Pulse amplitude distribution measurement

Figure 2.21 Pulse amplitude distributions measured at various diffraction angles from a sample of distilled water using a chromium anode x-ray tube at 50 kV and 10 mA, a scintillation detector, and a LiF(200) crystal.

Method of Data Processing. The amplitude of the signal pulses depends on the size of the phytoplankters, their trajectory, and their position in the measured volume because of the nonuniformity of the irradiated intensity and the characteristics of the collecting optics (Figure 6). This section presents our method to obtain size information of the particles from the raw data of the pulse-height distribution. 

Figure 8.23 Amplitude or pulse height and time record of signals from the detector is on the left. Transformation of the data into a pulse height distribution is shown on the right. The FWHM measurement is shown for the higher peak. (From Helsen and Kuczumow, used with permission.)...

Using time-resolved crystallographic experiments, molecular structure is eventually linked to kinetics in an elegant fashion. The experiments are of the pump-probe type. Preferentially, the reaction is initiated by an intense laser flash impinging on the crystal and the structure is probed a time delay. At, later by the x-ray pulse. Time-dependent data sets need to be measured at increasing time delays to probe the entire reaction. A time series of structure factor amplitudes, IF, , is obtained, where the measured amplitudes correspond to a vectorial sum of structure factors of all intermediate states, with time-dependent fractional occupancies of these states as coefficients in the summation. Difference electron densities are typically obtained from the time series of structure factor amplitudes using the difference Fourier approximation (Henderson and Moffatt 1971). Difference maps are correct representations of the electron density distribution. The linear relation to concentration of states is restored in these maps. To calculate difference maps, a data set is also collected in the dark as a reference. Structure factor amplitudes from the dark data set, IFqI, are subtracted from those of the time-dependent data sets, IF,I, to get difference structure factor amplitudes, AF,. Using phases from the known, precise reference model (i.e., the structure in the absence of the photoreaction, which may be determined from... 

CSIRO Minerals has developed a particle size analyzer (UltraPS) based on ultrasonic attenuation and velocity spectrometry for particle size determination [269]. A gamma-ray transmission gauge corrects for variations in the density of the slurry. UltraPS is applicable to the measurement of particles in the size range 0.1 to 1000 pm in highly concentrated slurries without dilution. The method involves making measurements of the transit time (and hence velocity) and amplitude (attenuation) of pulsed multiple frequency ultrasonic waves that have passed through a concentrated slurry. From the measured ultrasonic velocity and attenuation particle size can be inferred either by using mathematical inversion techniques to provide a full size distribution or by correlation of the data with particle size cut points determined by laboratory analyses to provide a calibration equation. 

The noise of the charge-sensitive preamplifier depends on three parameters the noise of the input FET, the input capacitance C , and the resistance connected to the input. The noise can be determined by injecting a charge Q, equivalent to E, into the preamplifier and measuring the amplitude of the generated pulse. Commercial preamplifiers are provided with a test input for that purpose. In general, the noise expressed as the width (keV) of a Gaussian distribution increases as input capacitance increases (Fig. 10.36). 

Either two or more molecular levels of a molecule are excited coherently by a spectrally broad, short laser pulse (level-crossing and quantum-beat spectroscopy) or a whole ensemble of many atoms or molecules is coherently excited simultaneously into identical levels (photon-echo spectroscopy). This coherent excitation alters the spatial distribution or the time dependence of the total, emitted, or absorbed radiation amplitude, when compared with incoherent excitation. Whereas methods of incoherent spectroscopy measure only the total intensity, which is proportional to the population density and therefore to the square ir of the wave function iff, the coherent techniques, on the other hand, yield additional information on the amplitudes and phases of ir. 

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