Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Phase-separation process thermosetting systems

Poncet et al. (1999) monitored frequency-dependent dielectric measurements to examine the phase-separation process in poly(2,6-dimethyl-1,4-phenylene ether) (PPE) in a DGEBA-MCDEA resin. Dielectric measurements measured the build up in Tg both in the PPE-rich continuous phase and in the epoxy-rich occluded phases for 30-60-wt.% PPE mixtures. In the 30% PPE mixmre, the rate of reaction of the thermoset phase is equivalent to that of the neat system due to two opposing effects, namely a slower reaction rate due to dilution and a low level of conversion at vitrification due to the presence of high-Tg PPE. In the 60-wt.% mixture the dilution effect of the PPE has a large effect of decreasing the reaction rate. The continuous thermoplastic-rich phase vitrifies first, followed by the thermoset occluded phase. The final morphology (size of occluded particles and composition of continuous phase) is affected by kinetics, diffusion and viscosity during phase separation. [Pg.366]

In order to make a thermodynamic analysis of the phase separation process in the metastable region (i.e. after reaching the CPC), the castor oil-modified DGEBA-EDA system will be considered again. The resulting trends may be generalized for any modified thermosetting polymer. [Pg.129]

In a system with a phase inversion structure, the complex viscosity of a blend system can be described by the Einstein equation (Eq. (4.11)). During viscoelastic phase separation, in which the interfadal tension plays a minor effect, the change in curing conversion is quite low and the viscosity difference between thermoplas-tics-rich matrix and dispersed thermoset-rich (low conversion and molecular weight) is very large and increases with the phase-separation process. When the viscosity of the dispersed thermoset-rich phase was neglected, the viscosity of the blend can be simplified as that of the thermoplastic-rich phase. [Pg.146]

Isothermal steady time tests are used to determine the gel point of a thermoset system as the point at which the shear viscosity tends towards infinity. In these tests the viscosity is measured as a function of time at a constant shear rate. This method has the following major disadvantages. Firstly, the infinite viscosity can never be measured due to equipment limitations and thus the gel time must be obtained by extrapolation. Secondly, shear flow may destroy or delay network formation. Finally, gelation may be confused with vitrification or phase separation since both these processes lead to an infinite viscosity (St John et al., 1993). However, some work by Matejka (1991) and Halley et al. (1994) has shown that extrapolation to zero values of reciprocal viscosity or normal stress (i.e. extrapolation to infinite viscosity and normal stress) can be used with some success. [Pg.346]

Two chemically dissimilar polymers will naturally attempt to phase separate and the structure that is formed will reflect the way in which this process occurs and the driving forces associated with the process. Phase separation is used to achieve rubber toughening in thermoset resin systems. Low molar mass CTBN copolymer is soluble in the simple mixtures of monomers used to create amine-cured epoxy resins systems. However, as the molecular mass of the epoxy resin increases so the balance of entropy and enthalpy of mixing of these components changes and a driving force for phase separation is created. [Pg.221]


See other pages where Phase-separation process thermosetting systems is mentioned: [Pg.31]    [Pg.170]    [Pg.56]    [Pg.181]    [Pg.186]    [Pg.106]    [Pg.152]    [Pg.276]    [Pg.211]    [Pg.429]    [Pg.441]    [Pg.653]    [Pg.24]    [Pg.161]    [Pg.170]    [Pg.285]    [Pg.291]    [Pg.130]    [Pg.83]    [Pg.121]    [Pg.381]    [Pg.70]    [Pg.271]    [Pg.224]    [Pg.316]    [Pg.12]    [Pg.158]    [Pg.885]    [Pg.4]    [Pg.134]    [Pg.189]    [Pg.82]    [Pg.142]    [Pg.142]   
See also in sourсe #XX -- [ Pg.178 ]




SEARCH



Phase processes

Phase separation process

Phase-separable system

Processing separation

Separable systems

Separation processes

Thermoset processes

Thermoset processing

Thermoset system Thermosetting

Thermoset systems

Thermosets processing

Thermosetting system

© 2024 chempedia.info