Pulping modelling

Little work has been carried out so far to characterize the lignin structures present in various types of high yield pulps. Model compound experiments have... 

Chemistry ofDelig niiic tion. The chemistry of delignification is complex and, despite the extensive Hterature, not completely understood. A variety of lignin model compounds have been studied and the results compared with the observed behavior of lignin during pulping (1,10—12,16). 

The stoichiometric relationship between chlorine dioxide added and color removed during bleaching is nonlinear, but it is independent of temperature, pH, and pulp concentration under conditions normally used. Models used to explain the kinetics and stoichiometry show a strong dependence on chromophore concentration that probably results from differences in the reaction rates of the various chromophores present in the pulps (80). 

To illustrate how different m(X ) and x may happen to be, let s consider as a specific example (others can be found in Saraiva and Stephanopoulos, 1992c) a Kraft pulp digester. The performance metric y, that one wishes to minimize, is determined by the kappa index of the pulp produced and the cooking yield. Two decision variables are considered H-factor (xj), and alkali charge (X2). Furthermore, we will assume as perfect an available deterministic empirical model (Saraiva and Stephanopoulos, 1992c), /, which expresses y as function of x, i.e., that y =/(xi, X2) is perfectly known. 

In order to verify how close to a known true optimum the final solutions found by our learning methodology happen to be, we will describe here its application to a pulp digester, for which a perfect empirical model /(x) is assumed to be available. Other applications are discussed in Saraiva and Stephanopoulos (1992c). 

The overall system that we will analyze comprises the unbleached Kraft pulp line, chemicals and energy recovery zones of a specific paper mill (Melville and Williams, 1977). We will employ a somewhat simplified but still realistic representation of the plant, originally developed in a series of research projects at Purdue University (Adler and Goodson, 1972 Foster et al., 1973 Melville and Williams, 1977). The records of simulated operation data, used to support the application of our learning architecture, were generated by a reimplementation, with only minor changes, of steady-state models (for each individual module and the system as a... 

Ralph, J. Lignin model quinone methides—facts and fallacies. In Proceedings of the Third International Symposium of Wood and Pulping Chemistry, Vancouver, BC, Canada, Chemical Institute of Canada (CIC), and Canadian Pulp and Paper Association (CPPA), Canada. 1985. 

Cotton paper (100%) obtained from Mead Corporation in South Lee, Massachusetts, was pulped at Krofta Engineering Corporation (KEC), Lenox, MA.59 A known amount of pulp was suspended in tap water to determine the percent recovery by a circular DAF cell (Model Supracell Type 3 diameter = 0.91 m [3 ft] depth = 55.88 cm [22 in.] flow = 45L/min [12gal/min]). The initial total... 

In a report comparing community responses to low-level exposure to a mixture of air pollutants from pulp mills, Jaakkola et al. (1990) reported significant differences in respiratory symptoms between polluted and unpolluted communities. The pollutant mixture associated with the pulp mills included particulates, sulfur dioxide, and a series of malodorous sulfur compounds. Major contributors in the latter mixture include hydrogen sulfide, methyl mercaptan, and methyl sulfides. In this study the responses of populations from three communities were compared, a nonpolluted community, a moderately polluted community, and a severely polluted community. Initial exposure estimates were derived from dispersion modeling these estimates were subsequently confirmed with measurements taken from monitoring stations located in the two polluted communities. These measurements indicated that both the mean and the maximum 4-hour concentrations of hydrogen sulfide were higher in the more severely polluted community (4 and 56 g/m3 2.9 and 40 ppb) than in the moderately polluted one (2 and 22 g/m3 1.4 and 16 ppb). Particulate measurements made concurrently, and sulfur dioxide measurements made subsequently, showed a similar difference in the concentrations of these two pollutants between the two polluted communities. 

Dayal, B. S., MacGregor, J. F., Taylor, P. A., Kildaw, R., and Marcikio, S., Application of Feedforward Neural Networks and Partial Least Squares Regression for Modelling Kappa Number in a Continuous Kamyr Digester, Pulp Paper Can., 95(1) 26 (1994)... 

RP-HPLC methods have been frequently applied for the investigation of various chemical, biochemical and biophysical processes in in vitro model systems. Thus, the separation of new compounds achieved by enzymatic oxidation of phloridzin was carried out by semi-preparative RP-HPLC. Phloridzin was incubated with a polyphenol oxidase prepared from apple pulp for 6h at 30°C under air agitation. After incubation the suspension was filtered, stabilized by NaF and injected into the RP-HPLC column using diluted acetic acid-ACN gradient. The new compounds were isolated and identified by NMR and MA techniques. The proposed mechanism of the formation of new phloridzin derivatives 3 and 4 is shown in Fig. 2.159. The results illustrate that RP-HPLC can be successfully used for the study of enzymatic processes in model systems [331],... 

Abstract In the beginning, the mixed potential model, which is generally used to explain the adsorption of collectors on the sulphide minerals, is illustrated. And the collector flotation of several kinds of minerals such as copper sulphide minerals, lead sulphide minerals, zinc sulphide minerals and iron sulphide minerals is discussed in the aspect of pulp potential and the nature of hydrophobic entity is concluded from the dependence of flotation on pulp potential. In the following section, the electrochemical phase diagrams for butyl xanthate/water system and chalcocite/oxygen/xanthate system are all demonstrated from which some useful information about the hydrophobic species are obtained. And some instrumental methods including UV analysis, FTIR analysis and XPS analysis can also be used to investigated sulphide mineral-thio-collector sytem. And some examples about that are listed in the last part of this chapter. 

One modification that pertains to the present book is the role of anthraquinone (AQ) in the pulping process. Under conditions of alkaline pulping, carbohydrates in the wood reduce AQ into an anion-radical (AQ ). Experiments with lignin quinonemethide as a model compound showed that the AQ anion-radical caused fragmentation of the quinonemethide (Scheme 8.23). 

Bourbonnais, R. Paice, M.G. Freiermuth, B. Bodie, E. Bomeman, S. Reactivities of various mediators and laccases with Kraft pulp and lignin model compounds. Appl. Environ. Microbiol. 1997, 63, 4627-4632. 

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