3,3 ,4,4 -Oxydiphthalic anhydride

The aromatic diamines and dianhydrides used in the preparation of the polyamic acid resins and the diamic acid additives are listed in Figure 1. The 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA), 4,4 -oxydianiline (4,4 -ODA), and 3,3 -diaminodiphenylsulfone (3,3 -DDS02) were obtained from commercial sources. The remaining monomers were obtained as experimental materials as follows (1) 4,4 -bis(3,4-dicarboxyphenoxy) diphenylsulfide dianhydride (BDSDA) from General Electric Corporate R D Center (2) 4,4 -oxydiphthalic anhydride (ODPA) from Occidental Chemical Corporation (3) 2,2-bis[4(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF) from Ethyl Corporation and (4) 2,2-bis[4(3-aminophenoxy)phenyl]hexafluoropropane (3-BDAF) and 3,3 -oxydianiline (3,3 -ODA) from Mitsui Toatsu, Inc. 

A series of 15 wt % isomeric polyimide precursor resin solutions was prepared by the National Aeronautics and Space Administration Langley Research Center. The polymerization procedure has been described previously (2,3). The poly(amic-acid) resin solutions were made from 3,3, 4,4 -benzophenonetetracarboxylic acid dianhydride (BTDA), 4,4 -oxydiphthalic anhydride (ODPA), diaminobenzophenone (DABP), and methylenedianiline (MDA) monomers. 

Poly [4,4 -oxybis(benzoyl chloride)-co-phenolphthalein] Poly [4,4 -oxydiphthalic anhydride-co-3,3 -bis(p-aminophenyl) 440... 

Oxydianiline (ODA) BEYO Chemical Co., 4,4 -Oxydiphthalic anhydride (ODPA) Shanghai Research Institute > o-... 

The incorporation of pyridine or triazole improves the adhesion between poly(imide)s and copper.Poly(3,3, 4,4 -benzophenone tetracarboxylic dianhydride-3,5-diamino-l,2,4-triazole) (BTDA-DATA) contains the triazole moiety as repeating units. Poly(4,4 -oxydiphthalic anhydride-1,3-aminophenoxybenzene-8-azaadenine) (ODPA-APB-8-AA) bears the triazole moieties at the end." BTDA-DATA starts to decompose at 350°C. However, ODPA-APB-8-AA starts to decompose at 400°C. The polymers have been tested as adhesives for copper surfaces. The adhesion is increased by the formation of copper complexes. 

Oxydiphthalic anhydride (4,4 -ODPA) can be prepared from chlorophthalic anhydride in < -dichlorobenzene and potassium carbonate. Hexaethylguanidinium chloride is used as a phase transfer catalyst. ... 

Intrinsically microporous Pis have been prepared from 2,2 -diamino-l,l -binaphthalene or 4,4 -(9-fluorenylidene)dianiline. As anhydrides pyromel-litic dianhydride, 3,3, 4,4 -biphenyltetracarboxylic dianhydride, 4,4 -oxydiphthalic anhydride, and 4,4 -(hexafluoroisopropylidene)diphthalic anhydride were used [81]. 

A poly(imide-siloxane)/titania hybrid film was fabricated by a sol-gel process by the in situ formation of titania within the poly(imide-siloxane) matrix [85]. The poly(amic acid siloxane) polymer was prepared from 4,4 -oxydiphthalic anhydride, 2, 2-bis [4-(4-aminophenoxy) phenyl] propane, and a,a>-bis(3-aminopropyl)polydimethylsiloxane. Acetylace-tone was used as chelating agent in order to reduce the rate of hydrolysis of titanium alkoxide in the polymer. The presence of titania on the surface of eventually produced films enhances the adhesive strength at the interface. 

Figure 2 Relation between dissolution rate and PAA/PAE blend ratio. BTDA 3,3, 4,4-benzophenonetetracarboxylic dianhydride, DDE 4,4 -diamino-diphenyl ether, ODPA 4,4 -oxydiphthalic anhydride, DAPP 2,2-bis((3-amino-phenoxy)phenyl)propane.

In a different smdy, they synthesized another five series of poly(ether imide)s based on five different cardo moiety containing diamines, designated as BPI, BAPA, FBP, BIDA, and SBPDA, as presented in Scheme 3.21. Five different aromatic dianhydride, 4,4 -(4,4 -isopropylidenediphenoxy) w(phthalic anhydride) (BPADA), 4,4 -(hexafluoro-isopropyli-dene) diphthalic anhydride (6-FDA), 3,3 4,4"-benzo-phenone tetracarboxylic acid dianhydride (BTDA), 4,4 -oxydiphthalic anhydride (ODPA), and benzene-1,2,4,5-tetracarboxylic dianhydride (PMDA), were used to prepare each series of poly(ether imide)s. The O2-N2 and CO2-CH4 separation properties for... 

Figure 7. Chemical structure of a) 4,4, 4"-triaminotriphenylmethane, b) 4,4 -oxydiphthalic anhydride and c) 4,4 -methylenedianiline...

An other relevant class of type I polymers is given by polyimides [59-65]. As compared with polymethacrilates they show higher Tg and, in general, better time stability of NLO performances. The synthetic route to polyimides is versatile. They can be obtained by polymerization between bis-anhydrides and amino-chromophores. High performances are obtained using bis-phthalic anhydrides such as 3,3, 4,4 -oxydiphthalic anhydride (ODRA) or 4,4 -(hexafluoro-isopropylidene)diphthalic anhydride (6FDA). 

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