Particle sizes, beads

Black Pigments. The only black pigment used to an appreciable extent in inks is carbon black It is used in newsprinting, pubHcation, commercial and packaging printing therefore, in large quantities. Black pigments ate offered in fluffy or beaded forms and in a variety of particle sizes and physical properties. 

A Gaussian distribution of particle size is the result of copolymer manufactured by suspension polymerization. A jetting process produces beads with more uniform particle size. The uniformity coefficient is a numerical method of indicating closeness of all beads to the same size. 

As manufactured, most resias have a Gaussian-Hke distributioa of particle size. Very few are as small as 0.3 mm or as large as 1.0 mm. Most are betweea 0.5—0.8 mm. A backwash before usiag aew resia is common practice to assure uniform flow during the adsorption and regeneration steps. The backwash eliminates air pockets that may have formed while filling the column and sorts the beads such that the smaller sizes are at the top of the bed and... 

In a suspension polymerization, monomer is suspended ia water as 0.1—5 mm droplets, stabilized by protective coUoids or suspending agents. Polymerization is initiated by a monomer-soluble initiator and takes place within the monomer droplets. The water serves as both the dispersion medium and a heat-transfer agent. Particle size is controlled primarily by the rate of agitation and the concentration and type of suspending aids. The polymer is obtained as small beads of about 0.1—5 mm in diameter, which are isolated by filtration or centrifugation. 

For prolonged action therapy, granular-sized encapsulated particles, ie, beads, are used and can be both uncoated or coated. The uncoated beads provide the initial dose the others are made to dissolve at various rates depending on the coating type and thickness. 

Suspension Polymerization. At very low levels of stabilizer, eg, 0.1 wt %, the polymer does not form a creamy dispersion that stays indefinitely suspended in the aqueous phase but forms small beads that setde and may be easily separated by filtration (qv) (69). This suspension or pearl polymerization process has been used to prepare polymers for adhesive and coating appHcations and for conversion to poly(vinyl alcohol). Products in bead form are available from several commercial suppHers of PVAc resins. Suspension polymerizations are carried out with monomer-soluble initiators predominantly, with low levels of stabilizers. Suspension copolymerization processes for the production of vinyl acetate—ethylene bead products have been described and the properties of the copolymers determined (70). Continuous tubular polymerization of vinyl acetate in suspension (71,72) yields stable dispersions of beads with narrow particle size distributions at high yields. 

Wollastonite with an aspect ratio of 15 1 is useful as a replacement for asbestos and as a high-strength filler for plastics. The feed material with dgo of 45 [Lm was similarly ground. Beads of 0.3 mm gave faster grinding than 0.8 mm beads, and these corresponded to a bead-particle-size ratio of 19, confirming other results. 

Among new mill developments, annular-gap bead mills and stirred bead mills are being used. These have a high cost, but result in a steep particle-size distribution when used in multipass mode [Kolb, Ceramic Forum International, 70(5), 212-216 (1993)]. Costs for fine grinding typically exceed the cost of raw materials. Produces are used for high-performance ceramics. 

Sephadex. Other carbohydrate matrices such as Sephadex (based on dextran) have more uniform particle sizes. Their advantages over the celluloses include faster and more reproducible flow rates and they can be used directly without removal of fines . Sephadex, which can also be obtained in a variety of ion-exchange forms (see Table 15) consists of beads of a cross-linked dextran gel which swells in water and aqueous salt solutions. The smaller the bead size, the higher the resolution that is possible but the slower the flow rate. Typical applications of Sephadex gels are the fractionation of mixtures of polypeptides, proteins, nucleic acids, polysaccharides and for desalting solutions. 

Two-phase suspension systems produce beaded products with broader particle-size distribution (e.g., 1-50 /rm). The microspherical particles usually need to be classified repeatedly to reduce the particle-size distribution in order to improve the resolution and efficiency in the separation for use in chromatography. The actual classification process depends on the size range involved, the nature of the beaded product, and its intended applications. Relatively large (>50 /rm) and mechanically stable particles can be sieved easily in the dry state, whereas small particles are processed more conveniently in the wet state. For very fine particles (<20 /rm), classification is accomplished by wet sedimentation, countflow setting, countflow centrifugation, or air classification. 

Each of the PLgel individual pore sizes is produced hy suspension polymerization, which yields a fairly diverse range of particle sizes. For optimum performance in a chromatographic column the particle size distribution of the beads should be narrow this is achieved by air classification after the cross-linked beads have been washed and dried thoroughly. Similarly, for consistent column performance, the particle size distribution is critical and is another quality control aspect where both the median particle size and the width of the distribution are specified. The efficiency of the packed column is extremely sensitive to the median particle size, as predicted by the van Deemter equation (4), whereas the width of the particle size distribution can affect column operating pressure and packed bed stability. 

The nonporous spherical gels for PCHdC are often specially prepared for research purposes. However, nonporous polystyrene/divinylbenzene beads. Solid Bead, can be obtained in various particle sizes from Jordi Associates, Inc. (Bellingham, MA). Columns packed with these gels can be used for HdC of the polymers that are currently analyzed using polystyrene/divinylbenzene SEC columns. Fumed silica nanospheres are offered by Cabot (Tuscola, IL) (17), and nonporous silica (NPS) microspheres are offered by Micra Scientific, Inc. (Northbrook, IL). These nonporous silica gels may also be used for HdC. 

The particle size distribution of AP was determined and Compared using the Ro-Tap, the Alpine Air Jet Sieve and the Micromerograph. For this purpose six different samples of ground AP were chosen and separated using sieves calibrated with National Bureau of Standards spherical glass beads. The results were plotted... 

The particle-size distribution of two test powders, spherical glass beads and crushed quartz was determined with different types of app (Ref 32), and indicate that the micro-mesh sieve data is in good agreement with those of other methods (Table 6) ... 

Fig 25 Comparison of microscopic particle size distribution with the average distribution of four identical runs made with the Coulter Counter (Sharpies standard glass bead sample, type XC-3)... 

These results are, however, only valid for the particle sizes referred to. Lee (L3) has reported measurements of average bubble diameter and gas-liquid interfacial area for gas-liquid fluidized beds of glass beads of 6-mm... 

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