Phenyl cellosolve

The following melting points have been recorded —methyl cellosolve, 152° cellosolve, 128° wo-propyl cellosolve, 80° butyl cellosolve, 85° phenyl cellosolve, 145° benzyl cellosolve, 104° methyl carbitol. 82° ethyl carbitol, 76° . butyl carbitol, 54°. 

Inorganic acids Methyl diacetoacetate Phenyl cellosolve Silica gel Tetradecane... 

Phenyl-l,3-butanedione, b63 4-Phenyl-2-butanone, b77a Phenyl cellosolve, p72 Phenyl chloride, c47 Phenylcyclohexane, c376... 

Glycol, Monophenylether of. See Ethyleneglycol Phenylether, also known as Phenyl Cellosolve in this vol, p E279-L... 

Phenyl Cellosolve and Ucon Fluid 50-HB-260, and greater than additive toxicity with propylene oxide. The mechanism for such interactions is not known. 

ETHYLENE GLYCOL ETHERS (see BUTYL CELLOSOLVE, p.48 CELLOSOLYE, p.55 METHOXYETHANOL, p.H7 PHENYL CELLOSOLVE, p. 149 WATER, p.183 Tables III,VIII)... 

EBB Cyclic ethylene benzene-boronate HEF 2-Hydroxy ethyl formate HE A 2-Hydroxyethyl acetate EC Ethylene carbonate PCL Phenyl Cellosolve EO Ethylene oxide CEO Cyclic ethylene oxalate... 

Phenol Phenyl Cellosolve Formic Add Acetic Add Diethylene Glycol... 

When a large quantity of diphenyl carbonate is used, or when the reaction is carried out at a low vacuum, (for example, at 100 torr), side Reaction 21 occurs and produces a phenyl cellosolve ester. 

Reaction 21 would interfere in increasing the degree of polymerization. The reaction, however, is minimized by selecting the suitable Reaction 21 occurs and produces a phenyl Cellosolve ester. 

Orthoesters. As model experiments (1) phenyl Cellosolve and tetraphenyl orthocarbonate, and (2) hydroxyethyl benzoate and tetra-phenyl orthocarbonate reacted at 275°C. Diphenyl carbonate was obtained from the latter reaction but not from the former. The facts that the distillate from the latter reaction contained ethylene oxide and that diphenyl carbonate was formed quantitatively from the reaction of carboxylic acid and tetraphenyl orthocarbonate suggest the following reaction mechanism ... 

Phenyl-1,3-butanedione, b64 4-Phenyk < c-butyl acetate, m361 Phenyl Cellosolve, p72 Phenyl chloride, c41... 

Note Phenyl " Cellosolve is Trademark of Union Carbide Corp Refs l)Beil 6, 146, (84) [150] 2)... 

Properties White solid. Mp 134.5-135.5C. Soluble in water, acetone, dimethyl formamide, and phenyl Cellosolve. ... 

PHENYL CARBOXYLIC ACID (65-85-0) C7HJO2 Combustible solid.Dust may form explosive mixture with air (flash point 250°F/121°C autoignition temp 1063°F/573°C Fire Rating 1). Incompatible with strong oxidizers, caustics, ammonia, amines, isocyanates. The aqueous solution is a weak acid. On small fires, use dry chemical powder (such as Piuple-K-Powder), foam, water spray, or COj extinguishers. PHENYL CELLOSOLVE [Union Carbide] (122-99-6) see ethylene glycol phenyl ether. 

PHENYL CELLOSOLVE (Union Carbide) (122-99-6) Combustible liquid (flash point 260°F/127°C). May be able to form unstable peroxides in storage. Incompatible with oxidizers, permanganates, peroxides, ammonium persulfate, bromine dioxide, strong acids sulfuric acid, nitric acid. 

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