Pressurization experiments, silicon

In particular, phase transformations under contact loading need a more detailed investigation. Both static and dynamic interactions between hard surfaces may result in phase transformations. Hydrostatic and deviatoric stresses must be taken into account and phase transformations in contact loading can be described as deformation-induced transformations. At the same time, the transformation pressures for silicon obtained in indentation tests are in good agreement with the results from high-pressure cell experiments, which utilize hydrostatic loading. 

Fig. 4. Calculated phase diagram of silicon including the diamond, / -tin, and the simple hexagonal (sh) structure, which was discovered recently (In high pressure experiments, Refs. 142 and 143). The c/a ratios of both metallic phases are calculated at each point shown by zeroing the shear stress. The / -tin to sh transition pressure is 143 Kbar, in good agreement with experiment, (from Ref. 32)...

Very high pressure and temperature experiments with the Sawaoka fixture on Nb-Si powder mixtures show that the silicon melted but the higher melt temperature niobium did not. Under these conditions, only chemical reaction... 

The metal itself, having an appreciable vapour pressure, is also toxic, and produces headaches, tremors, inflammation of the bladder and loss of memory. The best documented case is that of Alfred Stock (p. 151) whose constant use of mercury in the vacuum lines employed in his studies of boron and silicon hydrides, caused him to suffer for many years. The cause was eventually recognized and it is largely due to Stock s publication in 1926 of details of his experiences that the need for care and adequate ventilation is now fully appreciated. 

One of the possible ways to account for the effect of roughness on the pressure drop in a micro-tube is to apply a modified-viscosity model to calculate the velocity distribution. Qu et al. (2000) performed an experimental study of the pressure drop in trapezoidal silicon micro-channels with the relative roughness and hydraulic diameter ranging from 3.5 to 5.7% and 51 to 169 pm, respectively. These experiments showed significant difference between experimental and theoretical pressure gradient. 

FIGURE 26.9 Newton s interference fringes formed between a glass plate lubricated with a silicon oil film and a mbber sphere sliding on it, showing the deformation of the sphere through the hydrodynamic pressure exerted on the mbber sphere. (From Roberts, A.D., The Physics of Tire Traction, Theory and Experiment, Hayes, D.L. and Browne, A.L. (eds.). Plenum Press, New York/London, 1974.)... 

In the third study, Miyazaki and Henry (1978) carried out vapor bubble growth experiments with water drops in hot silicone oil under various pressures of argon gas. As conducted, the oil temperature was set so that the interface temperature was below the homogeneous nucleation temperature of water. When bubbles did appear, their growth was followed by... 

Fig. 27. The SiF pressure as a silicon surface is rotation into a beam of XeFj molecules with an without Ar ion bombardment. The SiF pressure was determined mass spectrometrically. The ratios of the pressure increases (top curve to bottom curve) indicate the magnitude of ion-assisted etching. The experiments were performed in a standard UHV system of the type often used for surface experiments. The experimental arrangement was similar to that described in Ref. )...

The best results were obtained with compound 21 that exhibited high vapor pressure and low decomposition temperature (<523 K). Various CVD conditions were applied and gave in all cases shiny, dark-brown deposits.43 XRD and XPS analyses of the deposits indicated the presence of a vanadium carbonitride phase with little contamination from oxygen and free carbon. The films were less adherent on steel substrates than on silicon ones. The steel substrates seemed to suffer corrosion due to the presence of Cl-containing species. We had noticed the same feature in the case of Cl-containing precursors to vanadium carbide. Therefore, in order to increase the volatility of compound 23 and to reduce the Cl content of the molecule, we prepared compounds 24 and 25. Unfortunately, the yields obtained in their syntheses were much too low to permit TG and CVD experiments. 

The semipermeable membrane proposed for the demineralization of sea water is based on H. L. Calendar s theory that osmosis takes place through the membrane as vapor, condensing at the opposite membrane surface. The actual membrane being used consists of two sheets of untreated cellophane separated by a water-repellent powder, such as a silicone-coated pumice powder. The vapor gap is maintained by an air pressure in excess of the pressure on the sea water and the cellophane sheets support the capillary surfaces, which will withstand pressures up to 1500 p.s.i. A number of successful experiments are reported with over 95% desalinization. The present effort is directed toward obtaining reproducible experimental results and better methods of fabricating the vapor gap. 

Upon completion of these experiments it became apparent that the differential pressure in the gap was a more important variable than the water repellency of the powder. Hence a 3 X 3 orthogonal set of experiments was planned, using nylon hair nets as the spacer instead of silicone-coated pumice. It was believed that this design would be more reproducible. 

In a typical experiment, 4.63 g. (0.025 mole) of niobium(V) fluoride is mixed with 0.348 g. (0.012 mole) of -200-mesh silicon and loaded into the reactor inside a glove box under dry nitrogen. The assembled reactor is connected to a helium tank and repeatedly pressurized and depressurized to rid the system of air. The entire system is pressurized to 50 p.s.i., the Monel reactor valve is closed, and the reaction chamber is placed in a vertical furnace at 350°C. The pressure in the external lines is left at 50 p.s.i. to prevent entry of air. 

Example 11.4. McGuiggan et al. [492] measured the friction on mica surfaces coated with thin films of either perfluoropolyether (PFPE) or polydimethylsiloxane (PDMS) using three different methods The surface forces apparatus (radius of curvature of the contacting bodies R 1 cm) friction force microscopy with a sharp AFM tip (R 20 nm) and friction force microscopy with a colloidal probe (R 15 nm). In the surface force apparatus, friction coefficients of the two materials differed by a factor of 100 whereas for the AFM silicon nitride tip, the friction coefficient for both materials was the same. When the colloidal probe technique was used, the friction coefficients differed by a factor of 4. This can be explained by the fact that, in friction force experiments, the contact pressures are much higher. This leads to a complete penetration of the AFM tip through the lubrication layer, rendering the lubricants ineffective. In the case of the colloidal probe the contact pressure is reduced and the lubrication layer cannot be displaced completely. 

The cubic y-modification has been recently observed under a pressure of 15 GPa and temperatures above 2000 K by the laser heating technique in a diamond cell [23] and in shock-wave compression experiments with pressures >33 GPa at 1800 K and >50 GPa at 2400 K [29]. This modification is often designated as the c-modification in the literature in analogy to the cubic boron nitride (c-BN). It has a spinel-type structure in which two silicon atoms are octahedrally coordinated by six nitrogen atoms, one silicon atom is coordinated tetrahedrally by four nitrogen atoms (Fig. 3c). The atomic coordinates for the cubic modification are given in Table 2. From calculations it is shown that this structure should have a high hardness similar to that of diamond and c-BN [23]. 

Equation (2.79) expresses the driving force in pervaporation in terms of the vapor pressure. The driving force could equally well have been expressed in terms of concentration differences, as in Equation (2.83). However, in practice, the vapor pressure expression provides much more useful results and clearly shows the connection between pervaporation and gas separation, Equation (2.60). Also, the gas phase coefficient, is much less dependent on temperature than P L. The reliability of Equation (2.79) has been amply demonstrated experimentally [17,18], Figure 2.13, for example, shows data for the pervaporation of water as a function of permeate pressure. As the permeate pressure (p,e) increases, the water flux falls, reaching zero flux when the permeate pressure is equal to the feed-liquid vapor pressure (pIsal) at the temperature of the experiment. The straight lines in Figure 2.13 indicate that the permeability coefficient d f ) of water in silicone rubber is constant, as expected in this and similar systems in which the membrane material is a rubbery polymer and the permeant swells the polymer only moderately. 

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