Pyrolysis paper

Shu, W. R., Ross, L. L., "A Feed Decomposition Model for Naphtha Pyrolysis". Paper No 62c, the 71st Annual Meeting of AIChE, Miami Beach, November 1978. 

F. B. Carlson, L. H. Yardumian, and M. T. Atwood, "The TOSCO AT, Process for Low Temperature Pyrolysis of Coal," paper presented at... 

J. J. Brenden, Effect of Fire-Retardant and Other Inorganic Salts on Pyrolysis Products ofPonderosa Pine at 250° and 350°C, Research Paper PPL 80, U.S. Department of Agriculture, Eorest Service, Eorest Products Laboratory, Madison, Wise., 1967. 

J. M. Femandez-Baujin and S. M. Solomon, "An Industrial Apphcation of Pyrolysis Technology Lummus SRT-III Module," paper presented at... 

An Ecoprofile is an assessment of the environmental and resource impacts of a waste disposal process. This paper describes ecoprofiles for six different ways of disposing the plastic fraction in municipal solid waste -two material recycling processes that include separation of the plastic waste, material recycling without separation of the plastic waste, pyrolysis, incineration with heat recovery, and landfill. 17 refs. 

This paper diseusses in detail the option of fluidised-bed reaetors to eraek mixed plastics waste into valuable raw materials, under the headings thermal cracking for feedstocks, pyrolysis of polyolefins, and other options. 7 refs. 

This paper discusses the effects of the pyrolysis of wood and paper treated with pentachlorophenol or sodium pentachlorophenate along with the exposure of sodium pentachlorophenate to ultraviolet light. The effect of heat, light, and air with respect to some of the chlorinated dibenzo-p-dioxins will be considered. 

Fuel industry is of increasing importance because of the rapidly growing energy needs worldwide. Many processes in fuel industry, e.g. fluidized catalytic cracking (FCC) [1], pyrolysis and hydrogenation of heavy oils [2], Fischer-Tropsch (FT) synthesis [3,4], methanol and dimethyl ether (DME) synthesis [5,6], are all carried out in multiphase reactors. The reactors for these processes are very large in scale. Unfortunately, they are complicated in design and their scale-up is very difflcult. Therefore, more and more attention has been paid to this field. The above mentioned chemical reactors, in which we are especially involved like deep catalytic pyrolysis and one-step synthesis of dimethyl ether, are focused on in this paper. 

An assortment of small corks for closing small bore tubing can, in addition, be very useful. If the flame is to come near to a cork or a rubber stopper it is best to wrap either in thin asbestos paper before inserting into the tube. When pyrolysis of the cork or rubber stopper seems probable it is best to use a cork and not a rubber stopper, because the pyrolysis products from a cork can be cleaned olf more easily than those from rubber. Sometimes a plug made from damp asbestos paper is adequate for closing a tube of small bore, and this plug can be heated quite strongly. 

A GC-IR-MS system with library search capability has been used to effectively identify the pyrolysis products of polybutadiene and the antioxidant additive 2,6-di-f-butyl-4-methylphenol [199]. Paper for food packaging was analysed by P T (at 100 °C) combined with /i-GC-UV. No specific applications of /rGC-UV to poly-mer/additive analysis have as yet been reported. 

The first part of this paper has shown that Australian black and brown coals differ significantly in a number of respects from coals of similar ranks from North America and elsewhere in the northern hemisphere. The rest of the paper than proceeded to indicate the progress being made to determine how the characteristics of Australian coals influence their conversion to volatile and liquid products during pyrolysis and hydrogenation. 

For a discussion of modern methods of olefin manufacture by pyrolysis, consult the paper by Ennis and co-workers (5). 

Additives, such as fire retardants, can have a major effect on pyrolysis, and even trace amounts of ash have been shown to influence pyrolysis (6 ). Generally, fire retardants work by increasing the dehydration reaction rate to form more char and as a direct result give fewer flammable volatile compounds (1,3,7). Several papers have noted that phosphoric acid and its salts decrease the Efl (13,18,22,29), aluminum chloride has little effect (22) on Efl and boric acid increases the Efl (12,18). The reaction order for treated samples has been generally reported as lst-order (12,13,18,29) which is also the most commonly used rate expression for analysis of TGA data of untreated cellulose. 

Tang, W. K., H. W. Eickner. Effect of Inorganic Salts on Pyrolysis of Wood, Cellulose, and Lignin Determined by Differential Thermal Analysis FPL Research Paper 82, U.S.D.A., 1967. 

George, C. W., R. A. Susott. Effects of Ammonium Phosphate and Sulfate on the Pyrolysis and Combustion of Cellulose Forest Service Research Paper INT-90, U.S.D.A., 1971. 

The collected data were aimed for the commercial heat treatment of hardboards (24) and for curing processes proposed for some paper grades (4,6,25). They thus refer to quite a mild pyrolysis in air, for a shorter treatment period than some of the data presented here... 

Plot the selectivity to C4H8 as a function of ethane conversion. Does it behave like a secondary or primary product Consult the paper by Dean (1990), and describe additional reactions which lead to molecular weight growth in hydrocarbon pyrolysis systems. While some higher molecular weight products are valuable, the heavier... 

Source Adapted from various sources M. A. Elliot, Ed., Chemistry of Coal Utilization, 2nd Supplementary Volume, Wiley-Interscience, 1981 Cheremis-inoff, N, and P. Cheremisinoff, Hydrodynamics of Gas-Solid Fluidization, Gulf Publishing Co., 1984 Joaquin, R. H., Kinetic and Hydrodynamic Study of Waste Wood Pyrolysis for its Gasification in Fluidized Bed Reactor, European Foundation for Power Engineering, 2002 (http //www.efpe.org/papers.html). 

---