Reactive system process safety

Reactive System Screening Tool (RSST) The RSST is a calorimeter that quickly and safely determines reactive chemical hazards. It approaches the ease of use of the DSC with the accuracy of the VSP. The apparatus measures sample temperature and pressure within a sample containment vessel. Tne RSST determines the potential for runaway reactions and measures the rate of temperature and pressure rise (for gassy reactions) to allow determinations of the energy and gas release rates. This information can be combined with simplified methods to assess reac tor safety system relief vent reqiiire-ments. It is especially useful when there is a need to screen a large number of different chemicals and processes. 

This section discusses how the interpretation, evaluation, and correlation of test results from bench-scale equipment can be integrated into an approach to inherent process safety involving reactive systems. 

Scale-up can also have a significant effect on the basic process control system and safety systems in a reactive process. In particular, a larger process will likely require more temperature sensors at different locations in the process to be able to rapidly detect the onset of out-of-control situations. Consideration should be given to the impact of higher-temperature gradients in plant-scale equipment compared to a laboratory or pilot plant reactor (Hendershot 2002). 

Listed in Table 2.1 are the essential elements of managing chemical reactivity hazards, as described in Sections 4.1 through 4.10 of this publication. They are mapped to comparable elements in three other, broader process safety and risk management systems ... 

Analysis and Safeguards Lees, Loss Prevention in the Process Industries ISBN 0750615478 Guidelines for Safe Storage and Handling of Reactive Materials Guidelines for Process Safety in Batch Reaction Systems Guidelines for Hazard Evaluation Procedures, Second Edition with Worked Examples... 

ACC has published a resource guide to aid member companies in implementing the Responsible Care Process Safety Code (ACC, 1989). Although the guide provides suggestions on how to continually improve process safety, it does not prescribe how to comply with the code. It does not list specific requirements for reactive hazard management, but does require management systems to be developed-several of which could apply to reactive hazards as determined by each member company. 

The field of chemical process miniaturization is growing at a rapid pace with promising improvements in process control, product quality, and safety, (1,2). Microreactors typically have fluidic conduits or channels on the order of tens to hundreds of micrometers. With large surface area-to-volume ratios, rapid heat and mass transfer can be accomplished with accompanying improvements in yield and selectivity in reactive systems. Microscale devices are also being examined as a platform for traditional unit operations such as membrane reactors in which a rapid removal of reaction-inhibiting products can significantly boost product yields (3-6). 

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