Polyanilines applications

MacDiarmid, A.G., et al. 1984. Aqueous chemistry and electrochemistry of polyacetylene and polyaniline Application to rechargeable batteries. Polym Prep Am Chem Soc Div Polym Chem 25 248. 

Polymers with n-conjugated backbones are an important class of materials that have captured the imagination of the scientific community due to their remarkable properties and exciting applications [91-95]. While most of the work on n-conjugated polymers has focused on all-carbon systems, there has been considerable interest in incorporating heteroatoms into the n-conjugated backbone (i.e.,polythiophene, polypyrrole, polyaniline) to tune their properties. 

Polyacetylene proved qnite incapable of working in a realistic battery context, and MacDiarmid did not mention this application in his Nobel lectnre of October, 8 2000. However, other materials have proven their worth, and prototype batteries made with polypyrrole and polyaniline as cathodes (positives), and metal or lithiated carbon materials as anodes (negatives), have been demonstrated in dne conrse by the Japanese and German indnstry, for instance. Novdk et al. (1997) have reviewed the field in detail. 

PP-g-MA) silicate nanocomposites and intercalated thermoset silicate nanocomposites for flame-retardant applications were characterised by XRD and TEM [333], XRD, TEM and FTIR were also used in the study of ID CdS nanoparticle-poly(vinyl acetate) nanorod composites prepared by hydrothermal polymerisation and simultaneous sulfidation [334], The CdS nanoparticles were well dispersed in the polymer nanorods. The intercalation of polyaniline (PANI)-DDBSA (dodecylbenzene-sulfonate) into the galleries of organo-montmorillonite (MMT) was confirmed by XRD, and significantly large 4-spacing expansions (13.3-29.6A) were observed for the nanocomposites [335],... 

Electronically conducting polymers (ECPs) such as polyaniline (PANI), polypyrrole (PPy) and po 1 y(3.4-cthy 1 cncdi oxyth iophcnc) (PEDOT) have been applied in supercapacitors, due to their excellent electrochemical properties and lower cost than other ECPs. We demonstrated that multi-walled carbon nanotubes (CNTs) prepared by catalytic decomposition of acetylene in a solid solution are very effective conductivity additives in composite materials based on ECPs. In this paper, we show that a successful application of ECPs in supercapacitor technologies could be possible only in an asymmetric configuration, i.e. with electrodes of different nature. 

As our quantum-chemical calculations show, similar transformation and delocalization of bonds takes place in the conductive forms of some other types of CPs (polyaniline, polypyrolle, etc.). Delocalization of chemical bonds after activation leads to appearance of an electronic conductivity in such types of conducting polymers and creates prerequisites for their application as electrode materials of electrochemical power sources. Such activation can be stimulated by intercalation of ions, applying the potential, and by use of some other low energetic factors. 

The application of conducting polymers such as polyaniline, polypyrrole, and polythiophene for immobilizing capture antibodies in immunoassay systems is widespread. 

Polyaniline (PAni, PANI), 73 550 22 207t. See also PAni/V205 entries applications, 7 538... 

Sheng, K. Bai, H. Sun, Y. Li, C. Shi, G., Layer-by-layer assembly of graphene/polyaniline multilayer films and their application for electrochromic devices. Polymer 2011. 

Another conducting polymer of interest for electrochemical applications is polyaniline ... 

Confinement of ion-radicals considerably changes their reactivity. What is more important for practical applications is that the confinement increases the ion-radical stability. For instance, the cation-radicals of polyanilines (emeraldines) sharply enhance their thermodynamic and kinetic stabilities when they are formed encapsulated in cucurbituril (Eelkema et al. 2007). Emeraldines have electric condnctivity as high as 1 X 10 cm (Lee et al. 2006). Encapsulation of emer-... 

Polyacetylene has good inert atmospheric thermal stability but oxidizes easily in the presence of air. The doped samples are even more susceptible to air. Polyacetylene films have a lustrous, silvery appearance and some flexibility. Other polymers have been found to be conductive. These include poly(p-phenylene) prepared by the Freidel-Crafts polymerization of benzene, polythiophene and derivatives, PPV, polypyrrole, and polyaniline. The first polymers commercialized as conductive polymers were polypyrrole and polythiophene because of their greater stability to air and the ability to directly produce these polymers in a doped form. While their conductivities (often on the order of 10" S/m) are lower than that of polyacetylene, this is sufficient for many applications. 

There is a large potential for conducting polymers as corrosion-inhibiting coatings. For instance, the corrosion protection ability of polyaniline is pH-dependent. At lower pH polyaniline-coated steel corrodes about 100 times more slowly than noncoated steel. By comparison, at a pH of about 7 the corrosion protection time is only twice for polyaniline-coated steel. Another area of application involves creation of solid state rechargeable batteries and electrochromic cells. Polyheterocycles have been cycled thousands of times with retention of over 50% of the electrochromic activity for some materials after 10,000 cycles. IR polarizers based on polyaniline have been shown to be as good as metal wire polarizers. 

Boyle A, Genies EM, Lapkowski M. Application of electronic conducting polymers as sensors— polyaniline in the solid-state for detection of solvent vapors and polypyrrole for detection of biological ions in solutions. Synth Met 1989 28 C769-C774. 

Li D, Huang J, Kaner RB (2009) Polyaniline nanofibers a unique polymer nanostructure for versatile applications. Acc Chem Res 42 135... 

MacDiarmid AG, Epstein AJ (1997) Application of thin films of polyaniline and polypyrrole in novel light-emitting devices. ACS Symp Ser 672 395 15... 

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