Phase diagram, of binary mixtures

In other cases, association has been demonstrated by means of phase diagrams of binary mixtures (158). 

The thermotropic behavior and phase diagrams of binary mixtures of copper and gold complexes of the type [MX(CNR)] (X = anionic ligand, R = p-alkoxyaryl group) have been studied [32] and the main results are ... 

Solid-Fluid Equilibria The phase diagrams of binary mixtures in which the heavier component (the solute) is normally a solid at the critical temperature of the light component (the solvent) include solid-liquid-vapor (SLV) curves which may or may not intersect the LV critical curve. The solubility of the solid is very sensitive to pressure and temperature in compressible regions where the solvent s density and solubility parameter are highly variable. In contrast, plots of the log of the solubility versus density at constant temperature exhibit fairly simple linear behavior. 

FIGURE 15.23 Approximate examples of phase diagrams of binary mixtures of triglycerides, indicated in each frame. The vertical axes give temperature (°C), the horizontal axes the mole fraction of the second triglyceride indicated. L is liquid, crystals are indicated by 3 or (3, and subscript C signifies compound crystals. 

Phase diagrams of binary mixtures of metaphosphate salts of various metals are reported by A. Durif, Rev. Phos. Chem., 6,109 (1969) and by J. Majling, F. Hanic, Topics Phos. Chem., 10,341 (1980). 

Phase Diagrams of Binary Mixtures Liquids and Vapors... 

Fan CF, Olafson BD, Blanco M, Hsu SL (1992) Application of molecular simulation to derive phase-diagrams of binary-mixtures. Macromolecules 25(14) 3667-3676 Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, Ithaca Forster A, Hempenstall J, Tucker I, Rades T (2001) Selection of excipients for melt extrusion with two poorly water-soluble drugs by solubility parameter calculation and thermal analysis. Int J Pharm 226(1-2) 147-161... 

Fig. 3.25 Phase diagram of binary mixtures of polyethylene and perhydrotriphenylene. (From Farina, DiSilvestre and Grasse (112))...

Figure 9.20. T-E phase diagrams of binary mixtures of EHPOCBC and MHPOOCBC with various mixing ratios (a) (/ )-EHPOCBC (b) 50.0% (/J)-EH-POCBC in (Jt)-MHPOOCBC (c) 19.8% (/ )-EHPOCBC in (/ )-MHPOOCBC and (d) 18.8% (i )-EHPOCBC in (/ )-MHPOOCBC.

Daoudi et al. [83] applied the thermodynamic approach equal Gibbs energy analysis to the pressure-composition phase diagrams of binary mixtures exhibiting reentrant phase behavior. Three different solution models are tested. The experimental data for the 4-n-hexyloxy- and 4-n-octyl-oxy-4 -cyanobiphenyl system are successfully described by the regular solution hypothesis. 

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