Sand cracking reactor

Salicylic acid purification, 646 Salt cake furnace, 590 Sand cracking reactor, 593 Sand filters, 118,322 SC (simultaneous conection) method, 404,408,410... 

Polystyrene bottles were pyrolyzed by the Japan Fluid Cracking process (JFC) in a fluid sand bed reactor of 500 mm diameter and with a capacity of 1 t/day [2]. The oily products were contaminated by oxidized compounds. 

The heat-carrying solids are particles of fluidized sand that circulate between the heating and reaction zones. The reaction section for hght hydrocarbons is at 720 to 850°C (1,328 to 1,562°F), the regenerated sand returns at 50 to 100°C (122 to 212°F) above the reactor temperature. The heat comes mostly from the burning of carbon deposited on the sand. This equipment is perhaps competitively suited to cracking heavy stocks that coke readily. 

In the Battelle/Columbus gasification system biomass particles are surrounded with extremely hot sand, which converts it into gaseous form. The solid biomass is surrounded by sand heated from 1800 to 1900°F, which converts the biomass into gas and residual char in a fluidized-bed reactor at 1500 to 1600°F. Sand is used to carry the biomass and the char and to distribute the heat. Using sand as a heat carrier keeps out the air. This results in a better quality fuel gas. A second reactor combusts the char to heat the sand. Remaining traces of condensable matter formed during gasification are removed in a chamber where a catalyst cracks and converts them into fuel gas. The clean biogas is then pressurized before it reaches the gas turbine. 

The Blowdec depolymerization process from Slovakia converts waste plastics into low-sulphur diesel fuel [35]. The main principle is the processing of waste plastics in a hot whirling bed of hot sand in the BLOWDEC reactor (Figure 15.19). The plastic is heated to 430°C. The process allows for simultaneous cracking of hydrocarbons and inhibition of coke formation. The fluidized sand bed products three types of cracking reactions mechano-activation thermal and catalytic (Si02/aluminosilicates). The process is covered under the US Patent 6,165,349. The process enables the economical conversion of mixed waste plastics into liquid hydrocarbons, mainly low-sulphur (25 ppm) diesel... 

The BP process [7] is based on a sand fluidized-bed pyrolysis reactor. The cracking temperature is kept at 400-600°C. Low-molecular hydrocarbons can be obtained. The process mainly involves converting waste plastics into normal linear hydrocarbons, the average molecular weight of which is 300-500. Most plastics can be treated by this process. Polyolefins are decomposed into small molecules with the same linear structure. PS is converted into styrene monomers and PET into mixture of hydrocarbons, carbon monoxide and carbon dioxide. A maximum of 2% PVC is allowed in this process, and the content of chlorine in the products is lower than 5 ppm. The distribution of alkene products in this process is like that in petroleum pyrolysis. The BP process was industrialized in 1997. 

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