Particulate silica fractionation

The rain rate of BSi is dependent on (1) the rate of its production by marine organisms, (2) shell dissolution rates, and (3) the time required for a shell to reach the seafloor. High rates of production by siliceous plankton ensure a large supply of opal to the water column. The fraction reaching the seafloor is largest when transit times are shortest. Thus, shells that sink fastest will be preferentially preserved and a greater fraction of the particulate silica flux reaches sediments that lie in shallow waters. 

Characterization of Colloidal and Particulate Silica by Field-Flow Fractionation... 

The 2003 ACGIH threshold limit valuetime-weighted average (TLV-TWA) for particulate matter containing no asbestos and <1% crystalline silica is 3mg/m for respirable size fraction and lOmg/m for inhalable mass fraction. Exposure to any substance in the particulate mass that has a designated TLV should be controlled to that value. 

Marine waters also receive some biogenic silica from the land. This material is transported to the sea as windblown dust and as part of the suspended load of rivers. Rivers also deliver about 0.43 Pg of dissolved silica annually to the oceans, and some fraction of this is undoubtedly derived from biological sources as well. Locally, terrigenous biogenic silica (in particulate form) may accumulate to significant concentrations on the sea floor. For example, Kolbe (1957) reported frequent occurrences of phytoliths and freshwater diatom frustules in deep-sea cores from the equatorial Atlantic, and one locahty contained diatom tests derived exclusively from freshwater species. 

Hayakawa K, Nakamura A, Terai N, Kizu R, Ando K. Nitroarene concentrations and direct-acting mutagenicity of diesel exhaust particulates fractionated by silica-gel column chromatography. Chem Pharm Bull 1997 45 1820-2. 

A comparison of critical temperature differences of resins filled with several ceramic particulates is shown in Figure 4. The volume fraction of all these composites is 34.2%. The critical temperature difference of epoxy filled with hard particulates was classified into three groups on the basis of thermal shock resistance. Composites filled with a strong particulate, such as silicon nitride or silicon carbide, showed high thermal shock resistance. Some improvement in thermal shock resistance was recognized for silica-filled composites. Composites filled with alumina or aluminum nitride showed almost comparable or lower resistance compared with the neat resin. 

Natural surface ectivity In assoc ialion with surface-active agents Foam fractionation for example, dete[gents from aqueous solutions Ion flotation, molecular flotation, adsorbing colloid flotation for example, Sr1 +, PtiJ +, Hg2+, cyanides Fnam flotation for example, microurganisms, proteins Microflotation, colloid flotation, ultraflotation for example, particulates in wastewater, clay, microoiganisms Froth flotation of noapolar minerals for example, sulfur Froth flotation For example minerals such as silica Precipitate flotation (1st and 2nd kind) Tor example, ferric hydroxide... 

EXPOSURE GUIDELINES ACGIH TLV 10 mg/m (total dust containing no asbestos and 1% crystalline silica for Particulates Not Otherwise Classified (PNOC)) OSH A PEL 15 mg/m (total dust), 5 mg/m (respirable fraction) NIOSH REL not established IDLH not determined. 

EXPOSURE GUIDELINES ACGIH TLV TWA 10 mgW of inhalable dust (for particulate matter containing no asbestos and less than 1% crystalline silica) OSHA PEL TWA 15 mg(total dust)/m 5 mg (respirable fraction)/m IDLH (not determined). 

We were anxious to evaluate the use of supercritical carbon dioxide (scCOj) to remediate an urban soil. A two-stage approach was prompted by our efiforts to make the process continuous. SCCO2 extraction of particulate media is inherently a batch process. Pressure within the extractor is maintained with a capillary restrictor (in our case a 50 pm diameter silica tube) that is prone to fouling. The non-polar organic Section of an aqueous (surfactant) extract can be removed continuously (either on site or off site) with scCOj in a counter current liquid-liquid like process. The heavy metal contaminants remain with the water fraction for subsequent treatment. The organics fraction is the subject of this short review on SCCO2 processing. 

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