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Outer nodes

The concept of the size of an atom is not well defined within quantum mechanics. An atom has no sharp boundary the probability of finding an electron decreases exponentially with distance from the atom s centre. Nevertheless, a useful measure of the size of the core is provided by the position of the outer node of the valence electron s radial function, since we have seen that the node arises from the constraint that the valence state... [Pg.38]

What about the outer nodes Whereas this is a topological diagram, it is useful to think about distorting it. One way to do so would be to wrap it around a sphere. If that were done, the three-arm B-DNA-branched junction at the middle could correspond to the north pole, and the three outer nodes would each flank the south pole. Hence, they, too, could be coalesced to form a DNA-branched junction. However, this junction would need to be constructed from Z-DNA, because the signs of the outer nodes are positive. [Pg.339]

IThe almost complete interatomic transfer of one electronic charge indicated in Table 7.4 for the ionic systems is verified by the nodal structure of the corresponding Laplacian maps. The cations, Li", Na", and K", all lack the outer nodes associated with the valence density distribution of the isolated atom. Thus, Li in LiCl has but one negative region rather than two, Na in NaCl has two rather than three, and K in KF has three rather than four he reader is referred to Fig. E7.2 for displays of the charge distributions and interatomic surfaces for some of these systems. Another characteristic of a closed-shell interaction exemplified by the alkali halides and discussed in Section E7.1 is the separate localization of the electrons within the basin of each atom, as determined by the spatial localization of the Fermi hole. [Pg.293]

GRAPH 5.9 Genetic Formal Graph of the four localization levels global, curve, surface, and volume, with the various operators linking them contra-gradient, contra-curl, and divergence. The two outer nodes are scalar variables, the two inner ones are vectors, symbolized with a bold circumference. Dotted connections represent inverse operators. [Pg.124]

The rectangular elements, which have four corner nodes and five degrees of freedom at each node, assume both a stress field inside the elements and linear displacement functions around their boundaries. The element stiffness matrices are derived from a complementary energy functional. Figure 1 shows a schematic representation of the finite element mesh used in the analysis of the strut. The magnetic loading is distributed along the outer nodes of the aluminum bulkhead. [Pg.381]

Main stmt Top section Point of intersection Node point line Outer intersection segmentation Vertical extending boundary line Outer node area... [Pg.21]

Breast Right Hard 2.4 x 3.0 cm mass in upper outer quadrant without associated erythema, dimpling, or skin changes, not fixed to skin, no ulceration. No palpable lymph nodes in axilla. Left Without masses or lymphadenopathy. [Pg.1308]

From the AV node, the electrical impulse spreads through the AV bundle or the bundle of His. This portion of the conduction system penetrates the fibrous tissue separating the atria from the ventricles and enters the interventricular septum where it divides into the left and right bundle branches. The bundle branches travel down the septum toward the apex of the heart and then reverse direction, traveling back toward the atria along the outer ventricle walls. This route of conduction of the impulse facilitates ejection of blood from the ventricles. If the impulse were to be conducted directly from the atria to the ventricles, the ventricular contraction would begin at the top of the chambers and proceed downward toward the apex. This would trap the blood at the bottom of the chambers. Instead, the wave of ventricular electrical stimulation and, therefore, contraction moves from the apex of the heart toward the top of the chambers where the semilunar valves are located and ejection takes place. [Pg.172]

Fig. 6 a-c Coordination mode of the outer Cu2+ ions and the La3+ ions at the three vertices of the huge octahedral cluster, d-e Polymeric chain with LagCuM clusters as nodes viewed along [111] and [010] directions, respectively... [Pg.183]

The length of the trans-Cu(gly)2 linker (the distance of the two spare carboxylate oxygen atoms) is about 7.83 A, as compared with 7.34 A of terephthalic acid and 7.08 A of 4,4 -bipyridine. This linker uses two spare carboxylate oxygen atoms to coordinate to the outer Cu11 of the [Er6Cu24] unit, and the two nodes are thus bridged. [Pg.186]

Fig. 9 a b Coordination mode of the outer Cu2+ ions and the Nd3+ ions at the two vertices of the huge octahedral cluster Nd6Cu24 j for 9. Symmetry codes for A and B are y, z, x and 0.5 - z, 1 — x, —0.5 + y, respectively, c Each cluster nodes link to 12 other cluster units through 12 trans-Cu(pro)2 groups, d 3D open-framework of 9. e Face-centered cubic network... [Pg.190]

A lymph node consists of a cortex and an inner medulla. The cortex is composed of an outer cortex, which contains B-lymphocytes, within lymphoid follicles, and paracortical areas, which contain mainly T-lymphocytes and dendritic cells. The proliferation of B-cells occurs in central areas, called germinal centres. The medulla consists of strings of macrophages and the B-cells that secrete the antibodies (i.e. the effector cells) these are the medullary cords (Figure 17.42). Lymph carries immune cells (e.g. lymphocytes, antigen-presenting cells) and pathogens from the tissues to the lymph nodes, via the afferent lymphatics. [Pg.402]


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See also in sourсe #XX -- [ Pg.200 ]




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