared to experimental data, such an approach appears to be approximately valid for fast fluidized beds where average solid concentration is above 8% by volume. Measurements obtained by Ebert, Glicksman and Lints (1993) indicate that the lean phase convection can contribute up to 20% of total... 

In measurement and visualization of gas-solid flow in fast fluidization, various techniques have been developed and used, such as pressure gradient, pressure fluctuation, capacitance probe, optical fiber probe, momentum probe, laser Doppler velocimeter, night-television, and video camera. The resulting data on local gas and solid velocity, solids concentration and its... 

Voidage profiles represent one of the most important aspects of the flow structure of fast fluidization, which play an important role in gas and solids mixing, mass and heat transfer, and conversion in a chemical reactor. Considerable efforts have been given to studying the axial and radial variation of solids concentration axially, dilute at the top and dense at the bottom, and radially, dilute in the center and dense in the vicinity of the wall. As already mentioned in Section II, these variations depend mainly on gas velocity and solids circulation rate and are also influenced by the configuration of the apparatus. 

Bader et al. (1988) used common salt as a solid tracer, which was injected into a flowing catalyst bed. Solids samples, withdrawn downstream of tracer injection, were leached with water and the salt concentration determined by electrical conductivity of the solution. Their results indicated substantial solids backmixing. Li et al. (1991) observed solids mixing in a fast fluidized bed combustor by using raw coal as a tracer, which was injected into the ash bed. Their results also showed that near-perfect mixing prevailed. Similar experiments was also conducted by Chesonis et al. (1991) in a cold model. 

Inasmuch as heat transfer depends on the hydrodynamic features of fast fluidization, if the fast fluidized bed is equipped with an abrupt exit, the axial distribution of solids concentration will have a C-shaped curve (Jin et al., 1988 Bai et al., 1992 Glicksman et al., 1991. See Chapter 3, Section III.F.l). The heat transfer coefficient will consequently increase in the region near the exit, as reported by Wu et al. (1987). 

The second and the third components become significant only at high temperatures (> 700°C) and low solids concentrations (< 30 kg/m3). In fast fluidized beds, the motion of the particles plays an overriding role in the heat transfer process, since the solids particles have larger heat capacity and higher thermal conductivity. Most of the heat transfer models reported in the literature give emphasis to particle convective transfer. 

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