Sedimentation hindered

Hindered Settling When particle concentration increases, particle settling velocities decrease oecause of hydrodynamic interaction between particles and the upward motion of displaced liquid. The suspension viscosity increases. Hindered setthng is normally encountered in sedimentation and transport of concentrated slurries. Below 0.1 percent volumetric particle concentration, there is less than a 1 percent reduction in settling velocity. Several expressions have been given to estimate the effect of particle volume fraction on settling velocity. Maude and Whitmore Br. J. Appl. Fhys., 9, 477—482 [1958]) give, for uniformly sized spheres,... 

Filtration frequently is accompanied by hindered or free gravitational sedimentation of solid particles. The directions of action of gravity force and filtrate motion may be cocurrent, countercurrent or cross current, depending on the orientation of the... 

If the feed rate exceeds the maximum of the design, particulate matter are unable to settle out of the normal clarification zone. Hence, there is an increase in the solids concentration, resulting in hindered settling. The result Is a corresponding decrease in the sedimentation rate below that observed for the feed slurry. 

Note that the above calculations are based on nonhindered sedimentation and, therefore, should be modified for a hindered "fall."... 

Three stages bubble escape, hindered sedimentation and solids consolidation... 

The self-constructed Laserphoto Sedimentometer and the measuring procedures to obtain the transmission-height profiles and the characterizing parameters for the turbidity and the hindered sedimentation behaviour of the flocculated suspension are described in earlier publications (10,1). Thus only a summary of these parameters is given here ... 

If the sediment sample contains elemental sulphur, which hinders the determination of chlorinated organic insecticides, then this can be removed by a process involving treatment with concentrated sulphuric acid and tetrabutyl ammonium sulphate. 

Dolomite is one of the most abundant sedimentary carbonate minerals but its mode of formation and its surface properties are less well known than for most other carbonate minerals. As we have mentioned, the nucleation of dolomites and its structural ordering is extremely hindered. There is a general trend for the "ideality" of dolomite to increase with the age of dolomite over geological time (Morse and Mackenzie, 1990). Most dolomites that are currently forming in surfacial sediments and that have been synthesized in the laboratory are calcium-rich and far from perfectly ordered. Such dolomites are commonly referred to as "protodolomites . Morse and Mackenzie (1990) have reviewed extensively the geochemistry (including the surface chemistry of dolomites and Mg-calcites. 

The First-Order Kinetic Model. Karickhoff (1, 68) has proposed a two-compartment equilibrium-kinetic model for describing the solute uptake or release by a sediment. This model is based on the assumption that two types of sorption sites exist labile sites, S, which are in equilibrium with bulk aqueous solution, and hindered sites, Sjj, which are controlled by a slow first-order rate process. Conceptually, sorption according to this model can be considered either as a two-stage process ... 

The thickener is the industrial unit in which the concentration of a suspension is increased by sedimentation, with the formation of a clear liquid. In most cases, the concentration of the suspension is high and hindered settling takes place. Thickeners may operate as batch or continuous units, and consist of tanks from which the clear liquid is taken off at the top and the thickened liquor at the bottom. 

Our knowledge about the forms and genesis of neoformed Fe " oxides in sediments and sedimentary rocks is still rather limited because the low concentrations and poor crystallinity of these oxides hinder their identification and description. Two groups of Fe-containing sediments, whose Fe oxides have, however, attracted more interest than usual, are red beds and sedimentary iron ores (Fiichtbauer, 1988). 

In this process, the reaction of the intermediates-essentially indophenols, chiefly in leuco form, or indophenol-like substances-with sulfur is effected by heating with alkali metal polysulfide in an aqueous or alcoholic medium under reflux. When monoethers of ethylene glycol or diethylene glycol (such as Carbitol) are used, the dye can be obtained in solution form after melting, without distillation and elimination of the solvent. Accordingly, these solvents are used chiefly in the preparation of ready-to-dye sulfur dye solutions. The addition of hydrotropic substances such as sodium xylenesulfonate improves the homogeneity of the melt and hinders sedimentation of the dye on storage. 

If the particle concentration in a suspension is high, then the particles do not sediment independently, but are influenced by the motions of surrounding particles (hindered settling). Hindered settling behaviour can be described by applying a correction factor to the Stokes Law terminal settling velocity (dx/dt from Eq. 2.20) to obtain a hindered settling velocity. Several equations have been advanced to describe the correction [69]. The Richardson-Zaki equation for this is ... 

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