Parison temperature

Bottles thin in various areas Parison curling Parison too long or short Adjust die ring concentricity Increase/decrease extruder speed and adjust parison temperature Reduce head temperature... 

This surface treatment allows low cost blow-molded PE bottles to be used for paint, paint thinner, lighter fluid, polishes, cleaning solvents, cosmetics, toiletries, etc, and higher cost resins or coextrusion processes are not always necessary. For floorination to be effective, the parison temperature must be greater than 195°C. 

During the blow moulding of polypropylene bottles, the parison is extruded at a temperature of 230°C and the mould temperature is 50°C. If the wall thickness of the bottle is I mm and the bottles can be ejected at a temperature of I20°C estimate the cooling time in the mould. 

When a parison or preform is inflated, it displaces the air around it within the mold. If no provision is made to vent the mold, compression of the air around the parison or preform can raise its temperature to such an extent that it can scorch the surface of the product. To avoid this problem, we equip blow molds with vents. These can consist of slit vents at the parting line between mold halves, porous plugs of sintered metal, or small holes drilled into the cavity walls. 

The parison is inflated fast, within seconds or less, at a predetermined rate such that it does not burst while expanding. It is a complex process that involves expansion of a nonuniform membrane-like element. Because the extension ratio is high (above 10), it is difficult to calculate the final thickness distribution. Naturally, much of the recent theoretical research on parison stretching and inflation (as in the case with thermoforming) focuses on FEM methods and the selection of the appropriate rheological constitutive models to predict parison shape, thickness, and temperature distribution during the inflation. 

With viscoelastic models used by an increasing number of researchers, time and temperature dependence, as well as strain hardening and nonisotropic properties of the deformed parison can, in principle, be accounted for. Kouba and Vlachopoulos (97) used the K-BKZ viscoelastic constitutive equation to model both thermoforming and parison membrane stretching using two-dimensional plate elements in three-dimensional space. Debbaut et al. (98,99) performed nonisothermal simulations using the Giesekus constitutive equation. 

Stretch blow molding holds the parison above its glass transition temperature (7 ) and stretch-orients it to increase modulus, strength, impact resistance, transparency, and impermeability. This is most important for PET, and is also used for PVC, polypropylene, and polyacrylonitrile. 

The parison head, sometimes called the die head or simply the die, is a specialized form of tube extrusion die (Chapter 17). Its function is to deliver a straight parison in the correct diameter, length, wall thickness, and at the correct temperature for BM. Prior to being clamped in the mold, the parison is suspended unsupported in free air. To avoid undue deformation, it is necessary to extrude the parison vertically downwards. 

The injection molding with rotation (MWR) is an example of processing at lower temperatures, pressure, etc. It is also called injection spin molding or injection stretched molding. This BM process combines injection molding and IBM, as performed in IBM reviewed, except it has the additional step of with melt orientation (Dow patent). The equipment used is what is commercially available for IM except the mold is modified so that either the core pin or outside cavity rotates. The rotated melt on its preform pin is transferred to a blow mold. The end product can come directly from the I MM mold or be a result of two-stage fabrication malting a parison and BM the parison.164... 

Gegiou et found only a very slight viscosity effect, both in the n-Ti and in the jt-jc absorption bands on the isomerization quantum yield. They used glycerol as a viscous solvent, but the result may also be transferred to polymer matrices. In solid matrices, several photoisomerization modes are observed (see the preceding section on the influence of temperature), A com parison between azobenzene isomerization in liquid methylmethacrylate and the slow mode in poly (methylmethacrylate) showed that the difference in quantum yields on Si (0.17) and S2 excitation (0.03) is retained in the solid matrix. The fast process is not observed in n —> n excitation. These data are important in relation to the use of the azobenzene isomerization method for the determination of the free volume in a polymer. 

In extrusion stretch blow moulding the first stage is similar to the first stage of extrusion blown, but the parison formed is conditioned to a specific temperature prior to stretching initially by a descending rod and then by compressed air (Figure 7.9). 

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