Rupture potential

Fig. 1.56(a) E-i curves and experimental potential-pH diagram for Armco iron in chloride-free solutions of different pHs (A is the unpolarised potential and P the passivation potential) and (b) E—i curves and experimental potential-pH diagram for Armco iron in solutions of different pHs containing 10 mol dm of chloride ion (r is the rupture potential and p the protection potential). (After Pourbaix )... 

Potential explosion phenomena include vapor cloud explosions (VCEs), confined explosions, condensed-phase explosions, exothermic chemical reactions, boiling liquid expanding vapor explosions (BLEVEs), and pressure-volume (PV) ruptures. Potential fire phenomena include flash fires, pool fires, jet fires, and fireballs. Guidelines for evaluating the characteristics of VCEs, BLEVEs, and flash fires are provided in another CCPS publication (Ref. 5). The basic principles from Reference 5 for evaluating characteristics of these phenomena are briefly summarized in this appendix. In addition, the basic principles for evaluating characteristics of the other explosion and fire phenomena listed above are briefly summarized, and references for detailed evaluation of characteristics are provided. 

Fig.l. Typical anodic polarization curve of stainless steels in sulfuric acid solutions. Eoc natural corrosion potential, Ep passivity potential, Er rupture potential. 

For vehicles, special attention is most often focused on the knocking potential encountered at high motor speeds in excess of 4000 rpm for which the consequences from the mechanical point of view are considerable and lead very often to mechanical failure such as broken valves or pistons, and rupture of the cylinder head gasket. Between RON and MON, it is the latter which better reflects the tendency to knock at high speeds. Conversely, RON gives the best prediction of the tendency to knock at low engine speeds of 1500 to 2500 rpm. 

This result reflects the Kramers relation (Gardiner, 1985). A millisecond time of unbinding, i.e.. Tact 1 ms, corresponds in this case to a rupture force of 155 pN. For such a force the potential barrier AU is not abolished completely in fact, a residual barrier of 9 kcal/mol is left for the ligand to overcome. The AFM experiments with an unbinding time of 1 ms are apparently functioning in the thermally activated regime. 

To enable an atomic interpretation of the AFM experiments, we have developed a molecular dynamics technique to simulate these experiments [49], Prom such force simulations rupture models at atomic resolution were derived and checked by comparisons of the computed rupture forces with the experimental ones. In order to facilitate such checks, the simulations have been set up to resemble the AFM experiment in as many details as possible (Fig. 4, bottom) the protein-ligand complex was simulated in atomic detail starting from the crystal structure, water solvent was included within the simulation system to account for solvation effects, the protein was held in place by keeping its center of mass fixed (so that internal motions were not hindered), the cantilever was simulated by use of a harmonic spring potential and, finally, the simulated cantilever was connected to the particular atom of the ligand, to which in the AFM experiment the linker molecule was connected. 

Fowler, D.W., T.R. Herndon, R.C. Wahrmund, 1968, an Analysis of Potential Overpressure of Heat Exchanger Shell Due to a Rupture Tube, presented at the American Society of Mechanical Engineers Petroleum Division Conference, September 22-25, 1968. 

At Site E, personnel had not been trained in how to shut off the LPG tank in case of an LPG line rupture or leak, even though a potential rupture or leak was discussed as a hazard in the SSAHP. 

Assume that the system described below exists in a process unit recently purchased by your company. As the manager, the safety of this unit is now your responsibility. You are concerned because your process hazard analysis team identified the potential for an operator error to result in a rupture of the propane condenser. You have commissioned a human reliability analysis (HRA) to estimate the likelihood of the condenser rupturing as the result of such an error and to identify ways to reduce the expected frequency of such ruptures... 

Where e.xperience indicates a reiisoiiable potential for equipment failure (such as a tank overflow, rupture, or leakage), the plan is to include a prediction of the direction, rate of flow, and total quantity of oil that could be discharged from the facility as a result of each major type of failure... 

Adsorbers, distillation colunuis, and packed lowers are more complicated vessels and as a result, the potential exists for more serious hazards. These vessels are subject to tlie same potential haz. uds discussed previously in relation to leaks, corrosion, and stress. However, llicse separation columns contain a wide variety of internals or separation devices. Adsorbers or strippers usually contain packing, packing supports, liquid distributors, hold-down plates, and weirs. Depending on tlie physical and chemical properties of the fluids being passed tlirough tlie tower, potential liazards may result if incompatible materials are used for llie internals. Reactivity with llie metals used may cause undesirable reactions, which may lead to elevated temperatures and pressures and, ullinialely, to vessel rupture. Distillation columns may contain internals such as sieve trays, bubble caps, and valve plates, wliicli are also in conlacl with tlie... 

In this exercise, you will explore the bond rupture process by performing a potential energy surface scan. Run potential energy surface scans for these molecules, gradually increasing one of the C-H bond lengths, using the specified model chemistries ... 

Rupture disks when properly sized and located on the potentially overpressure vessel have been shown to provide the best protection for a deflagration but not a detonation [54],... 

For a flare stack to function properly and to handle the capacity that may be required, the flows under emergency conditions from each of the potential sources must be carefully evaluated. These include, but may not be limited to, pressure relief valves and rupture disks, process blowdown for startup, shutdown, upset conditions, and plant... 

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