Phosphines nitrato

The complex [Co(dmgh)(NO)] would be expected to react in the same fashion as the compounds just discussed, but under comparable conditions (e.g., in the presence of Lewis bases) it gives a mixture of nitrato and nitro products (192). The factors that infiuence the proportion of nitro and nitrato products have not been established by mechanistic studies, but a possible pathway involves the isomerization of the peroxy intermediate (35) to the nitrato species (37), as indicated in Fig. 20, or by further oxidation of the nitro product. Recent studies (193) have shown that the nitro complex is a reactive intermediate in the formation of [RuCl(N03)(bpy)2]. Tertiary phosphine complexes of the platinum metals also tend to give nitrato products (194)-. 

NITRATO MAGNESICO (Spanish) (10377-60-3) A powerful oxidizer. Reacts violently with dimethylformamide, reducing agents, combustible materials, fuels, organic substances, metal powders, potassium hexanitrocobalite(III) (C.I. pigment yellow), sodium acetylide, and easily oxidizable matter. Incompatible with aluminum, ammonium hexacyanoferrate(II), fcH-butylhydroperoxide, citric acid, ethanol, ferrocyanides, hydrazinium perchlorate, isopropyl chlorocarbonate, metal phosphinates, nitrosyl perchlorate, organic azides, phosphorus, sodium thiosulfate, sulfamic acid, thiocyanates, tin(II) fluoride, and many other substances. 

NITRATO MERCURICO (Spanish) (10045-94-0) A powerful oxidizer. Violent reaction with reducing agents, combustibles, phosphinic acid, hypophosphoric acid, petroleum hydrocarbons. Forms heat- and/or shock-sensitive compounds with acetylene (forms mercury acetylide), ethanol (forms mercury fulminate), ferrocene, isobutene, phosphine, potassium cyanide, sulfur. Incompatible with strong acids, acetic anhydride, ammonia, ammonium hexacyanoferrate(II), organic azides, citric acid, hydrazinium perchlorate, isopropyl chloro-carbonate, nitrosyl perchlorate, sodium thiosulfate, sulfamic acid, thiocyanates, hydrozoic acid, methyl isocyanoacetate, sodium peroxyborate, trinitrobenzoic acid, urea nitrate. Aqueous solution corrodes metals. 

NITRATO de PLATA (Spanish) (7761-88-8) A powerful oxidizer. Forms friction- and shock-sensitive compounds with many materials, including acetylene, anhydrous ammonia (produces compounds that are explosive when dry), 1,3-butadiyne, buten-3-yne, calcium carbide, dicopper acetylide. Contact with hydrogen peroxide causes violent decomposition to oxygen gas. Violent reaction with chlorine trifluoride, metal powders, nitrous acid, phospho-nium iodide, red or yellow phosphorus, sulfur. Incompatible with acetylides, acrylonitrile, alcohols, alkalis, ammonium hydroxide, arsenic, arsenites, bromides, carbonates, carbon materials, chlorides, chlorosulfonic acid, cocaine chloride, hypophosphites, iodides, iodoform, magnesium, methyl acetylene, phosphates, phosphine, salts of antimony or iron, sodium salicylate, tannic acid, tartrates, thiocyanates. Attacks chemically active metals and some plastics, rubber, and coatings. 

BAuFjIrjNOjPgCjjHjg, Borate(l -), tetra-fluoro-, tris[l,2-ethanediylbis(diphenyl-phosphine)]hexahydrido[(nitrato-0,0 )gold]triiridium(l+), 29 290 BAu2F4lrOjP4C72Hg, Borate(l-), tetra-fluoro-, p-hydrido-(nitrato-0,0 )-bis(triphenylphosphine)bis[(triphenyl-phosphine)gold]iridium(l+), 29 284 BAujRejCijjHiig, Borate(l-), tetraphenyl-, hexahydridotetrakis(triphenylphos-phine)-bis[(triphenylphosphine)gold]di-rhenium(l+), 29 291... 

PtAujFjNOjPjCjjHjo, Platinum 1+), nitrato-0,0 )bis triphenylphos-phine)bis triphenylphosphine)gold]-, hexafluorophosphate —), 29 293 PtAu4B2P,C 2H,4s, Platinum 2+), tri-phenylphosphine)hexakis triphenyl-phosphine)gold]-, bis[tetraphenyl-borate 1 -)], 29 295... 

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