Orientation transparency

Maximum information is obtained by making Raman measurements on oriented, transparent single crystals. The essentials of the experiment are sketched in Figure 3. The crystal is aligned with the crystallographic axes parallel to a laboratory coordinate system defined by the directions of the laser beam and the scattered beam. A useful shorthand for describing the orientational relations (the Porto notation) is illustrated in Figure 3 as z(xz) y. The first symbol is the direction of the laser beam the second symbol is the polarization direction of the laser beam the third symbol is the polarization direction of the scattered beam and the fourth symbol is the direction of the scattered beam, all with respect to the laboratory coordinate system. 

M. Ogawa, Formation of Novel Oriented Transparent Films of Layered Silica-Surfactant Nanocomposites. J. Am. Chem. Soc., 1994, 116, 7941-7942. 

Variable Orientation Transparency Gloss Stiffness Impact Resistance... 

Rough determination of the tenacity of the partially oriented opaque filaments and the oriented transparent filaments prepared from them by cold... 

Fig. 10. Characteristics of the LAM found in highly oriented transparent isotactic polypropylene (a) at 300 K and (b) at 110 K band at right is at 398 cm (c) plot of Raman frequency versus L — 1 (L is the Bragg spacing of the X-ray small-angle maximum).

Crosslinking can be used to overcome the aforementioned obstacles, as in the case of the calamitic networks in which the orientation and polarity are preserved. First experiments were performed by swelling a calamitic LCE with a low-molar-mass BCLC [182, 183]. Up to 35 mol% of this material could be incorporated into the network. The resulting gel had a flexoelectric cmistant e-i of 20 nC/m. This is one-third of the value of the low-molar-mass BCLC, which corresponds to the volume fraction of the BCLC. Only recently has a pure bent-core elastomer (BCFLCE) been made [139, 169]. Following the synthetic route of Finkelmann, an oriented, transparent nematic elastomer sample could be obtained. As a polysiloxane backbone was used, the Tg was close to room temperature. The flexoelectric constant of 40 nC/m is somewhat smaller than for the pure bend-core monomer, but larger than the value obtained for the swollen elastomer. 

Nishiyama N., Tanaka S., Egashira Y., Oku Y., Ueyama K. Vapor-phase s)mthesis of mesoporous silica thin films. Chem. Mate. 2003 15 1006-1011 Noma T., Takada K., Miyata H., lida A. X-ray micro diffraction study on mesostructured silica thin films. Nucl. Instrum. Methods Phys. Res. A 2001 467 1021-1025 Ogawa M. Formation of novel oriented transparent films of layered silica-surfactant nanocomposites. J. Am. Chem. Soc. 1994 116 7941-7942... 

Ogawa M. Incorporation of pyrene into an oriented transparent films of layered silica-hexadecyltrimethylammonium bromide nanocomposite. Langmuir 1995 11 4639 641 Ogawa M. A simple sol-gel route for the preparation of silica-surfactant mesostructured materials. Chem. Commun. 1996 1149-1150... 

Ogawa, M., 1994. Formation of novel oriented transparent films of layered silica-surfactant nanocomposites. J Am Chem Soc 116 7941 2. 

Figure C3.1.13. Experimentai configuration for far-UV nanosecond CD measurements using a frequency-upconverted Ti sapphire iaser as a probe source. Pj and P2 are Mgp2 Rochon poiarizers at cross orientations. SP is a strained transparent piate with about i ° of iinear birefringence for quasi-nuii eiiipsometric CD detection. Prism PMj and the iris Ij seiect the far-UV fourth hannonic of the argon iaser-pumped Ti-sapphire iaser s near-IR fundamentai output to probe the eiiipticity of the sampie. A second iaser beam at 532 nm is used to pump CD...

The ir spectra acquired in this way are extremely sensitive to the orientation of the surface molecules. Molecules must have a significant component of a molecular vibration perpendicular to the surface to be sensed by coupling with the highly directional electric field. Molecules whose dipole moments are perfectly parallel to the surface caimot couple to the existing electric fields, and therefore, are ir transparent by this method. This selectivity of the approach for molecule dipole moments perpendicular as opposed to parallel to the surface is known as the surface selection rule of irras. 

Poly(vinyl fluoride) is available from Du Pont both as a resia and as transparent and pigmented films under the trademark Tedlar PVF film. Films are available ia nonoriented and oriented grade ia several tensile modifications and thicknesses, with either adherable or nonadherable release-grade surfaces. The 1992 prices ranged from 30 to 70/kg, vs 24 to 62/kg ia 1988. Prices for specially tailored films were significantly higher. 

Oriented polypropylene film (OPP) may be classified as heat-set and non-heat-set, blown and tentered, coextmded and coated. Orientation improves the cold-temperature resistance and other physical properties. Heat-set biaxially oriented polypropylene film (BOPP) is the most widely used protective packagiag film ia the United States. It is used to wrap bakery products, as lamination pHes for potato and com chips, and for pastas and numerous other flexible pouch and wrapping appHcations. Nonheat-set OPP is used as a sparkling, transparent shrink-film overwrap for cartons of candy. 

Soft-drink bottles made from poly(ethylene terephthalate) (PET) are usuady made by stretch-blow mol ding in a two-step process. Eirst, a test-tube-shaped preform is molded, which is then reheated to just above its glass-transition temperature, stretched, and blown. Stretching the PET produces biaxial orientation, which improves transparency, strength, and toughness of the botde (54,56). A one-step process is used for many custom containers that are injection stretch-blow molded. 

The essential differences between sequential-modular and equation-oriented simulators are ia the stmcture of the computer programs (5) and ia the computer time that is required ia getting the solution to a problem. In sequential-modular simulators, at the top level, the executive program accepts iaput data, determines the dow-sheet topology, and derives and controls the calculation sequence for the unit operations ia the dow sheet. The executive then passes control to the unit operations level for the execution of each module. Here, specialized procedures for the unit operations Hbrary calculate mass and energy balances for a particular unit. FiaaHy, the executive and the unit operations level make frequent calls to the physical properties Hbrary level for the routine tasks, enthalpy calculations, and calculations of phase equiHbria and other stream properties. The bottom layer is usually transparent to the user, although it may take 60 to 80% of the calculation efforts. 

Two crossed polarizers are frequently used to inspect transparent materials placed between them for optical activity, either for birefringence or for optical rotary effects. Birefringence effects are produced by materials with a regular ordered structure that allows light to pass through at one orientation at a higher velocity than at another orientation. As a result of this, the two wave trains generated by the different velocities... 

This concept has been known for over a century. Expressed as Brewster s Constant law, it states that the index of refraction in a strained material becomes directional, and the change of the index is proportional to the magnitude of the stress (or strain) present. Therefore, a polarized beam in the clear plastic splits into two wave fronts in the X and Y directions that contain vibrations oriented along the directions of principal stresses. An analyzing filter passes only vibrations parallel to its own transmitting plane (Chapter 4, TRANSPARENT AND OPTICAL PRODUCT, Polarized Lighting). 

Figure 1 Schematic drawing of the morphology of the ribosome. The ribosomal subunits are labeled, as are the approximate locations of their respective functional centers. The drawing is a transparent view from the solvent side of the small subunit. Transfer RNAs are shown in different binding states with the arrow indicating their direction of movement through the ribosome. The tRNA anticodon ends are oriented towards the viewer, whereas the 3-ends of the tRNAs are oriented towards the peptidyl transferase region on the large subunit. The letters h and b denote the head and body regions on the 30S subunit, respectively.

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