Transient oscillations

Finally a further recommendation for the start-up of cooled CSTR processes shall be given. The oscillating transient behaviour during start-up which was demonstrated here may be avoided if the CSTR is started up as an SBR with constant cooling temperature until the desired operating point is reached. At this time the feed of the second component is then switched on. The design principles to be obeyed for this procedure are discussed in Section 4.3.1.4. 

Xenon peaking Xenon oscillation transient Xenon equilibrium Xenon d... 

Besides the sinusoidal oscillations, transient tests such as stress relaxation, start-up of steady shear flow, and cessation of steady shear flow are also important in the rheological characterization of polymeric liquids. The instrument limitations and features, and their effect on the data obtained in some types of transient tests, are examined in this section. Also, we shall illustrate the use of linear viscoelastic transformation to obtain, for example, stress relaxation data from tests such as start-up of steady shear flow and sinusoidal oscillations. 

A microwave pulse from a tunable oscillator is injected into the cavity by an anteima, and creates a coherent superposition of rotational states. In the absence of collisions, this superposition emits a free-mduction decay signal, which is detected with an anteima-coupled microwave mixer similar to those used in molecular astrophysics. The data are collected in the time domain and Fourier transfomied to yield the spectrum whose bandwidth is detemimed by the quality factor of the cavity. Hence, such instruments are called Fourier transfomi microwave (FTMW) spectrometers (or Flygare-Balle spectrometers, after the inventors). FTMW instruments are extraordinarily sensitive, and can be used to examine a wide range of stable molecules as well as highly transient or reactive species such as hydrogen-bonded or refractory clusters [29, 30]. 

Figure B2.1.8 Dynamic absorption trace obtained with the dye IR144 in methanol, showing oscillations arising from coherent wavepacket motion (a) transient observed at 775 mn (b) frequency analysis of the oscillations obtained using a linear prediction, smgular-value-decomposition method.

Most chemically reacting systems tliat we encounter are not tliennodynamically controlled since reactions are often carried out under non-equilibrium conditions where flows of matter or energy prevent tire system from relaxing to equilibrium. Almost all biochemical reactions in living systems are of tliis type as are industrial processes carried out in open chemical reactors. In addition, tire transient dynamics of closed systems may occur on long time scales and resemble tire sustained behaviour of systems in non-equilibrium conditions. A reacting system may behave in unusual ways tliere may be more tlian one stable steady state, tire system may oscillate, sometimes witli a complicated pattern of oscillations, or even show chaotic variations of chemical concentrations. 

The relaxation and creep experiments that were described in the preceding sections are known as transient experiments. They begin, run their course, and end. A different experimental approach, called a dynamic experiment, involves stresses and strains that vary periodically. Our concern will be with sinusoidal oscillations of frequency v in cycles per second (Hz) or co in radians per second. Remember that there are 2ir radians in a full cycle, so co = 2nv. The reciprocal of CO gives the period of the oscillation and defines the time scale of the experiment. In connection with the relaxation and creep experiments, we observed that the maximum viscoelastic effect was observed when the time scale of the experiment is close to r. At a fixed temperature and for a specific sample, r or the spectrum of r values is fixed. If it does not correspond to the time scale of a transient experiment, we will lose a considerable amount of information about the viscoelastic response of the system. In a dynamic experiment it may... 

CRO Cathode ray oscillograph, to record voltages of a transient nature. For instance, re-striking voltages (TRVs), whose frequency of oscillations is beyond the response range of EMO. 

I his is the frequency at w hich the surges travel. This frequency can be very high, of the order of 5-100 kHz or more, depending upon the circuit paramelers. The natural frequency of oscillations of the transient recovery voltage of the circuit in terms of circuit parameters can be expres.sed as ... 

The leriTi naUiral is used lo dilTcreniiale a p[Pg.565]

This is to achieve a higher level of fault current to obtain a quicker tripping on fault. It is obtained when the system has a ground fault factor not exceeding 1.4 (Vg < O.SVf), as noted above. A solidly grounded system will provide effective grounding. This system will reduce the transient oscillations and allow a current sufficient to select a ground fault protection. It is normally applicable to an LT system. 

Reactive control is also possible through synchronous condensers. As they rotate, the rotor stores kinetic energy which tends to absorb sudden Huctuations in the supply system, such as sudden loadings. They are. however, sluggish in operation and very expensive compared to thyristor controls. Their rotating masses add inertia, contribute to the transient oscillations and add to the fault level of the system. All these factors render them less suitable for such applications. Their application is therefore gradually disappearing. 

Actually, a total closed-loop phase lag limit of 3i5 degrees is commonly used by designers any closer to 360 degrees would constitute a metastable system. This could result in the power supply breaking out into periods of oscillation when large loads or line transients are experienced. 

In an effort to determine the processes responsible for this type of behavior, Akiba and Tanno (A3), Sehgal and Strand (S2), and Beckstead (B6) have studied the coupling between the dynamics of the combustion process and the dynamic ballistics of the combustion chamber as described by Eq. (7). Each of these investigators has postulated admittedly simplified but slightly different combustion models to couple with the transient ballistic equations. Each has examined the combined equations for regions of instability. The results of these studies suggest a correlation between the L of the motor (the ratio of combustion-chamber volume to nozzle throat area) and the frequency of the oscillations. 

The connection between instability and termination is not clearly understood. Some investigators have suggested that the oscillating pressures resulting from the instability induce depressurization rates. Their argument says that by rearrangement of the transient ballistic mass balance [Eq. (7)], the depressurization rate is... 

Achieving steady-state operation in a continuous tank reactor system can be difficult. Particle nucleation phenomena and the decrease in termination rate caused by high viscosity within the particles (gel effect) can contribute to significant reactor instabilities. Variation in the level of inhibitors in the feed streams can also cause reactor control problems. Conversion oscillations have been observed with many different monomers. These oscillations often result from a limit cycle behavior of the particle nucleation mechanism. Such oscillations are difficult to tolerate in commercial systems. They can cause uneven heat loads and significant transients in free emulsifier concentration thus potentially causing flocculation and the formation of wall polymer. This problem may be one of the most difficult to handle in the development of commercial continuous processes. 

This set of first-order ODEs is easier to solve than the algebraic equations where all the time derivatives are zero. The initial conditions are that a ut = no, bout = bo,... at t = 0. The long-time solution to these ODEs will satisfy Equations (4.1) provided that a steady-state solution exists and is accessible from the assumed initial conditions. There may be no steady state. Recall the chemical oscillators of Chapter 2. Stirred tank reactors can also exhibit oscillations or more complex behavior known as chaos. It is also possible that the reactor has multiple steady states, some of which are unstable. Multiple steady states are fairly common in stirred tank reactors when the reaction exotherm is large. The method of false transients will go to a steady state that is stable but may not be desirable. Stirred tank reactors sometimes have one steady state where there is no reaction and another steady state where the reaction runs away. Think of the reaction A B —> C. The stable steady states may give all A or all C, and a control system is needed to stabilize operation at a middle steady state that gives reasonable amounts of B. This situation arises mainly in nonisothermal systems and is discussed in Chapter 5. 

The steady-state design equations (i.e., Equations (14.1)-(14.3) with the accumulation terms zero) can be solved to find one or more steady states. However, the solution provides no direct information about stability. On the other hand, if a transient solution reaches a steady state, then that steady state is stable and physically achievable from the initial composition used in the calculations. If the same steady state is found for all possible initial compositions, then that steady state is unique and globally stable. This is the usual case for isothermal reactions in a CSTR. Example 14.2 and Problem 14.6 show that isothermal systems can have multiple steady states or may never achieve a steady state, but the chemistry of these examples is contrived. Multiple steady states are more common in nonisothermal reactors, although at least one steady state is usually stable. Systems with stable steady states may oscillate or be chaotic for some initial conditions. Example 14.9 gives an experimentally verified example. 

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