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Parameters Field Work

Here the functions g(0) and /(0) are defined in a suitable way to produce the desired phase behavior (see Chapter 14). The amphiphile concentration does not appear expHcitly in this model, but it influences the form of g(0)— in particular, its sign. Other models work with two order parameters, one for the difference between oil and water density and one for the amphiphile density. In addition, a vector order-parameter field sometimes accounts for the orientional degrees of freedom of the amphiphiles [1]. [Pg.666]

Fig. 1.38. The Fowler Nordheim equation for field emission. The relevant dimensions are much smaller than the tip radius. Therefore, a one-dimensional model is adequate. Neglecting the image-force effect, the potential U(z) outside the metal surface is linear with respect to distance z- The relevant parameters are work function of the material, tj), and the field intensity near the surface, F. Fig. 1.38. The Fowler Nordheim equation for field emission. The relevant dimensions are much smaller than the tip radius. Therefore, a one-dimensional model is adequate. Neglecting the image-force effect, the potential U(z) outside the metal surface is linear with respect to distance z- The relevant parameters are work function of the material, tj), and the field intensity near the surface, F.
The measurements of water quality parameters (oxidation-reduction potential, pH, temperature, conductivity, dissolved oxygen, and turbidity) and the collection of field screening data with field portable instruments and test kits constitute a substantial portion of field work. Field measurements, such as pH, stand on their own as definitive data used for the calculations of solubility of chemical species and chemical equilibrium in water, whereas others serve as indicators of well stabilization or guide our decision-making in the field. Table 3.8 shows the diversity of field measurement... [Pg.166]

Firstly, these /8 parameters are rather ill-defined but most immediately, the qualitative trends between the values has been shown merely to reflect a greater reduction in Fi than in from the corresponding free-ion values. In short these parameter trends furnish little or no evidence for differential orbital expansion. Further, even if such differentiation is really there - by which we presumably mean within a conventional m.o. sheme - it must manifest itself only within the numerical values of (and ligand field parameters). While working within a (f basis, therefore, there is no inconsistency whatever by recognizing the non-spherical hgand field within Fl.f. of (1-5) at the same time as representing the interelectron repulsions - l/r,y of (1-5) - in the usual free-ion Condon-Shortley theory. [Pg.42]

As an example for the use of field data (in this case, a combination of a generic study, a field-effect study and a field residue study), the following case study is presented the agricultural scenario was a spray application of an organothio-phosphate insecticide in arable crops. Due to the inherent bird toxicity (e.g., LDjq 10 mg a.s./kg bw) estimated according to the EU Guidance Document SANCO/4145/2000, the acute TER is < 0.5 within a Tier 1 risk assessment [1]. Since the trigger value within the EU (> 10) is not met, a refined risk assessment is necessary. As a consequence, a field study was conducted to derive refined exposure parameters for small insectivorous birds in an arable crop. Furthermore, the effects of the product on the population were recorded. The field work of the... [Pg.427]

Field working method, technology and working parameters... [Pg.104]

In electrospinning, process parameters are typically considered as the applied electric field, working distance, flow rate, and, in some cases, collector [rotor] velocity. [Pg.36]

The general emphasis in force field development is towards transferrable force fields, where the functional form and the values of associated parameters can be used in a wide variety of molecules and crystals. As the parameters are developed empirically, transferability implies a degree of reliability and confidence that the parameters will work for crystals for which they were not specifically parameterised. In a recent development of the so-called tailor-made force field, it was pointed out that for the specific case of crystal structure prediction, the force field does not need to be transferable and that in fact there are some important advantages to having a force field derived specifically for the molecule of interest. Given sufficiently accurate information from quantum mechanical calculations, the tailor-made force field can be obtained by fitting to the quantum mechanical potential energy surface. Neumann defined a number of quantum mechanical data sets which represented both the non-bonded and bonded interactions in the crystal. The parameters of the force field were then optimised to fit these data sets. The quantum mechanical method chosen for the calculations was the DFT(d) method which will be described below. [Pg.51]

The physical nature of an atmospheric chemical plasma varies according to the type of gas, mixture of gases, the input pressure of gases used, the confinement (or lack thereof) of the plasma, and the type of electrical field which maintains the plasma. Putting all of these parameters to work, the degree of ionization of an atmospheric chemical plasma becomes directly relative to the proportion of atoms which have lost or gained electrons within the ionization process, which is in turn driven by the plasma process temperature (typically directly related to applied electrical power) and its control. [Pg.77]

The scheme of dispersion effects displayed in engineering materials of different structures was considered and an analysis of the causes of their occurrence was performed in our work. The spectrum of structural noise is considered as an element of unified spectral characteristics, reflected interaction of the ultrasonic field with given parameters and heterogeneous medium... [Pg.733]

The parameter J.j is a measure of the energy of interaction between sites and j while h is an external potential or field common to the whole system. The tenn ll, 4s a generalized work temi (i.e. -pV, p N, VB M, etc), so is a kind of generalized enthalpy. If the interactions J are zero for all but nearest-neighbour sites, there is a single nonzero value for J, and then... [Pg.643]


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