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Partner promotions Got partners attending the seune event Do some co-promotion. Send out co-sponsored emails or do a pre-event webinar together to gain more traction. [Pg.269]

Photoprocessing chemicals, solvents, and inks ate much mote difficult to recycle, but printers who partner with their suppHets and promote the use... [Pg.56]

The Friedlander reaction is quite versatile. The primary limitation on the o-aminobenzaldehyde component is preparation of the starting material as one might expect, these compounds are prone to self-condensation. Both electron rich and electron poor o-aminobenzocarbonyl compounds undergo the Friedlander reaction. When ketone partner 2 has only one available reactive methyl or methylene or is symmetrical, only one product is obtained. Even when two products can be formed, it is possible to choose reaction conditions such that only one product is isolated vide infra). The reaction can be promoted by acid catalysis, sometimes with improved results. [Pg.412]

In all the reactions described so far a chiral Lewis acid has been employed to promote the Diels-Alder reaction, but recently a completely different methodology for the asymmetric Diels-Alder reaction has been published. MacMillan and coworkers reported that the chiral secondary amine 40 catalyzes the Diels-Alder reaction between a,/ -unsaturated aldehydes and a variety of dienes [59]. The reaction mechanism is shown in Scheme 1.73. An a,/ -unsaturated aldehyde reacts with the chiral amine 40 to give an iminium ion that is sufficiently activated to engage a diene reaction partner. Diels-Alder reaction leads to a new iminium ion, which upon hydrolysis af-... [Pg.46]

The 2-pyrones can behave as dienes or dienophiles depending on the nature of their reaction partners. 3-Carbomethoxy-2-pyrone (84) underwent inverse Diels-Alder reaction with several vinylethers under lanthanide shift reagent-catalysis [84] (Equation 3.28). The use of strong traditional Lewis acids was precluded because of the sensitivity of the cycloadducts toward decarboxylation. It is noteworthy that whereas Yb(OTf)j does not catalyze the cycloaddition of 84 with enolethers, the addition of (R)-BINOL generates a new active ytterbium catalyst which promotes the reactions with a moderate to good level of enantio selection [85]. [Pg.126]

Heteroarylphenylalanines could be smoothly obtained via microwave-promoted Suzuki reaction of heteroaryl halides with 2-amino-3-[4-(dihy-droxyboryl)phenyl]propanoic acid (Scheme 28) [46]. Interestingly, the free amino acid could be used without any protection of the amine and carboxylic acid fimctionahty. When 4-(dihydroxyboryl)-L-phenylalanine was used as organometallic partner no racemization was observed. The carboxylate anion and free amino group seem to shield the a-C - H from deprotonation and thus hmit racemization. [Pg.169]

N-protected aminoacids 14 behave as carboxyl partners in Ag20 promoted reactions of 2-bromo-isobutyramides or -propanamides affording, respectively, esters of 2-hydroxy-isobutyramides (ref. 20a) or lactamides 15 (ref. 20b). While we plan further research on stereochemical and other aspects of these reactions, model units obtained from 2-bromo-isobutyramides have been used in conformational studies of depsi-peptides (ref. 21). [Pg.167]

The way in which these different partners may be involved in iron uptake across the intestine is presented in Figure 8.3. Reduction of ferric complexes to the Fe2+ form is achieved by the action of the brush border ferric reductase. The Fe2+ is transported across the brush border membrane by the proton-coupled divalent cation transporter (E)CT1) where it enters an unknown compartment in the cytosol. Fe2+ is then transported across the basolateral membrane by IREG1, where the membrane-bound copper oxidase hephaestin (Hp) promotes release and binding of Fe3+ to circulating apotransferrin. [Pg.240]

The new quality concept was developed in cooperation with other research members of the international research association Organic Food Quality and Health (FQH, for projects and partners see www.organicfqhresearch.org). The research association was established to promote research into the health effects of good quality organic food and to develop parameters for quality assessment. The research members distinguish four lines of research ... [Pg.54]

Using a different catalytic system, the Larhed group was able to perform regio-selective microwave-promoted chelation-controlled double-/3-arylations of terminal alkenes (Scheme 6.5) [24]. In this Heck approach, the authors used vinyl ethers as chelating alkenes and aryl bromides as coupling partners, employing Herrmann s... [Pg.110]

Microwave-assisted Heck reactions have also been carried out with triflates as coupling partners, involving some very complex molecules. Winterfeld and coworkers have reported a multigram synthesis of a complex non-symmetrical bis-steroidal diene by microwave-promoted coupling of the corresponding alkene and triflate steroidal moieties (Scheme 6.8) [27]. [Pg.112]

Therefore, researchers reasoned that the natural switch with age of NRl s partner could explain why the NMDA receptor in adult brain has a much narrower window of time for cellular association to occur, and it might explain why adult animals find it harder to learn and register new information [26]. So a copy of the NR2B gene was linked to a forebrain-specific promoter that increases NR2B s expression in the adult mouse forebrain (Fig. 53-5A), thereby counteracting the natural decline of the NR2B expression in the adult. [Pg.867]

Kletz, T. A. 1992b. Inherently safer design - a review. 7th International Symposium on Loss Prevention and Safety Promotion in the Process Industries, SRP Partners, Rome, Vol.I, pp. 1-13. [Pg.128]

If the client consents to involvement of family or friends, they can be good sources for information that can help you devise a thoughtful treatment plan. As mentioned earlier in this chapter, people with drug problems may have relationship stressors that need to be addressed in order to promote a successful treatment outcome. Being able to gather information from partners or friends about the nature of these stressors adds another dimension to understanding the source and treatment for the problems. Sometimes a family member or friend has a different view on the nature of a problem or on the behavior pattern related to a problem that may help you better understand how to treat it. [Pg.166]

Current evolutionary theorists mostly agree upon the role of pathogens as a significant driving force in evolution. In social animals it is of particular relevance to monitor health status of potential social or sexual partners. Closer contact with infected conspecifics may promote pathogen transmission and, in the case of sexual partners, susceptibility to infection or an inherited deficiency that can deteriorate offspring viability. It is well documented in many animal species that olfaction is used to monitor health status in mate choice. For instance mice can discriminate between parasitized and non-infected individuals (Kavaliers and Colwell 1995). [Pg.206]

The experiments using Sn adatoms are Intended to test for a correlation between the activity of these species as promoters for CO oxidation kinetics and their influence on the CO vibrational spectrum. Watanabe et. al. have proposed an "adatom oxidation" model for the catalytic activity of these adatoms (23). They propose that the function of the Sn adatoms is to catalyze the generation of adsorbed 0 or OH species at a lower potential than would be required on unpromoted Pt (23). The latter species then react with neighboring adsorbed CO molecules to accomplish the overall oxidation reaction. One implication of this proposed mechanism is that the adsorbed adatom is expected to have little, if any, direct interaction with the adsorbed CO reactant partner. Vibrational spectroscopy can be used to test for such an interaction. [Pg.372]


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