Pyrocatechol violet

Ni indirattri as ellicient as pyrocatechol violet T.A.R. cxlraclion of variadiiiin... 

Pyrocatechol Violet Indicator Solution. Dissolve 0.1 g of the solid dyestuff in 100 mL of water. 

Solvent extraction techniques are useful in the quantitative analysis of niobium. The fluoro complexes are amenable to extraction by a wide variety of ketones. Some of the water-insoluble complexes with organic precipitants are extractable by organic solvents and colorimetry is performed on the extract. An example is the extraction of the niobium—oxine complex with chloroform (41). The extraction of the niobium—pyrocatechol violet complex with tridodecylethylammonium bromide and the extraction of niobium—pyrocatechol—sparteine complex with chloroform are examples of extractions of water-soluble complexes. Colorimetry is performed on the extract (42,43). Colorimetry may also be performed directly on the water-soluble complex, eg, using ascorbic acid and 5-nitrosahcyhc acid (44,45). 

The results of the complexation study of Cu(II), Pb(II), Zn(II), Fe(III), Hg(II), Cd(II), Sn(IV), Zr(IV), Ti(IV) with arsenazo III, sulfonazo III, SPADNS, Eriochrome T, Acid Chrome Dai k Blue, Xylenol Orange, Methyl Thymol Blue, Pyrocatechol Violet, Chrome Azurol S, Eriochrome Cyanin R, Basic Blue K, Methyl Violet, Brilliant Green, Rhodamine C and Astraphoxin in solid phase. The obtained data ai e used for the working out of a new method of metal determination. 

Pyrocatechol Violet (tetraphenolictriphenylmethanesulfonic acid Na salt) [115-41-3] M 386.4, e 1.4 x 1(H at 445nm in acetate buffer pH 5.2-5.4, pKesi(i)>0 (SO3H), pK ,t(2) 9.4, pKEst(3) 13. It was recrystd from glacial acetic acid. Very hygroscopic. Indicator standard for metal complex titrations. [Mustafin et al. Zh Anal Khim 22 1808 1967.]... 

Dipping solution Dissolve 100 mg pyrocatechol violet (pyrocatecholsulfophtha-lein) in 100 ml ethanol. 

Pyrocatechol violet forms colored complexes with a variety of metal ions, the complexes are stable in differing pH ranges. 

Pyrocatechol dioxygenases. 6, 325 Pyrocatechol violet metallochromic indicator, 1,556 Pyrogallol... 

PVC (200 mg) was dissolved in 20 mL THF and precipitated with 50 mL EtOH. Several drops of 0.1 % pyrocatechol violet solution were added to the heated filtrate until a blue colour appeared. This solution was titrated with 0.001 M EDTA until the change via green to yellow. In the presence of Mg, Ca, and Zn, Eriochrome Black was added before titration. 

The selective determination of Cu(II) was accomplished by making use of pyrocatechol violet indicator, dissolved in plasticized PVC membrane as a... 

Figure 19. Chemical structure of pyrocatechol violet (1) and the pyrocatechol violet-tetraoctylammonium ion pair (2).

Murkovic Steinberg I., Lobnik A., Wolfbeis O.S., Characterisation of an optical sensor membrane based on the metal ion indicator Pyrocatechol Violet, Sensors Actuators B. 2003 90 (1-3) 230-235. 

Korenaga et al. [26] have described an extraction procedure for the spectrophotometric determination of trace amounts of aluminium in seawater with pyrocatechol violet. The extraction of ion-associate between the alu-minium/pyrocatechol violet complex and the quaternary ammonium salt,... 

Several ions (e.g., manganese, iron (II), iron (III), cobalt, nickel, copper, zinc, cadmium, lead, and uranyl) react with pyrocatechol violet, and to some extent are extracted together with aluminium. The interferences from these ions and other metal ions generally present in seawater could be eliminated by extraction with diethyldithiocarbamate as masking agent. With this agent most of the metal ions except aluminium were extracted into chloroform, and other metal ions did not react in the amounts commonly found in seawater. Levels of aluminium between 6 and 6.3 pg/1 were found in Pacific Ocean and Japan Sea samples by this method. 

Aluminium Extraction of pyrocatechol violet complex with chloroform Spectrophotometry at 590 nm < 0.1 xg/l [26]... 

The complex of Sn(IV) ions and pyrocatechol violet (2) in a flow system is concentrated on Sephadex QAE A-25 gel and subsequently determined by visible spectrophotometry at 576 nm. The linear range of the method is 2-40 pg/L with LOD 0.3 pg/L27a. 

The metal may he analyzed hy atomic absorption or emission spectrophotometry (at trace levels). Other techniques include X-ray diffraction, neutron activation analysis, and various colorimetric methods. Aluminum digested with nitric acid reacts with pyrocatechol violet or Eriochrome cyanide R dye to form a colored complex, the absorbance of which may be measured by a spectrophotometer at 535 nm. 

Pyrocatechol violet 0.1 g/100 mL solution is stable for several weeks. 

Pyrocatechol violet (Table 12-3) is to be used as a metal ion indicator in an EDTA titration. The procedure is as follows ... 

In addition to the above method, based on the use of pyrocatechol violet, Tecator also describes a flow injection analysis for determining 0.5-0.5mg/l aluminium in soil extracts based on the measurement of the chromazurol-aluminium complex at 570 nm [4,5]. 

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