Piezoelectric strain coefficient matrix

The piezoelectric strain coefficients now take the form d and the relation between the applied stress, o- , and induced polarization, P,-, can be expressed in final matrix-like form as ... 

Pyro- and Piezoelectric Properties The electric field application on a ferroelectric nanoceramic/polymer composite creates a macroscopic polarization in the sample, responsible for the piezo- and pyroelectricity of the composite. It is possible to induce ferroelectric behavior in an inert matrix [Huang et al., 2004] or to improve the piezo-and pyroelectricity of polymers. Lam and Chan [2005] studied the influence of lead magnesium niobate-lead titanate (PMN-PT) particles on the ferroelectric properties of a PVDF-TrFE matrix. The piezoelectric and pyroelectric coefficients were measured in the electrical field direction. The Curie point of PVDF-TrFE and PMN-PT is around 105 and 120°C, respectively. Different polarization procedures are possible. As the signs of piezoelectric coefficients of ceramic and copolymer are opposite, the poling conditions modify the piezoelectric properties of the sample. In all cases, the increase in the longitudinal piezoelectric strain coefficient, 33, with ceramic phase poled) at < / = 0.4, the piezoelectric coefficient increases up to 15 pC/N. The decrease in da for parallel polarization is due primarily to the increase in piezoelectric activity of the ceramic phase with the volume fraction of PMN-PT. The maximum piezoelectric coefficient was obtained for antiparallel polarization, and at < / = 0.4 of PMN-PT, it reached 30pC/N. 

When written in matrix form these equations relate the properties to the crystallographic directions. For ceramics and other crystals the piezoelectric constants are anisotropic. For this reason, they are expressed in tensor form. The directional properties are defined by the use of subscripts. For example, d i is the piezoelectric strain coefficient where the stress or strain direction is along the 1 axis and the dielectric displacement or electric field direction is along the 3 axis (i.e., the electrodes are perpendicular to the 3 axis). The notation can be understood by looking at Figure 31.19. 

The constants of proportionality d and e are called piezoelectric stress and strain coefficients. The stress and strain forces are represented by matrix quantities, and the coefficients are tensor quantities. A tensor mathematically represents the fact that the polarization can depend on the stress or strain in more than one direction. This is also true for the relationship between the stress or strain and the electric field. Many other physical properties in crystals also exhibit this nature, which is called anisotropy. Thus when a property is anisotropic, its value depends on the direction of orientation in the crystal. For the direct piezoelectric effect, the total polarization effect is the sum of these two contributions, an applied electric field and applied mechanical force. Based on the relationship between the electric displacement and the electric polarization it is then possible to write equations that relate the displacement D to the applied stress or strain. Electric displacement is the quantity that is preferred in experiment and engineering. 

Here D is the vector of the dielectric displacement (size 3x1, unit C/m ), S is the strain (size 6x1, dimension 1), E is a vector of the electric field strength (size 3x1, unit V/m) and T is a vector of the mechanical tension (size 6x1, unit N/m ). As the piezoelectric constants depend on the direction in space they are described as tensors e- is the permittivity constant also called dielectric permittivity at constant mechanical tension T (size 3x3, unit F/m) and 5 , is the elastic compliance matrix (size 6x6, unit m /N). The piezoelectric charge coefficient df " (size 6x3, unit C/N) defines the dielectric displacement per mechanical tension at constant electrical field and (size 3x6, unit m/V) defines the strain per eiectric fieid at constant mechanical tension [84], The first equation describes the direct piezo effect (sensor equation) and the second the inverse piezo effect (actuator equation). 

The independerrt componerrt s stmctrrre of the piezoelectric coefficient is more clearly seen in rrratrix than in tensor notation. Symmetry of the piezoelectric tensor reflects syrrrmetry of mechanical stress/strain (they are secorrd-rarrk syrrrmet-rical tensors). Piezoelectric coefficient is therefore third-rarrk terrsor syrrrmetrical with respect to the permutation of two indexes. Piezoelectric coeffiderrts satisfy following relations between tensor dyk and matrix di coefficients... 

Since the stress and strain tensors are symmetric. the piezoelectric coefficients can be converted from tensor to matrix notation. Table 13 provides the piezoelectric matrices for a-quartz together with several values rfyk and Cjjk. including the corresponding temperature coefficients [259], [261]. 

The subscripts i and / take values 1,..., 6 following the convention in Fig. 5.6, with Ti, T2 and the tension stresses parallel to the 1, 2 and 3 axes respectively, and T, and T(, the shear stresses around the 1,2 and 3 axes. Similarly, Sj, S2, S3 are the relative tension strains and S4, S5, the shear strains. Therefore, like the piezoelectric coefficients, is assigned a matrix related to the crystal symmetry of the material ... 

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