Signature Materials

Room-temperature fluorescence (RTF) has been used to determine the emission characteristics of a wide variety of materials relative to the wavelengths of selected Fraunhofer lines in support of the Fraunhofer luminescence detector remote-sensing instrument. RTF techniques are now used in the compilation of excitation-emission-matrix (EEM) fluorescence "signatures" of materials. The spectral data are collected with a Perkin-Elraer MPF-44B Fluorescence Spectrometer interfaced to an Apple 11+ personal computer. EEM fluorescence data can be displayed as 3-D perspective plots, contour plots, or "color-contour" images. The integrated intensity for selected Fraunhofer lines can also be directly extracted from the EEM data rather than being collected with a separate procedure. Fluorescence, chemical, and mineralogical data will be statistically analyzed to determine the probable physical and/or chemical causes of the fluorescence. 

Odd torque harmonics become significant as strain increases and are therefore considered as the nonlinear viscoelastic signature of tested materials, only available through FT rheometry. Figure 30.10 shows the typical pattern of corrected relative TTHC (i.e., T(nw/lw)) versus strain y that, in most cases, can be modeled with a simple equation, i.e.. 

What convinces scientists that sustained fission once occurred at Oklo is the presence of characteristic fission products in the ore. Elements of mass numbers between 75 and 160 occur in the ore in larger amounts than elsewhere. Furthermore, mass analysis of the elements in Oklo ore shows that they are distributed in the characteristic pattern shown in Figure 22-12. This isotopic signature, which is not found in any other naturally occurring materials, is so characteristic that it has convinced most scientists that the ore deposits at Oklo once formed a huge nuclear reactor. 

It is equally important for the manufacturer and regulator to know the level of additives in a polymer material to ensure that the product is fit for its intended purpose. Additive analysis marks sources of supply, provides a (total) process signature and may actually be used as a fingerprint of a polymeric material, in particular as molecular characterisation of the polymer... 

Since most (if not all) low-metallicity objects that are currently observed in the halo are not in the AGB phase, material enriched in carbon and the s-process elements is assumed to have accreted from the companion AGB stars, which have already evolved to faint white dwarfs, to the surface of the surviving companion. This scenario is the same as that applied to classical CH stars [4], Unfortunately, long-term radial velocity monitoring has been obtained for only a limited number of objects a clear binarity signature has been established for six objects in our sample to date. However, there exists additional support for the mass-accretion scenario for the Ba-rich CEMP stars. Fig. lb shows [C/H] as a function of luminosity roughly estimated from the effective temperature... 

The use of natural abundance variations in stable isotopes as tracers relies on the fractionations that occur during chemical, physical and biological processes (Ambrose 1993). Differences in fractionation during these processes lead to distinct isotopic signatures for biological materials, such as in foods exploited by humans in antiquity. 

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