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Reaction residues

FIG. 23-15 Chemical conversion by the dispersion model, (a) First-order reaction, volume relative to plug flow against residual concentration ratio, (h) Second-order reaction, residual concentration ratio against kC t. [Pg.2090]

Modification reactions Residues introduced/nm S-layer surface (SUM) BSA OVA CA MYO... [Pg.349]

Applications Although Soxtec combines the best qualities of reflux and Soxhlet extractions up to now fairly little evidence has been reported concerning the efficacy of this system for polymer and rubber analysis. Nevertheless, it appears that oligomers and other reaction residues, softeners, antioxidants (e.g. BHT) and several other additives used to modify polymers are easily extracted from PVC, PP, PE, PS, rubber and many other polymeric materials. Also, some leading international plastic, rubber and packaging companies have made Soxtec an integral part of their quality control routines. Some application examples where Soxtec has proved successful are [148] ... [Pg.72]

Interaction to form the corresponding tribromomethyl compound is extremely hazardous, even using previously specified precautions [1]. Several fires occurred in the effluent gases, and in reaction residues exposed to air [2], doubtless owing to phosphine or its derivatives. [Pg.123]

During ozonolysis of vinyl fluoride an explosive solid residue is produced, and the volatile ozonide, trapped at —63°C, may explode spontaneously or dining removal by syringe [1]. During the cryogenic distillation of the ozonide (formulated as a trioxolane), several explosions occurred, and the explosive reaction residue was destroyed by digestion with 5% potassium iodide solution for 24 h [2],... [Pg.286]

Chatt, J. et al., J. Chem. Soc., Dalton Trans., 1985, 1131-1136 A modified method of preparation from ethylene, phosphorus trichloride and phosphorus in a stainless autoclave gives a highly pyrophoric reaction residue. [Pg.303]

The formyl ester and hydroxylamine were allowed to react in ethanol, which was then removed by vacuum evaporation at 40°C. The dry residue decomposed violently 5 min later. Analysis of the residue suggested that the oxime had undergone an exothermic Beckmann rearrangement, possibly catalysed by traces of hydrogen chloride in the reaction residue. [Pg.809]

This is prepared from 2-nitrochlorobenzene and sodium disulfide in ethanol, and the reaction residue after recovery of the ethanol by steam distillation is known to be of limited thermal stability. On one occasion, a container (atypically with closed vents) of bulked residues totalling over 2 t exploded violently while awaiting collection for disposal. It seems remotely possible that an aci-nitro thioquinonimine species derived from 2-nitrobenzenethiol may have been involved. [Pg.1143]

The reaction residue is allowed to cool to room temperature and is filtered by suction. The dark mineral oil filtrate may be reused in the process. The malodorous filter cake is not pyrophoric and is almost completely soluble in water or dilute alkali with liberation of hydrogen sulfide. [Pg.75]

The reaction residue is placed on the column as is, and the reaction flask is rinsed with small portions of hexane-chloroform which are also loaded onto the column. [Pg.141]

Disposal. The reaction residue of AsC13 is treated with hot water under a well-ventilated fume hood to give solid As203, which is recovered by filtration. [Pg.150]

Renewal or reactivation of a catalyst that has accumulated reaction residues such as coke, usually accomplished by passage of steam or reducing gases over the catalyst bed. [Pg.1434]

One particular application for which supported Au catalysts may find a niche market is in fuel cells [4, 50] and in particular in polymer electrolyte fuel cells (PEFC), which are used in residential electric power and electric vehicles and operate at about 353-473 K. Polymer electrolyte fuel cells are usually operated by hydrogen produced from methane or methanol by steam reforming followed by water-gas shift reaction. Residual CO (about 1 vol.%) in the reformer output after the shift reaction poisons the Pt anode at a relatively low PEFC operating temperature. To solve this problem, the anode of the fuel cell should be improved to become more CO tolerant (Pt-Ru alloying) and secondly catalytic systems should be developed that can remove even trace amounts of CO from H2 in the presence of excess C02 and water. [Pg.84]

However, it has been found that a by-product arising from the interaction of formaldehyde and hydrogen chloride is bis(chloromethyl)ether (BCME), which is a potent carcinogen. For this reason the classical chloromethylation route to side-chain halogenated products should not be regarded as a desirable synthetic procedure, and in general should only be used if the required compound cannot be readily prepared by other methods. When used, effective precautions should be taken during the reaction and in the disposal of the reaction residues.12 13... [Pg.866]

A modified method of preparation from ethylene, phosphorus trichloride and phosphorus in a stainless autoclave gives a highly pyrophoric reaction residue. [Pg.336]


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See also in sourсe #XX -- [ Pg.82 ]




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3-Elimination reaction, ester-bound residue

Carbohydrate residues, coupling reactions

Cross-reactions residues detection

Elimination reactions beta, of cystine residues

Hydrocracking Reaction of Heavy Residues

Investigation on the hydrocracking reaction of heavy residues

Metal residue after hydrochloric acid reaction

Proline residues protein folding reactions

Reaction mechanism for mutants lacking the general acid residue

Reaction of cysteinyl residues with azobenzene-2-sulfenyl bromide

Residual heat of reaction

Residual reaction exotherm

Residual reaction exotherm solvent

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