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Sodium hypophosphite

Triethylammonium formate is another reducing agent for q, /3-unsaturated carbonyl compounds. Pd on carbon is better catalyst than Pd-phosphine complex, and citral (49) is reduced to citronellal (50) smoothly[55]. However, the trisubstituted butenolide 60 is reduced to the saturated lactone with potassium formate using Pd(OAc)2. Triethylammonium formate is not effective. Enones are also reduced with potassium formate[56]. Sodium hypophosphite (61) is used for the reduction of double bonds catalyzed by Pd on charcoal[57]. [Pg.520]

However, hydrogen is formed in two side reactions, ie, by the decomposition of some sodium hypophosphite (eq. 2) and by the direct reaction of phosphoms with sodium hydroxide (eq. 3). [Pg.317]

Excess calcium hydroxide is precipitated by usiag carbon dioxide and the calcium carbonate, calcium hydroxide, and calcium phosphite are removed by filtration. The filtered solution is treated with an equivalent amount of sodium sulfate or sodium carbonate to precipitate calcium sulfate or carbonate. Sodium hypophosphite monohydrate [10039-56-2] is recovered upon concentration of the solution. Phosphinic acid is produced from the sodium salt by ion exchange (qv). The acid is sold as a 50 wt %, 30—32 wt %, or 10 wt % solution. The 30—32 wt % solution is sold as USP grade (Table 12) (63). Phosphinic acid and its salts are strong reduciag agents, especially ia alkaline solution (65). [Pg.375]

Approximately 4500 tons of sodium hypophosphite [7681-53-0] NaH2P02, was produced in 1990. This material is used principally in electroless nickel plating of plastic objects. Of the secondary products made from primary phosphoms compounds, phosphoms oxychloride is manufactured in the largest volume. Phosphoms pentachloride and phosphoms sulfochloride are made from phosphoms trichloride. [Pg.383]

Hand in hand with this research on finding a suitable carboxyUc acid chemical for cross-linker has been the search for an economical catalyst system. The catalyst found to be most effective for the esterification reaction was sodium hypophosphite (NaH2P02). This material was also costiy and out of range for the textile industry. Because weak bases function as catalyst, a range of bases has been explored, including the sodium salts of acids such as malic acid. [Pg.447]

Distibines and Distibenes. A considerable number of tetraalkyl- and tetraaryldistibines have been investigated. These are usually obtained by the reduction of a dialkyl- or diaryUialostibine with sodium hypophosphite (111,112) or magnesium (108,116). Distibines can also be prepared by the treatment of a metal dialkyl- or diarylstibide with a 1,2-dihaloethane (70,71,77,85,91,128)... [Pg.207]

Electroless nickel—boron baths use sodium borohydride or dimethylamine borane [74-94-2] in place of sodium hypophosphite (see Boron compounds). The nickel—boron aHoy is brittle, highly stressed, and much more expensive than nickel—phosphoms aHoys. Nickel—boron is mainly used to replace gold in printed circuit board plating. [Pg.108]

Pd-C, R0H,.HC02NH4J hydrazine or sodium hypophosphite, 42-91% yield. 2-Benzylaminopyridine and benzyladenine were stable to these reaction conditions. Lower yields occurred because of the water solubility of the product, thus hampering isolation. [Pg.365]

Commercial processes Commercial electroless nickel plating stems from an accidental discovery by Brenner and Riddell made in 1944 during the electroplating of a tube, with sodium hypophosphite added to the solution to reduce anodic oxidation of other bath constituents. This led to a process available under licence from the National Bureau of Standards in the USA. Their solutions contain a nickel salt, sodium hypophosphite, a buffer and sometimes accelerators, inhibitors to limit random deposition and brighteners. The solutions are used as acid baths (pH 4-6) or, less commonly, as alkaline baths (pH 8-10). Some compositions and operating conditions are given in Table 13.17 . [Pg.535]

In the alternative method of reduction, which is particularly valuable for the determination of small amounts of tellurium, the procedure is as follows. Treat the solution containing, say, up to about 0.01 g Te in 90 mL with 10 mL of 1 3-sulphuric acid, then add 10 g sodium hypophosphite (phosphinate), and heat on a steam bath for 3 hours. Collect and weigh the precipitated tellurium as above. [Pg.466]

PCA 16 is available as Beldene 161/164 (50/35% w/w solids), Acumer 4161 (50%), and Polysperse (50%). These are low-phosphorus content materials that have found application in boiler FW formulations because of excellent sludge conditioning and particulate dispersion properties. The number 16 represents a 16 1 w/w ratio of acrylic acid and sodium hypophosphite, giving PCA 16 a MW range of 3,300 to 3,900. PCA 16 is particularly effective for the control of calcium carbonate and sulfate deposition. It is usually incorporated with other polymers in formulations and is approved for use under U.S. CFR 21, 173.310. [Pg.452]

C = C—NO2 —> — CH—C=NOH) with sodium hypophosphite and with Pb—HOAc—DMF, as well as with certain other reagents. ... [Pg.1558]

Sodium hydrogen telluride, (NaTeH), prepared in situ from the reaction of tellurium powder with an aqueous ethanol solution of sodium borohydride, is an effective reducing reagent for many functionalities, such as azide, sulfoxide, disulfide, activated C=C bonds, nitroxide, and so forth. Water is a convenient solvent for these transformations.28 A variety of functional groups including aldehydes, ketones, olefins, nitroxides, and azides are also reduced by sodium hypophosphite buffer solution.29... [Pg.219]

The principal evidence in favor of the electrochemical mechanism is the observation that metal deposition can occur, albeit at a much reduced rate, in a two-compartment cell. When one of the compartments contains only the metal ions and the other only the sodium hypophosphite, metal deposition occurs on the electrode in the first compartment, being driven by hypophosphite oxidation at the electrode in the other half-cell [36, 37],... [Pg.255]


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