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Primary characteristics chemical compositions

Classification system for chondrites, adapted from Van Schmus and Wood (1967). A meteorite is classified by identifying its chemical group and petrologic type. Approximate temperatures for metamorphism or alteration are shown at the bottom. The relative abundances of meteorites assigned to various petrologic types are indicated by the shaded proportion of each box (data from Scott and Krot, 2004). [Pg.167]


Variables It is possible to identify a large number of variables that influence the design and performance of a chemical reactor with heat transfer, from the vessel size and type catalyst distribution among the beds catalyst type, size, and porosity to the geometry of the heat-transfer surface, such as tube diameter, length, pitch, and so on. Experience has shown, however, that the reactor temperature, and often also the pressure, are the primary variables feed compositions and velocities are of secondary importance and the geometric characteristics of the catalyst and heat-exchange provisions are tertiary factors. Tertiary factors are usually set by standard plant practice. Many of the major optimization studies cited by Westerterp et al. (1984), for instance, are devoted to reactor temperature as a means of optimization. [Pg.705]

The primary characteristic necessary for a liner, cover, or cutoff wall is low permeability, which essentially enables them to slow down the seepage or diffusion of chemicals. Clay is therefore the main material used to construct these containment systems. The thickness and chemical compatibility of containment systems are of concern in assessing the performance of a system. For example, clay liners are constructed as a simple liner that is 2 to 5 ft thick. In composite and double liners, the compacted clay layers are usually between 2 and 5 ft thick, depending on the characteristics of the underlying geology and the type of liner to be installed. Regulations specify that the clay used can only allow water to penetrate at a rate of less than 1.2 in./yr. However, the effectiveness of clay liners can be reduced by fractures induced by freeze-thaw cycles, drying out, and the presence of some chemicals. [Pg.190]

Elemental composition K 56.58%, C 8.69%, O 34.73%. The salt can be identified from its physical and chemical properties. Its aqueous solution is highly alkaline. Reaction with dilute acids evolves CO2 with effervescence. The latter can be identified by GC-TCD or GC/MS. The primary characteristic mass ion for CO2 is 44. Also, CO3 2- anion can be measured by ion chromatography. Potassium can be analyzed by various instrumental and wet methods (see Potassium). [Pg.744]

The formation of copolymer by polycondensation reaction was proved by IR analysis. The spectra show absorption band at 1470, 1640, 2990, and 3100 cm-1 characteristic of—C—O—NH— groups, at 3300 cm-1 for imine groups and at 920 cm-1 for primary amine groups. From the point of view of chemical composition, the polycondensation products are composed by a fraction insoluble in... [Pg.25]

The model of systems with random fluxes can be applied to solid materials prepared from high-dispersion primary materials in a fluidized bed where the characteristics of the involved solid and fluid (their pressure, temperature, chemical composition, etc.) do not change significantly with time. [Pg.55]

The fundamental thermodynamic properties that arise in connection with the first and second laws of thermodynamics are internal energy and entropy. These properties together with the two laws for which they are essential apply to all types of systems. However, different types of systems are characterized by different sets of measurable coordinates or variables. The type of system most commonly encountered in chemical technology is one for which the primary characteristic variables are temperature T, pressure P, molar volume V, and composition, not all of which are necessarily independent. Such systems are usually made up of fluids (liquid or gas) and are called PVT systems. [Pg.648]

The primary structure of macromolecules is defined as the sequential order of monomers connected via covalent chemical bonds. This structural level includes features such as chain length, order of monomer attachment in homopolymers (head-to-head, head-to-tail placement), order of monomer attachment in various copolymers (block copolymers, statistical and graft copolymers, chemical composition of co-monomers), stereoregularity, isomers, and molecular topology in different branched macromolecules and molecular networks. Structure at this primary level can be manipulated by polymer synthesis [4]. With AFM it is possible to visualize, under certain conditions, single macromolecules (Fig. 3.2) and it is even possible to manipulate these (i.e. push with AFM tips). Characteristics of chain-internal... [Pg.81]

The molecular and chemical composition of the polymer will influence its solubility characteristics. Park (A) has discussed the solvent-resin relationships in detail in "Advances in Chemistry Series 12A." They can be summarized as follows Aromatics such as toluene and xylene are primary solvents for only the most soluble of the vinyl resins. The homopolymers have very slight aromatic tolerances. Aliphatic-type solvents are not considered good solvents for vinyls. As with the aromatics, the extremely soluble resins will tolerate aliphatic solvents if a strong ketone is present. Only fair aliphatic tolerance is obtained with the low molecular weight high vinyl chloride content solution polymers. Aliphatic tolerance of the homopolymers is practically nil. The alcohol tolerance of vinyl resins is very limited. Recent studies with the high solubility type metal adhesion copolymers indicate that appreciable quantities of 2-propanol may be used, if a strong ketone solvent is used. [Pg.1218]

The fraction of singlet-correlated pairs is a very important characteristic of primary radiation chemical events. The scale of magnetic field effect as well as the product composition are the functions of this quantity. [Pg.74]

A major but defining difference between polymers and biopolymers can be found in their structures. Polymers, including biopolymers, are made of repetitive units called monomers. Biopolymers often have a well-defined structure, though this is not a defining characteristic (e.g. lignocellulose). The exact chemical composition and the sequence in which these units are arranged is called the primary structure in the case of proteins. Many biopolymers spontaneously fold into characteristic compact shapes which determine their biological functions and depend in a complicated way on their primary structures. In contrast, most synthetic polymers have much simpler and more random (or stochastic) structures [7, 8]. [Pg.462]


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