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Perchloromethyl

Physical Properties. Trichloromethanesulfenyl chloride [594-42-3] (perchloromethyl mercaptan, a misnomer but used as the common commercial name), CCl SCl, is a strongly acrid, pale yellow Hquid, boiling at 149°C with some decomposition at atmospheric pressure, 68°C at 6.93 kPa (52... [Pg.131]

If bromine is used in equation 8, carbon tetrabromide [558-13-4] is formed. With a minor amount of iodine present, and in the absence of iron catalyst, carbon disulfide and chlorine react to form trichioromethanesulfenyl chloride (perchloromethyl mercaptan [594-42-3]), CCI3SCI, which can be reduced with staimous chloride or tin, and hydrochloric acid to form thiophosgene (thiocarbonyl chloride [463-71-8], CSCI2, an intermediate in the synthesis of many organic compounds (see Sulfurcompounds). [Pg.27]

Perchloromethyl mercaptan Perchloryl fluoride Petroleum distillates (naphtha)... [Pg.381]

Perchlorocyclopentadiene Perchloromethyl Chloroformate Perchloromethyl Mercaptan Perdesiekte... [Pg.687]

The 2003 ACGIH threshold limit value-time-weighted average (TLV-TWA) for perchloromethyl mercaptan is 0.1 ppm (0.76 mg/m ). [Pg.567]

Toxicology. Perchloromethyl mercaptan is a severe pulmonary irritant and lacrimating agent fatal exposure has also caused liver and kidney injury. [Pg.567]

Of three chemical workers who were observed after accidental exposures to perchloromethyl mercaptan, two survived episodes of pulmonary edema, and the third died after 36 hours. The fatality resulted from a spill of the liquid on the clothing and floor with exposure to the vapor. At autopsy, there was necrotizing tracheitis, massive hemorrhagic pulmonary edema, marked toxic nephrosis, and vacuolization of centrilobular hepatic cells. [Pg.567]

Althoff H Tbdliche Perchlormethylmercap-tan-intoxikation (fatal perchloromethyl mercaptan intoxication). Arch Toxikol 31 121-135, 1973... [Pg.567]

ACGIH Perchloromethyl mercaptan. Documentation of the TLVs and BEls, 6th ed, pp 1195-1196. Cincinnati, OH, American Conference of Governmental Industrial... [Pg.567]

Knapp HF, MacAskill SM, Axicker GM, et al Effects in rats of repeated inhalation exposure to perchloromethyl mercaptan. Toxicologist 7 191 (Abst 762) 1987... [Pg.567]

Compound Name Hexachlorocyclopentadiene Tetrachloroethylene Carbon Tetrachloride Perchloromethyl Mercaptan T etrachloroethylene Urea Peroxide Decahydronaphthalene Tetrachloroethylene Hydrogen Peroxide Peracetic Acid... [Pg.75]

Perchloromethyl — Fire Hazards Flash Point (deg. F) Not flammable Flammable Limits in Air (%) Not flammable Fire Extinguishing Agents Not pertinent Fire Extinguishing Agents Not to be Used Not pertinent Special Hazards of Combustion Products Very irritating vapors formed from hot material. May form toxic phosgene gas, hydrogen chloride and sulfur dioxide Behavior in Fire ... [Pg.425]

Perchloromethyl mercaptan 5-(l-Ethylpentyl)hydantoin sodium salt... [Pg.957]

Thus the conception of this discovery the gestation in the early period was difficult and troubled. In the beginning of this century, perchloromethyl mercaptan was considered (and had been given a brief trial as) a war gas. There was little experience with its use by industry. The cost projections and the... [Pg.152]

See other pages where Perchloromethyl is mentioned: [Pg.1204]    [Pg.735]    [Pg.167]    [Pg.238]    [Pg.29]    [Pg.303]    [Pg.1079]    [Pg.90]    [Pg.255]    [Pg.185]    [Pg.97]    [Pg.262]    [Pg.280]    [Pg.1473]    [Pg.282]    [Pg.567]    [Pg.757]    [Pg.75]    [Pg.88]    [Pg.88]    [Pg.88]    [Pg.88]    [Pg.89]    [Pg.89]    [Pg.89]    [Pg.89]    [Pg.89]    [Pg.103]    [Pg.735]   
See also in sourсe #XX -- [ Pg.425 ]



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Perchloromethyl mercaptan

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