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Potential clustering

While an exact number of site clusters has not been proposed, the authors consider from approximately 3 to 10 clusters of sites to be appropriate. These clusters should represent different ecoregions with different ecological characteristics as well as different loadings (both in amount and source) of mercury deposition. Care should be taken to monitor different types of water bodies and watersheds (e.g., seepage lakes, drainage lakes, old reservoirs, rivers, and estuaries). Areas that should be considered as potential cluster site locations include lakes in northern New England/the Adirondacks, lakes in the upper Midwest, rivers and streams in the southeastern coastal plain, lakes in south-central and southeastern Canada, western... [Pg.200]

Tables II and III list the numbers of electrons provided by various potential cluster units, assuming that the skeletal atoms make available three AO s apiece for skeletal bonding, and use their remaining valence shell orbital(s) to bond ligands to the cluster. For example, a main group element E (Table II) such as boron can make three AO s available for cluster bonding if it uses its one remaining valence shell AO (an inert... Tables II and III list the numbers of electrons provided by various potential cluster units, assuming that the skeletal atoms make available three AO s apiece for skeletal bonding, and use their remaining valence shell orbital(s) to bond ligands to the cluster. For example, a main group element E (Table II) such as boron can make three AO s available for cluster bonding if it uses its one remaining valence shell AO (an inert...
The perturbation theories [2, 3] go a step beyond corresponding states the properties (e.g., Ac) of some substance with potential U are related to those for a simpler reference substance with potential Uq by a perturbation expansion (Ac = Aq + A + Aj + ). The properties of the simple reference fluid can be obtained from experimental data (or from simulation data for model fluids such as hard spheres) or corresponding states correlations, while the perturbation corrections are calculated from the statistical mechanical expressions, which involve only reference fluid properties and the perturbing potential. Cluster expansions involve a series in molecular clusters and are closely related to the perturbation theories they have proved particularly useful for moderately dense gases, dilute solutions, hydrogen-bonded liquids, and ionic solutions. [Pg.131]

The risk of vaccine-associated poliomyelitis has remained exceedingly low but stable since the mid-1960s. In all, 260 cases of vaccine-associated poliomyelitis were reported in the USA between 1961 and 1989. Cases of vaccine-associated poliomyelitis appeared to occur randomly in time and space. One potential cluster of vaccine-associated poliomyelitis consisting of six cases occurring over an 18-month period in Indiana was investigated during the period 1980-89. These cases were not shown to be epidemiologically related. [Pg.2884]

Bifunctional Catalysts. One reason invoked (there are others) for why metal particles with high dispersion are desirable for catalysis is that the ratio of surface metal atoms to total number of atoms is quite high. Consider the potential cluster size for two zeolites faujasite and ZSM-12. Faujasite has supercages, which for the purposes of this question can be described as spherical with a diameter of 12 A, and ZSM-12 has a one-dimensional elliptical pore structure of dimensions 5.6 x 6.0 A. Assuming the metal atoms of inteiest have a diameter of 1.0 A and the cluster has a packing fraction corresponding to an FCC structure (0.74), estimate the number of atoms in a metal cluster in each of the two zeolites mentioned above. [Pg.357]

The model mentioned for clnstering and declnstering and the influence of moisture on a may be valid only if there is snfflcient time during the low-field period for solvent molecules to encounter the ion. At 50 ppm water in air at ambient temperature and pressure, there are 1.3 x 10 molecules cm. If we take a typical collision rate constant of about 1 x 10" cm molecule" s for ion-neutral encounters, and knowing that the concentration of ions is far less than that of water, the time between collisions is approximately l/k[H20] = 0.8 ps. In the low-field period of abont 1.6 ps, an ion will undergo approximately two collisions with water molecules, a sufficient nnmber if the association reaction is efficient, to change the mass and the cross section of the ion. At elevated water concentrations, the nnmber of collisions in the low-field period will increase proportionately and reach 400 at 10,000 ppm. With an increase of water concentration, the potential cluster size will increase, but the strength of the... [Pg.233]

In the pages that follow, we summarize methods for the synthesis of clusters in cages, their structural characterization, reactivity, and catalytic and other properties. The literature of encaged clusters is limited to clusters in zeolites, and thus little is included here about other molecular sieves or potential cluster hosts. The literature dtations are not comprehensive rather, examples are dted to illustrate prindples and to emphasize the unique properties of encaged clusters and the... [Pg.304]

The situation is complicated by the fact that the master process cannot send a new cluster center to another slave process until it is established that the potential cluster center does not belong to a cluster defined by a previous cluster center. As long as each slave process performs the comparisons in order, the master process will be able to deduce that the next unclustered point should be regarded as a new cluster center as soon as aU active slave processes have reported progress beyond that point. To facilitate this process, each slave process reports its progress back to the master process at well-defined intervals, in addition to those instances where a cluster match is found. [Pg.397]

Abstract. Colors for one high-redshift target field are presmted fitom out sample of potential cluster fields. This field, 3C208.1, was observed in R (rest U) and H (rest R) bands. From the colors of the objects within an Abell core radius, it is nnKIcdy that 3C208.1 resides in a cluster at s=1.02. [Pg.135]


See other pages where Potential clustering is mentioned: [Pg.13]    [Pg.459]    [Pg.293]    [Pg.459]    [Pg.156]    [Pg.459]    [Pg.21]    [Pg.433]    [Pg.295]    [Pg.126]    [Pg.20]    [Pg.500]    [Pg.133]    [Pg.339]    [Pg.363]    [Pg.84]    [Pg.22]    [Pg.500]    [Pg.90]    [Pg.57]    [Pg.494]    [Pg.947]   
See also in sourсe #XX -- [ Pg.57 ]




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Argon clusters additional potentials

Calculated using coupled-cluster potential energy surface

Cluster compounds ionization potential

Cluster models potential energy surfaces

Cluster potential

Cluster potential

Cluster redox potential, determination

Cluster redox potential, determination kinetics methods

Clusters exchange-correlation potential

Clusters external potential

Clusters high-potential iron proteins

Clusters photoionization potentials

Clusters potential energy surfaces , theoretical

Clusters redox potentials

Coupled cluster method ionization potentials

Coupled cluster method potential energy surfaces

Coupled-cluster theory potential energy curves

Effective core potentials coupled-cluster

Effective core potentials coupled-cluster spin-orbit effects

Effective core potentials coupled-cluster theory

Fock-space coupled cluster method ionization potentials

High-potential iron proteins cluster stability

Hydrated silver clusters, redox potentials

Intermolecular potentials clusters

Ionization potential, clusters

Ionization potential, clusters atoms

Ionization potentials coupled-clusters

Ionization potentials, metal clusters

Jellium model, metal cluster potentials

Lennard-Jones potential, water molecule clustering

Metallic clusters potential determination

Metals cluster potentials

Models metal cluster potentials

Molecular potential coupled-cluster theories

Nuclearity silver cluster redox potential

Platinum catalysts cluster potentials

Potential energy coupled-clusters

Potential energy surface coupled-cluster [CCSD

Potential energy surfaces coupled-cluster theory

Redox potential charged cluster

Redox potentials of oligomeric metal clusters

Relativistic Ab-Initio Model Potential Calculations for Molecules and Embedded Clusters

Structural transition mechanisms, potential clusters

Water clusters, potential energy surfaces

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